Sorption and diffusion of Eu in sedimentary rock in the presence of humic substance
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Y. Seida
Abstract
Sorption and diffusion behaviors of Eu in sedimentary rock in the presence of humic substance were investigated. The sedimentary rock collected from 500 m depth of HDB-6 bore hole at horonobe URL site of Japan and Aldrich humic acid (HA) were used in the present study. Sorption behaviors of Eu and the HA on the sedimentary rocks with and without the rock organic matter (ROM) were elucidated as a function of HA concentration. The HA reduced the sorption of Eu on the rock with the increase of HA. Eu and HA sorption on the rock with the ROM was larger than on the rock after removing the ROM, indicating that the ROM plays an important role on the sorption of Eu and HA. The diffusion of Eu in the presence of HA was examined as a function of HA concentration and molecular weight of the HA (∼150 kDa or below 10 kDa) by means of a reservoir depletion test method with the intact rock core of the sedimentary rock. Depletion of Eu concentration in the reservoir was reduced with the increase of HA concentration. On the other hand, slight depletion of HA concentration in the reservoir was observed, indicating that the larger HA molecule diffused less into the rock. From the depletion curve and in-diffusion profile of Eu in the rock, the effective diffusion coefficient, De, and distribution coefficient, Kd, in the intact system were estimated based on the profile fitting of the diffusion data with the conventional simple diffusion-sorption model. It was elucidated that the HA reduced the Kd and De of Eu in the intact system with the increase of HA. The contribution of the HA with smaller molecular weight to both the Eu sorption and diffusion was examined.
© by Oldenbourg Wissenschaftsverlag, Ibaraki, 319-1194, Germany
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Articles in the same Issue
- Preface
- Solubility of tetravalent actinides in alkaline CaCl2 solutions and formation of Ca4[An(OH)8]4+ complexes: A study of Np(IV) and Pu(IV) under reducing conditions and the systematic trend in the An(IV) series
- Solubility of triuranyl diphosphate tetrahydrate (TDT) and Na autunite at 23 and 50 °C
- Effect of reduction on the stability of Pu(VI) hydrolysis species
- Retention and redox behaviour of uranium(VI) by siderite (FeCO3)
- Neptunium(V) complexation by natural pyoverdins and related model compounds
- Complexation of Nd(III) with tetraborate ion and its effect on actinide(III) solubility in WIPP brine
- Complexation of Tc(IV) with acetate at varying ionic strengths
- Uranyl photochemistry: decarboxylation of gluconic acid
- Influence of Boom Clay organic matter on the adsorption of Eu3+ by illite – geochemical modelling using the component additivity approach
- The role of green rust in the migration of radionuclides: An overview of processes that can control mobility of radioactive elements in the environment using as examples Np, Se and Cr
- A comparative batch sorption and time-resolved laser fluorescence spectroscopy study on the sorption of Eu(III) and Cm(III) on synthetic and natural kaolinite
- U(VI) sorption on granite: prediction and experiments
- Quantum chemical study of inner-sphere complexes of trivalent lanthanide and actinide ions on the corundum (0001) surface
- Quantum chemical modeling of uranyl adsorption on mineral surfaces
- Interaction of PuO2 thin films with water
- Molecular interactions of plutonium(VI) with synthetic manganese-substituted goethite
- Chlorine speciation in nuclear graphite: consequences on temperature release and on leaching
- Chemical status of U(VI) in cemented waste forms under saline conditions
- Influence of iron redox transformations on plutonium sorption to sediments
- Modelling of a large-scale in-situ migration experiment with 14C-labelled natural organic matter in Boom Clay
- Sorption and diffusion of Eu in sedimentary rock in the presence of humic substance
- Diffusion and sorption of neptunium(V) in compacted montmorillonite: effects of carbonate and salinity
- Uranium(VI) diffusion in low-permeability subsurface materials
- Distribution of Cs and Am in the solution-bentonite colloids-granite ternary system: effect of addition order and sorption reversibility
- Mechanisms of plutonium sorption to mineral oxide surfaces: new insights with implications for colloid-enhanced migration
- Understanding uranium behaviour at the Askola uranium mineralization
