Inhibition of Steel Corrosion in Sulfuric Acid Solution by 1,10-Phenanthroline, para-Aminobenzoate and their Corresponding Manganese Complex
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Rola N. Tabesh
,
Hassan H. Hammud
Abstract
The ligands 1,10-phenanthroline, (P) and para-aminobenzoate, (B); as well as their corresponding MnPB complex [bis-(dimanganese di-μ-paraaminobenzoate dichloro diphenanthroline)] have been investigated as inhibitors of mild steel corrosion in H2SO4 (0.5 M) solutions via potentiodynamic and electrochemical impedance spectroscopy techniques. Stability of the prepared complex was examined by UV-visible spectroscopy. The corrosion inhibition, thermodynamics, and adsorptive properties obtained have shown that MnPB complex has remarkable effects in the acidic solutions. Theoretical fitting of different adsorption isotherms such as Langmuir, Flory–Huggins, and the kinetic-thermodynamic models were tested and the thermodynamic activation parameters were calculated. The data revealed that the corrosion inhibition mechanism of mild steel in acidic solutions by the MnPB complex goes via physicochemical adsorption.
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Artikel in diesem Heft
- Frontmatter
- 1-(2-Aminoethyl)-1-dodecyl-2-undecyl-4,5-dihydro-1H-imidazol-1-ium chloride, 1-(2-Aminoethyl)-1-dodecyl-2-tridecyl-4,5-dihydro-1H-imidazol-1-ium chloride as Corrosion Inhibitors for Carbon Steel in Oil Wells Formation Water
- Inhibition of Steel Corrosion in Sulfuric Acid Solution by 1,10-Phenanthroline, para-Aminobenzoate and their Corresponding Manganese Complex
- New Star Shape Tetra-Cationic Surfactant Synthesis and Evaluation as Corrosion Inhibitor for Carbon Steel in Different Acidic Media
- A Novel Approach for Modification of Biosorbent by Silane Functionalization and its Industrial Application for Single and Multi-Component Solute System
- Exploring the Effect of Electron Withdrawing Groups on Optoelectronic Properties of Pyrazole Derivatives as Efficient Donor and Acceptor Materials for Photovoltaic Devices
- 4-Acetamidophenol Binding Mechanism with DNA by UV-Vis and FTIR Techniques Based on Binding Energy, LUMO and HOMO Orbitals and Geometry of Molecule
- Growth, Vibrational, Optical, Mechanical and DFT Investigations of an Organic Nonlinear Optical Material – Phenylurea
Artikel in diesem Heft
- Frontmatter
- 1-(2-Aminoethyl)-1-dodecyl-2-undecyl-4,5-dihydro-1H-imidazol-1-ium chloride, 1-(2-Aminoethyl)-1-dodecyl-2-tridecyl-4,5-dihydro-1H-imidazol-1-ium chloride as Corrosion Inhibitors for Carbon Steel in Oil Wells Formation Water
- Inhibition of Steel Corrosion in Sulfuric Acid Solution by 1,10-Phenanthroline, para-Aminobenzoate and their Corresponding Manganese Complex
- New Star Shape Tetra-Cationic Surfactant Synthesis and Evaluation as Corrosion Inhibitor for Carbon Steel in Different Acidic Media
- A Novel Approach for Modification of Biosorbent by Silane Functionalization and its Industrial Application for Single and Multi-Component Solute System
- Exploring the Effect of Electron Withdrawing Groups on Optoelectronic Properties of Pyrazole Derivatives as Efficient Donor and Acceptor Materials for Photovoltaic Devices
- 4-Acetamidophenol Binding Mechanism with DNA by UV-Vis and FTIR Techniques Based on Binding Energy, LUMO and HOMO Orbitals and Geometry of Molecule
- Growth, Vibrational, Optical, Mechanical and DFT Investigations of an Organic Nonlinear Optical Material – Phenylurea
