Single-crystal structure determination of LaNi5–xInx and LaNi9–xIn2+x
-
Yaroslav Kalychak
,
Volodymyr Babizhetskyy
Abstract
The crystal structures of the solid solution LaNi5–xInx (x = 0.51) and the ternary compound LaNi9–xIn2+x (x = 0.80) have been investigated by single-crystal X-ray data. The LaNi5–xInx phase is isotypic with CaCu5: space group P6/mmm, a = 5.042(2), c = 4.009(1) Å. The crystal structure investigation of LaNi9–xIn2+x (x = 0.80) was performed at T = 295 and 100 K: YNi9In2 type, space group P4/mbm, a = 8.3976(3), c = 5.0439(3) Å for T = 295 K and a = 8.3814(2), c = 5.0352(2) Å for T = 100 K. The lanthanum atoms are located on split positions 2a (0 0 0) and 4e (0 0 0.05).
Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: None declared.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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Articles in the same Issue
- Frontmatter
- In this issue
- Research articles
- Derivatives of the triaminoguanidinium ion, 7: unsymmetrically substituted N,N',N''-triaminoguanidinium salts via a cyclopentanone spiroaminal intermediate
- Diethyl (iodoethynyl)phosphonate and (iodoethynyl)diphenylphosphane oxide: crystal structures and some cycloaddition reactions
- Synthesis, molecular structure and BSA-binding properties of a new binuclear Cd(II) complex based on 2-(1H-tetrazol-1-methyl)-1H-imidazole-4,5-dicarboxylic acid
- Microwave synthesis of a blue luminescent silver(I) coordination polymer with a rigid tris-triazole ligand
- Single-crystal structure determination of LaNi5–xInx and LaNi9–xIn2+x
- The reaction of imidazo[1,5-a]pyridines with ninhydrin revisited
- The syntheses, structures, and magnetic properties of two mononuclear manganese(II) complexes involving in situ hydrothermal decarboxylation
- A cobalt(II) coordination polymer constructed with the 2-carboxy-phenoxyacetate linker showing a corrugated layer structure: synthesis, structure analysis and magnetic properties
- Hexaniobate anions connected by [Ni(cyclam)]2+ complexes yield two interpenetrating three-dimensional networks
- High-pressure synthesis and crystal structure of the samarium meta-oxoborate γ-Sm(BO2)3
- High-pressure synthesis and characterization of the non-centrosymmetric scandium borate ScB6O9(OH)3
- Al5B12O25(OH) and Ga4InB12O25(OH) – two additional triel borates with the structure type M5B12O25(OH) (M = Ga, In)
- Al/N-based active Lewis pairs: isocyanate insertion products as efficient nucleophiles employed for the facile generation of highly functional molecules
- New compounds of the Li2MSn3S8 type
- Synthesis and magnetic properties of the extended RE4Pd9Al24 series (RE = Sc, Y, Ce–Nd, Sm, Gd–Lu)
- Solid solutions EuAu4Cd2−xMgx with a remarkably stable ferromagnetic ground state
- Mechanistic investigations on C–H activated dealkylating cyclo-amination reactions of substituted triazenes, formamidines and amidines
- Orthoamide und Iminiumsalze, IIC. Darstellung von N-(ω-Ammonioalkyl)-N,N′,N′,N″,N″-peralkylierten Guanidiniumsalzen und N-(ω-Aminoalkyl)-N′,N′,N″,N″-tetramethylguanidinen
- Orthoamide und Iminiumsalze, IC. Synthese und Reaktionen von N,N,N′,N′,N′′-Pentaalkyl-N′′-[2-(N,N,N′,N′,N′′-pentaalkylguanidinio)ethyl]-guanidiniumsalzen
- Orthoamide und Iminiumsalze, C. Vinyloge Guanidiniumsalz-basierte ionische Flüssigkeiten sowie phenyloge Guanidiniumsalze und Orthoamide
- Notes
- La5Ir1.73In4.27 with Lu5Ni2In4-type structure
- The scandium-rich indide Sc50Pt13.47In2.53
Articles in the same Issue
- Frontmatter
- In this issue
- Research articles
- Derivatives of the triaminoguanidinium ion, 7: unsymmetrically substituted N,N',N''-triaminoguanidinium salts via a cyclopentanone spiroaminal intermediate
- Diethyl (iodoethynyl)phosphonate and (iodoethynyl)diphenylphosphane oxide: crystal structures and some cycloaddition reactions
- Synthesis, molecular structure and BSA-binding properties of a new binuclear Cd(II) complex based on 2-(1H-tetrazol-1-methyl)-1H-imidazole-4,5-dicarboxylic acid
- Microwave synthesis of a blue luminescent silver(I) coordination polymer with a rigid tris-triazole ligand
- Single-crystal structure determination of LaNi5–xInx and LaNi9–xIn2+x
- The reaction of imidazo[1,5-a]pyridines with ninhydrin revisited
- The syntheses, structures, and magnetic properties of two mononuclear manganese(II) complexes involving in situ hydrothermal decarboxylation
- A cobalt(II) coordination polymer constructed with the 2-carboxy-phenoxyacetate linker showing a corrugated layer structure: synthesis, structure analysis and magnetic properties
- Hexaniobate anions connected by [Ni(cyclam)]2+ complexes yield two interpenetrating three-dimensional networks
- High-pressure synthesis and crystal structure of the samarium meta-oxoborate γ-Sm(BO2)3
- High-pressure synthesis and characterization of the non-centrosymmetric scandium borate ScB6O9(OH)3
- Al5B12O25(OH) and Ga4InB12O25(OH) – two additional triel borates with the structure type M5B12O25(OH) (M = Ga, In)
- Al/N-based active Lewis pairs: isocyanate insertion products as efficient nucleophiles employed for the facile generation of highly functional molecules
- New compounds of the Li2MSn3S8 type
- Synthesis and magnetic properties of the extended RE4Pd9Al24 series (RE = Sc, Y, Ce–Nd, Sm, Gd–Lu)
- Solid solutions EuAu4Cd2−xMgx with a remarkably stable ferromagnetic ground state
- Mechanistic investigations on C–H activated dealkylating cyclo-amination reactions of substituted triazenes, formamidines and amidines
- Orthoamide und Iminiumsalze, IIC. Darstellung von N-(ω-Ammonioalkyl)-N,N′,N′,N″,N″-peralkylierten Guanidiniumsalzen und N-(ω-Aminoalkyl)-N′,N′,N″,N″-tetramethylguanidinen
- Orthoamide und Iminiumsalze, IC. Synthese und Reaktionen von N,N,N′,N′,N′′-Pentaalkyl-N′′-[2-(N,N,N′,N′,N′′-pentaalkylguanidinio)ethyl]-guanidiniumsalzen
- Orthoamide und Iminiumsalze, C. Vinyloge Guanidiniumsalz-basierte ionische Flüssigkeiten sowie phenyloge Guanidiniumsalze und Orthoamide
- Notes
- La5Ir1.73In4.27 with Lu5Ni2In4-type structure
- The scandium-rich indide Sc50Pt13.47In2.53
