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The Hot Iodine Substitution Reaction in Gaseous Methyl Iodide
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R.J. Cross
Published/Copyright:
August 1, 1964
Summary
Chemical reactions of hot atomic iodine formed by recoil from a photoneutron emission process, (γ, n) have been studied. The yield of the hot substitution, 126I + CH3I → CH3126I + I was determined. The probability of this process, compared to analogous reactions of hot hydrogen atoms, was found to be low. A possible reason for what appears to be a generally low efficiency of gas phase hot halogen atom substitution reactions is discussed.
Published Online: 1964-8-1
Published in Print: 1964-8-1
© 2013 Oldenbourg Wissenschaftsverlag GmbH, Rosenheimer Str. 145, 81671 München
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Articles in the same Issue
- Geleitwort
- Hot Electron Chemistry
- The Hot Iodine Substitution Reaction in Gaseous Methyl Iodide
- État chimique de formé au cours de l’irradiatión neutronique de composés du tellure
- Versuche zur Identifizierung der bei der 191Ir (n, γ) 192Ir-Kernreaktion entstandenen chemischen Folgeprodukte im Na2lrCl6 • 6H2O
- Hot-Atom Chemistry and Thermal Decomposition of Sodium Azide Crystals Containing Nitrogen-13 Recoil Atoms
- Neutron Activatiön Analysis of Traces of Sodium in Quartz
- Bestimmung von Spuren Protaetinium-231
- Heteropoly Salts
- Kurze Mitteilungen
- Isolation of Carrier-Free 202mPb and 203Pb
- Isolation of Carrier-Free 90mY and 93mMo
- Szilard-Chalmers Effect in Solid Xenon Tetrafluoride
- Kationenselbstaustausch an dünnen Schichten sulfonierten Polystyrols
Articles in the same Issue
- Geleitwort
- Hot Electron Chemistry
- The Hot Iodine Substitution Reaction in Gaseous Methyl Iodide
- État chimique de formé au cours de l’irradiatión neutronique de composés du tellure
- Versuche zur Identifizierung der bei der 191Ir (n, γ) 192Ir-Kernreaktion entstandenen chemischen Folgeprodukte im Na2lrCl6 • 6H2O
- Hot-Atom Chemistry and Thermal Decomposition of Sodium Azide Crystals Containing Nitrogen-13 Recoil Atoms
- Neutron Activatiön Analysis of Traces of Sodium in Quartz
- Bestimmung von Spuren Protaetinium-231
- Heteropoly Salts
- Kurze Mitteilungen
- Isolation of Carrier-Free 202mPb and 203Pb
- Isolation of Carrier-Free 90mY and 93mMo
- Szilard-Chalmers Effect in Solid Xenon Tetrafluoride
- Kationenselbstaustausch an dünnen Schichten sulfonierten Polystyrols
