Mechanistic Study on Surface Tension of Binary and Ternary Mixtures Containing Choline Chloride, Ethylene Glycol and Water (Components of Aqueous Solutions of a Deep Eutectic Solvent, Ethaline)
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Yelyzaveta Rublova
Abstract
The paper reports the results of the measurement of surface tension in binary liquid mixtures containing choline chloride, ethylene glycol and water and ternary mixtures of ethaline (a eutectic mixture of ethylene glycol and choline chloride, the so-called deep eutectic solvent) with water. The surface tension is determined in a wide range of components’ concentration for the temperatures of 25, 30, 40, 50, 60 and 70 °C. The dependences of surface tension on the concentration of liquids are treated by means of Gibbs adsorption isotherm and linear form of Langmuir adsorption isotherms. The values of the equilibrium constant of adsorption at the interface liquid solution/air as well as the standard adsorption Gibbs energy, enthalpy and entropy are calculated for the binary and ternary mixtures under consideration. The obtained results are interpreted in the light of intermolecular interactions in fluids. Our findings show that ethylene glycol and choline cation interact with each other in the adsorbed surface layer formed at the interface between air and diluted solutions of ethaline.
Acknowledgements
This work was supported by the Ministry of Education and Science of Ukraine (project no. 0118U003398).
References
1. A. P. Abbott, G. Capper, D. L. Davies, R. K. Rasheed, V. Tambyrajah, Chem. Commun. (2003) 70.10.1039/b210714gSuche in Google Scholar PubMed
2. E. L. Smith, A. P. Abbott, K. S. Ryder, Chem. Rev. 114 (2014) 11060.10.1021/cr300162pSuche in Google Scholar PubMed
3. A. Abo-Hamad, M. Hayyan, M. A. AlSaadi, M. A. Hashim, Chem. Eng. J. 273 (2015) 551.10.1016/j.cej.2015.03.091Suche in Google Scholar
4. A. Paiva, R. Craveiro, I. Aroso, M. Martins, R. L. Reis, A. R. C. Duarte, ACS Sustain. Chem. Eng. 2 (2014) 1063.10.1021/sc500096jSuche in Google Scholar
5. L. I. N. Tomé, V. Baião, W. da Silva, C. M. A. Brett, Appl. Mater. Today 10 (2018) 30.10.1016/j.apmt.2017.11.005Suche in Google Scholar
6. Q. Zhang, K. D. O. Vigier, S. Royer, F. Jérôme, Chem. Soc. Rev. 41 (2012) 7108.10.1039/c2cs35178aSuche in Google Scholar PubMed
7. C. Florindo, F. Lima, B. D. Ribeiro, I. M. Marrucho, Curr. Opin. Green Sustain. Chem. 18 (2019) 31.10.1016/j.cogsc.2018.12.003Suche in Google Scholar
8. D. Shah, F. S. Mjalli, Phys. Chem. Chem. Phys. 16 (2014) 23900.10.1039/C4CP02600DSuche in Google Scholar
9. C. Du, B. Zhao, X.-B. Chen, N. Birbilis, H. Yang, Sci. Rep. 6 (2016) 29225.10.1038/srep29225Suche in Google Scholar PubMed PubMed Central
10. D. C. McCalman, L. Sun, Y. Zhang, J. F. Brennecke, E. J. Maginn, W. F. Schneider, J. Phys. Chem. B 119 (2015) 6018.10.1021/acs.jpcb.5b01986Suche in Google Scholar PubMed
11. V. S. Protsenko, A. A. Kityk, D. A. Shaiderov, F. I. Danilov, J. Mol. Liq. 212 (2015) 716.10.1016/j.molliq.2015.10.028Suche in Google Scholar
12. L. S. Bobrova, F. I. Danilov, V. S. Protsenko, J. Mol. Liq. 223 (2016) 48.10.1016/j.molliq.2016.08.027Suche in Google Scholar
13. V. S. Protsenko, L. S. Bobrova, F. I. Danilov, Ionics 23 (2017) 637.10.1007/s11581-016-1826-7Suche in Google Scholar
14. L. Weng, M. Toner, Phys. Chem. Chem. Phys. 20 (2018) 22455.10.1039/C8CP03882ASuche in Google Scholar PubMed
15. O. S. Hammond, D. T. Bowron, K. J. Edler, Angew. Chem. 129 (2017) 9914.10.1002/ange.201702486Suche in Google Scholar
