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The crystal structure of Tl5Te3 and its relationship to the Cr5B3 type
Published/Copyright:
August 25, 2010
Abstract
Single crystals of Tl5Te3 have been synthesized from stoichiometric mixtures of the elements in a two step reaction. Tl5Te3 crystallizes in the tetragonal space group I4/mcm (No. 140) with a = 8.930(2) Å and c = 12.589(4) Å. The structure is isopointal to the Cr5B3 structure type but differs in some details. The interatomic distances clearly show a separation into Tl2Te molecular-like fragments (Tl – Te = 3.16 Å; [unk] Tl – Te – Tl = 78.5°) and one-dimensional infinite linear TlTe chains (Tl – Te = 3.15 Å). The axial ratio c/a and the positional parameters indicate unambiguously that Tl5Te3 and Cr5B3 belong to definitively separated branches of the Cr5B3 structure type.
Published Online: 2010-08-25
Published in Print: 1989
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Articles in the same Issue
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- Crystal structure analysis from powder diffraction data
- Intensitätsstatistik für Strukturen mit Überstruktureffekten
- Crystal and molecular structure of 10-methoxy-8, 8-dimethyl 2H,8H-benzo (1,2-b:5,4-b′-dipyron-2-one) (Luvangetin)
- Crystal structure of a complex of glycine with zinc chloride
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