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J-aggregate structures in crystals of three bisazomethine dyes

  • Shinya Matsumoto , Kazuko Shirai , Kimiko Kobayashi , Tatsuo Wada and Motoo Shiro
Published/Copyright: September 25, 2009

Abstract

The crystal structures of three bisazomethine dyes, which form J-aggregates in vapor-deposited films, were investigated. The characteristic two-dimensional arrangement of molecules proposed for J-aggregates was recognized in crystals of all three dyes. The observation of unusual bond lengths in one of the dyes at 298 K was resolved by a low temperature study, i.e. 93 K, that showed the existance of conformational disorder at the higher temperature.

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Published Online: 2009-9-25
Published in Print: 2004-4-1

© 2004 Oldenbourg Wissenschaftsverlag GmbH

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