New Star Shape Tetra-Cationic Surfactant Synthesis and Evaluation as Corrosion Inhibitor for Carbon Steel in Different Acidic Media
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Elsayed A. El-Sharaky
,
Olfat E. El-Azabawy
Abstract
A new star shape tetra-cationic surfactant was synthesized to evaluate as corrosion inhibitors for carbon steel in different acid media. This surfactant prepared by the reaction of tris(2-(dimethylamino)ethyl) O,O′,O′′-(nitrilotris(ethane-2,1-diyl)) trimaleate with 1-bromododecane and abbreviated as STCS. The chemical structure of the prepared surfactant was confirmed by FT-IR, 13C and 1HNMR and elemental analysis. Their aggregation behavior in watery solution was explored by surface tension measurements. The surface tension of water was decreased nearly to 35 mN m−1 when adding the surfactant. This result demonstrates that the surfactant shows remarkable surface activity, due to the effect of the head groups. Corrosion inhibition efficiency of the surfactant on the carbon steel surface in 1 M hydrochloride acid and 1 M H2SO4 was evaluated using the electrochemical measurements. These measurements revealed that the synthesized surfactant act as effective mixed-type corrosion inhibitors. Their adsorption on a carbon steel surface was well described by the Langmuir adsorption isotherm. Corrosion inhibition efficiency was enhanced with increasing the concentration of inhibitor and increasing the temperatures. The results of the quantum chemical calculations and the electrochemical measurements were in good agreement.
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©2019 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- 1-(2-Aminoethyl)-1-dodecyl-2-undecyl-4,5-dihydro-1H-imidazol-1-ium chloride, 1-(2-Aminoethyl)-1-dodecyl-2-tridecyl-4,5-dihydro-1H-imidazol-1-ium chloride as Corrosion Inhibitors for Carbon Steel in Oil Wells Formation Water
- Inhibition of Steel Corrosion in Sulfuric Acid Solution by 1,10-Phenanthroline, para-Aminobenzoate and their Corresponding Manganese Complex
- New Star Shape Tetra-Cationic Surfactant Synthesis and Evaluation as Corrosion Inhibitor for Carbon Steel in Different Acidic Media
- A Novel Approach for Modification of Biosorbent by Silane Functionalization and its Industrial Application for Single and Multi-Component Solute System
- Exploring the Effect of Electron Withdrawing Groups on Optoelectronic Properties of Pyrazole Derivatives as Efficient Donor and Acceptor Materials for Photovoltaic Devices
- 4-Acetamidophenol Binding Mechanism with DNA by UV-Vis and FTIR Techniques Based on Binding Energy, LUMO and HOMO Orbitals and Geometry of Molecule
- Growth, Vibrational, Optical, Mechanical and DFT Investigations of an Organic Nonlinear Optical Material – Phenylurea
Articles in the same Issue
- Frontmatter
- 1-(2-Aminoethyl)-1-dodecyl-2-undecyl-4,5-dihydro-1H-imidazol-1-ium chloride, 1-(2-Aminoethyl)-1-dodecyl-2-tridecyl-4,5-dihydro-1H-imidazol-1-ium chloride as Corrosion Inhibitors for Carbon Steel in Oil Wells Formation Water
- Inhibition of Steel Corrosion in Sulfuric Acid Solution by 1,10-Phenanthroline, para-Aminobenzoate and their Corresponding Manganese Complex
- New Star Shape Tetra-Cationic Surfactant Synthesis and Evaluation as Corrosion Inhibitor for Carbon Steel in Different Acidic Media
- A Novel Approach for Modification of Biosorbent by Silane Functionalization and its Industrial Application for Single and Multi-Component Solute System
- Exploring the Effect of Electron Withdrawing Groups on Optoelectronic Properties of Pyrazole Derivatives as Efficient Donor and Acceptor Materials for Photovoltaic Devices
- 4-Acetamidophenol Binding Mechanism with DNA by UV-Vis and FTIR Techniques Based on Binding Energy, LUMO and HOMO Orbitals and Geometry of Molecule
- Growth, Vibrational, Optical, Mechanical and DFT Investigations of an Organic Nonlinear Optical Material – Phenylurea
