Influence of doping concentrations on the structural, optical, and magnetic properties of Ba-doped LaCoO3 nanostructure
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Jhelai Sahadevan
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Ikhyun Kim
Abstract
In this article we report the structural, morphology, vibrational, optical and magnetic properties of Ba x La1−xCoO3 (x = 0, 0.05, and 0.1) (LBCO) samples. The X-ray diffraction shows that samples are in single rhombohedral phase. The Raman signals of LCO were quite small in comparison to LBCO, which exhibited a Raman peak above 675 cm−1. The band seen with a wavenumber of 484 cm−1 corresponds to the vibrational modes of Eg bending and Ba–O stretching. UV–DRS and photoluminescence spectra indicated broad absorption over the ultraviolet, visible, and near-infrared spectrums. Surface morphology and EDAX spectra corroborated the materials homogeneous size distribution and homogenous microstructure, with Ba indicating a more stable structure. XPS was used to study chemical states of LBCO and found Co (2p), La (3d), O (1s), and C (1s) elements in perovskite compounds. A peak beneath 300 eV indicated adventitious carbon on surface materials. XPS survey spectrum elements La, Ba, Co, and O had their own binding energies. The magnetization-field dependency of LBCO at 300 K showed that Ba insertion into the LCO switched it from paramagnetic to weak ferromagnetic. Ba considerably decreased magnetic saturation and coercivity, influencing magneto-crystallites’ anisotropy and coercive field.
Funding source: Researchers Supporting Project number (RSP2024R70), King Saud University, Riyadh, Saudi Arabia
Award Identifier / Grant number: Project Number (RSP2024R70)
Acknowledgments
The authors express their sincere appreciation to the Researchers Supporting Project Number (RSP2024R70), King Saud University, Riyadh, Saudi Arabia.
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Research ethics: Not applicable.
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Author contributions: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.
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Competing interests: The authors state no conflict of interest.
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Research funding: Researchers Supporting Project number (RSP2024R70), King Saud University, Riyadh, Saudi Arabia.
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Data availability: The raw data can be obtained on request from the corresponding author.
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© 2024 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Contributions to “Materials for solar water splitting”
- Preparation of fluorinated zirconia doped with tin oxide nanocomposites for photocatalytic degradation of organic dyes in contaminated water bodies
- A study of the effect of cerium ion doping concentration on the structural, electrical, and thermoelectric properties of CaMnO3 nanoparticles
- Biosensors and its diverse applications in healthcare systems
- Estimation on magnetic entropy change and specific heat capacity through phoenomological model for Heusler melt spun ribbon of Ni47Mn40−xSi x In3 (x = 1, 2 and 3)
- Probing the structural and electronic properties of MAX phases and their corresponding MXenes using first-principles calculations
- Boosted electrochemical properties of Co3O4 nanoflakes by the addition of a redox-additive electrolyte
- Evaluation of magnetic and electrochemical performance of copper oxide nanoparticles using Myristica fragrans (mace) extract
- Incredible electrochemical performance of ZnWO4/PANI as a favorable electrode material for supercapacitor
- Influence of doping concentrations on the structural, optical, and magnetic properties of Ba-doped LaCoO3 nanostructure
- Green engineering of NiO nanoparticles decorated with Arachis hypogaea shell extract for biomedical applications
Artikel in diesem Heft
- Frontmatter
- Contributions to “Materials for solar water splitting”
- Preparation of fluorinated zirconia doped with tin oxide nanocomposites for photocatalytic degradation of organic dyes in contaminated water bodies
- A study of the effect of cerium ion doping concentration on the structural, electrical, and thermoelectric properties of CaMnO3 nanoparticles
- Biosensors and its diverse applications in healthcare systems
- Estimation on magnetic entropy change and specific heat capacity through phoenomological model for Heusler melt spun ribbon of Ni47Mn40−xSi x In3 (x = 1, 2 and 3)
- Probing the structural and electronic properties of MAX phases and their corresponding MXenes using first-principles calculations
- Boosted electrochemical properties of Co3O4 nanoflakes by the addition of a redox-additive electrolyte
- Evaluation of magnetic and electrochemical performance of copper oxide nanoparticles using Myristica fragrans (mace) extract
- Incredible electrochemical performance of ZnWO4/PANI as a favorable electrode material for supercapacitor
- Influence of doping concentrations on the structural, optical, and magnetic properties of Ba-doped LaCoO3 nanostructure
- Green engineering of NiO nanoparticles decorated with Arachis hypogaea shell extract for biomedical applications
