Rice husk composite with polyaniline, sodium alginate and polypyrrole: naphthalene adsorption kinetics, equilibrium and thermodynamic studies
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Tayyba Arooj
,
Najla AlMasoud
Abstract
In this investigation, composites consisting of polypyrrole (PPy), polyaniline (PAN), and sodium alginate combined with rice husk (RH) biomass were fabricated, utilizing them as adsorbents for naphthalene. The optimization of key process variables, including pH, pesticide concentration, composite dosage, contact time, and temperature were systematically undertaken to enhance the removal efficiency of naphthalene. Notably, the composites exhibited promising efficacy in adsorbing naphthalene, with native rice husk and PPy/RH (at pH 4), PAN/RH (at pH 5), and Na-alginate/RH (at pH 6) displaying the highest removal rates. Optimized conditions for composite dosage, temperature, and contact time were determined as 0.05 g, 30 °C, and 90 min, respectively, ensuring efficient removal of naphthalene. The adsorption capacities for naphthalene were found to be 22.04, 23.15, 23.89 and 21.67 (mg/g) for RH, PAN/RH, PPY/RH and Na-alginate/RH, respectively. The Langmuir isotherm and pseudo-first-order kinetics models aptly described the adsorption process onto the composite material. The surface morphology and functional groups involved in the biocomposite formation were examined through scanning electron microscope (SEM) and Fourier-transform infrared (FTIR) techniques. These analyses confirmed that PPy, PAN, and Na-alginate composites with RH biomass exhibit high effectiveness in naphthalene removal, showcasing their potential application in the remediation of naphthalene from effluents.
Funding source: Princess Nourah bint Abdulrahman University Researchers
Award Identifier / Grant number: (PNURSP2024R18)
Funding source: Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia
Acknowledgments
The authors express their gratitude to Princess Nourah bint Abdulrahman University Researchers Supporting Project number (PNURSP2024R18), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.
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Research ethics: Not applicable.
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Competing interests: The authors declare that they have no conflicts of interest.
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Research funding: This research was funded by Princess Nourah bint Abdulrahman University Researchers Supporting Project number (PNURSP2024R18), Princess Nourah bint Abdulrahman University, Riyadh, Saudi Arabia.
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Data availability: Not applicable.
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© 2024 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Review Article
- The assessment of pollutant waste generated by battery and its effect on the environment: a concise review
- Original Papers
- Biosynthesis of ZnO/Ag nanocomposites heterostructure for efficient photocatalytic degradation of antibiotics and synthetic dyes
- Kinetics, equilibrium and thermodynamics investigations of polypyrrole and polyaniline composites with Oryza sativa biomass for the removal of Nitenpyram insecticide
- Remediation of pesticides, acetamiprid and imidacloprid from aqueous solutions using cellulose derived from sawdust of Populus nigra
- Rice husk composite with polyaniline, sodium alginate and polypyrrole: naphthalene adsorption kinetics, equilibrium and thermodynamic studies
- Graphene oxide composite as a novel corrosion inhibitor for N80 steel in 15 % HCl: experimental and quantum chemical examinations
- Molecular level interaction, molecular structure, chemical reactivity, electronic and topological exploration and docking studies of 1-acetyl-4-piperidinecarboxylic acid
- Exploring the dynamics of halogen and hydrogen bonds in halogenated coumarins
- Electrochemical sensing and detection of phosgene and thiophosgene chemical warfare agents (CWAs) by all-boron B38 fullerene analogue: a DFT insight
Artikel in diesem Heft
- Frontmatter
- Review Article
- The assessment of pollutant waste generated by battery and its effect on the environment: a concise review
- Original Papers
- Biosynthesis of ZnO/Ag nanocomposites heterostructure for efficient photocatalytic degradation of antibiotics and synthetic dyes
- Kinetics, equilibrium and thermodynamics investigations of polypyrrole and polyaniline composites with Oryza sativa biomass for the removal of Nitenpyram insecticide
- Remediation of pesticides, acetamiprid and imidacloprid from aqueous solutions using cellulose derived from sawdust of Populus nigra
- Rice husk composite with polyaniline, sodium alginate and polypyrrole: naphthalene adsorption kinetics, equilibrium and thermodynamic studies
- Graphene oxide composite as a novel corrosion inhibitor for N80 steel in 15 % HCl: experimental and quantum chemical examinations
- Molecular level interaction, molecular structure, chemical reactivity, electronic and topological exploration and docking studies of 1-acetyl-4-piperidinecarboxylic acid
- Exploring the dynamics of halogen and hydrogen bonds in halogenated coumarins
- Electrochemical sensing and detection of phosgene and thiophosgene chemical warfare agents (CWAs) by all-boron B38 fullerene analogue: a DFT insight
