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Hot-Atom Chemistry and Thermal Decomposition of Sodium Azide Crystals Containing Nitrogen-13 Recoil Atoms
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B. Reitzner
Published/Copyright:
August 1, 1964
Summary
The reactions of recoil 13N atoms produced by the (n, 2n) reaction in sodium azide have been studied: labelled azide and nitrogen (N2) are the principal products, with yields of about 30 and 65% respectively. The yield of azide shows little dependence on temperature. When samples of the irradiated salt are subjected to thermal decomposition, the specific activity of the nitrogen evolved first falls, then rises and shows a peak during the "induction period" for bulk decomposition. This behavior is interpreted in terms of displacement spike theory.
Published Online: 1964-8-1
Published in Print: 1964-8-1
© 2013 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
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Articles in the same Issue
- Geleitwort
- Hot Electron Chemistry
- The Hot Iodine Substitution Reaction in Gaseous Methyl Iodide
- État chimique de formé au cours de l’irradiatión neutronique de composés du tellure
- Versuche zur Identifizierung der bei der 191Ir (n, γ) 192Ir-Kernreaktion entstandenen chemischen Folgeprodukte im Na2lrCl6 • 6H2O
- Hot-Atom Chemistry and Thermal Decomposition of Sodium Azide Crystals Containing Nitrogen-13 Recoil Atoms
- Neutron Activatiön Analysis of Traces of Sodium in Quartz
- Bestimmung von Spuren Protaetinium-231
- Heteropoly Salts
- Kurze Mitteilungen
- Isolation of Carrier-Free 202mPb and 203Pb
- Isolation of Carrier-Free 90mY and 93mMo
- Szilard-Chalmers Effect in Solid Xenon Tetrafluoride
- Kationenselbstaustausch an dünnen Schichten sulfonierten Polystyrols
