New compounds of the Li2MSn3S8 type
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Eva M. Heppke
Abstract
The substitution of Cu/Ag by lithium in complex thiospinels with the general formula AI2BIICIV3XVI8 was achieved by ball milling and a subsequent annealing step in an atmosphere of H2S. Four hitherto unknown compounds Li2MSn3S8 with M = Mg, Mn, Fe, Ni were obtained without side phases and have been structurally investigated. From X-ray powder diffraction experiments, space group Fd
Funding source: German Science Foundation
Award Identifier / Grant number: DFG, LE 781/19-1
Acknowledgment
The authors would like to thank Astrid Müller-Klauke for performing the ICP-OES analysis and Leo Sagurna for his support and provision of the UV–Vis spectrometer (both TU Berlin).
Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: This project was partially supported by the German Science Foundation (DFG, LE 781/19-1).
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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Articles in the same Issue
- Frontmatter
- In this issue
- Research articles
- Derivatives of the triaminoguanidinium ion, 7: unsymmetrically substituted N,N',N''-triaminoguanidinium salts via a cyclopentanone spiroaminal intermediate
- Diethyl (iodoethynyl)phosphonate and (iodoethynyl)diphenylphosphane oxide: crystal structures and some cycloaddition reactions
- Synthesis, molecular structure and BSA-binding properties of a new binuclear Cd(II) complex based on 2-(1H-tetrazol-1-methyl)-1H-imidazole-4,5-dicarboxylic acid
- Microwave synthesis of a blue luminescent silver(I) coordination polymer with a rigid tris-triazole ligand
- Single-crystal structure determination of LaNi5–xInx and LaNi9–xIn2+x
- The reaction of imidazo[1,5-a]pyridines with ninhydrin revisited
- The syntheses, structures, and magnetic properties of two mononuclear manganese(II) complexes involving in situ hydrothermal decarboxylation
- A cobalt(II) coordination polymer constructed with the 2-carboxy-phenoxyacetate linker showing a corrugated layer structure: synthesis, structure analysis and magnetic properties
- Hexaniobate anions connected by [Ni(cyclam)]2+ complexes yield two interpenetrating three-dimensional networks
- High-pressure synthesis and crystal structure of the samarium meta-oxoborate γ-Sm(BO2)3
- High-pressure synthesis and characterization of the non-centrosymmetric scandium borate ScB6O9(OH)3
- Al5B12O25(OH) and Ga4InB12O25(OH) – two additional triel borates with the structure type M5B12O25(OH) (M = Ga, In)
- Al/N-based active Lewis pairs: isocyanate insertion products as efficient nucleophiles employed for the facile generation of highly functional molecules
- New compounds of the Li2MSn3S8 type
- Synthesis and magnetic properties of the extended RE4Pd9Al24 series (RE = Sc, Y, Ce–Nd, Sm, Gd–Lu)
- Solid solutions EuAu4Cd2−xMgx with a remarkably stable ferromagnetic ground state
- Mechanistic investigations on C–H activated dealkylating cyclo-amination reactions of substituted triazenes, formamidines and amidines
- Orthoamide und Iminiumsalze, IIC. Darstellung von N-(ω-Ammonioalkyl)-N,N′,N′,N″,N″-peralkylierten Guanidiniumsalzen und N-(ω-Aminoalkyl)-N′,N′,N″,N″-tetramethylguanidinen
- Orthoamide und Iminiumsalze, IC. Synthese und Reaktionen von N,N,N′,N′,N′′-Pentaalkyl-N′′-[2-(N,N,N′,N′,N′′-pentaalkylguanidinio)ethyl]-guanidiniumsalzen
- Orthoamide und Iminiumsalze, C. Vinyloge Guanidiniumsalz-basierte ionische Flüssigkeiten sowie phenyloge Guanidiniumsalze und Orthoamide
- Notes
- La5Ir1.73In4.27 with Lu5Ni2In4-type structure
- The scandium-rich indide Sc50Pt13.47In2.53