16. T. Zhekenov, N. Toksanbayev, Z. Kazakbayeva, D. Shah, F. S. Mjalli, Fluid Phase Equilib. 441 (2017) 43.10.1016/j.fluid.2017.01.022Suche in Google Scholar
17. C. Ma, A. Laaksonen, C. Liu, X. Lu, X. Ji, Chem. Soc. Rev. 47 (2018) 8685.10.1039/C8CS00325DSuche in Google Scholar PubMed
18. D. Lapeña, L. Lomba, M. Artal, C. Lafuente, B. Giner, Fluid Phase Equilib. 492 (2019) 1.10.1016/j.fluid.2019.03.018Suche in Google Scholar
19. N. G. Tsierkezos, I. E. Molinou, J. Chem. Eng. Data 43 (1998) 989.10.1021/je9800914Suche in Google Scholar
20. M. Tariq, M. G. Freire, B. Saramago, J. A. P. Coutinho, J. N. C. Lopes, L. P. N. Rebelo, Chem. Soc. Rev. 41 (2012) 829.10.1039/C1CS15146KSuche in Google Scholar PubMed
21. Y. Marcus, Entropy 20 (2018) 524.10.3390/e20070524Suche in Google Scholar PubMed PubMed Central
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Artikel in diesem Heft
- Frontmatter
- The Effect of Crystalline Microstructure of PVDF Binder on Mechanical and Electrochemical Performance of Lithium-Ion Batteries Cathode
- Mechanistic Study on Surface Tension of Binary and Ternary Mixtures Containing Choline Chloride, Ethylene Glycol and Water (Components of Aqueous Solutions of a Deep Eutectic Solvent, Ethaline)
- Thiadiazole-2-Thiol-5-Thione and 2,5-Dimercapto-1,3,4-Thiadiazol Tautomerism, Conformational Stability, Vibrational Assignments, Inhibitor Efficiency and Quantum Chemical Calculations
- The Thermodynamic and pH Metric Binding Studies of Cu+2 Ions with Egg Protein by Spectrometric and Diffusion Current Techniques
- Adsorption of 2,4-Dichlorophenoxyacetic Acid from Aqueous Solution Using Carbonized Chest Nut as Low Cost Adsorbent: Kinetic and Thermodynamic
- The Kinetics and Equilibrium Thermodynamics Study on the Removal of Direct Blue and Titan Yellow Dyes from Aqueous Media by Modified Rice Husk Char
- Investigation of Dielectric Properties, Electric Modulus and Conductivity of the Au/Zn-Doped PVA/n-4H-SiC (MPS) Structure Using Impedance Spectroscopy Method
- Finding Solvent for Polyamide 11 Using a Computer Software
- Phytochemical Synthesis of Silver Nanoparticles Using Anthemis Nobilis Extract and Its Antibacterial Activity
Artikel in diesem Heft
- Frontmatter
- The Effect of Crystalline Microstructure of PVDF Binder on Mechanical and Electrochemical Performance of Lithium-Ion Batteries Cathode
- Mechanistic Study on Surface Tension of Binary and Ternary Mixtures Containing Choline Chloride, Ethylene Glycol and Water (Components of Aqueous Solutions of a Deep Eutectic Solvent, Ethaline)
- Thiadiazole-2-Thiol-5-Thione and 2,5-Dimercapto-1,3,4-Thiadiazol Tautomerism, Conformational Stability, Vibrational Assignments, Inhibitor Efficiency and Quantum Chemical Calculations
- The Thermodynamic and pH Metric Binding Studies of Cu+2 Ions with Egg Protein by Spectrometric and Diffusion Current Techniques
- Adsorption of 2,4-Dichlorophenoxyacetic Acid from Aqueous Solution Using Carbonized Chest Nut as Low Cost Adsorbent: Kinetic and Thermodynamic
- The Kinetics and Equilibrium Thermodynamics Study on the Removal of Direct Blue and Titan Yellow Dyes from Aqueous Media by Modified Rice Husk Char
- Investigation of Dielectric Properties, Electric Modulus and Conductivity of the Au/Zn-Doped PVA/n-4H-SiC (MPS) Structure Using Impedance Spectroscopy Method
- Finding Solvent for Polyamide 11 Using a Computer Software
- Phytochemical Synthesis of Silver Nanoparticles Using Anthemis Nobilis Extract and Its Antibacterial Activity
