A new modification of [Ag4Br4(PPh3)4]: synthesis, structure and properties
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Xintong Han
Abstract
A new modification of the homometallic silver(I) cluster [Ag4Br4(PPh3)4] has been prepared and characterized by elemental analysis, UV/Vis and IR spectroscopy, and X-ray crystallography. The tetramer shows a polycyclic structure with a chair conformation. The bromine atoms adopt μ2- and μ3-bridging modes. The shortest Ag–Ag distance in the cluster is 3.159(2) Å, which indicates significant Ag–Ag interactions. A supramolecular structure is arranged by hydrogen bonds (C–H···Br). Cyclic voltammograms of the cluster indicate a quasi-reversible Ag+/Ag couple. The fluorescence properties of the ligand and the Ag(I) cluster were studied in the solid state. The emission peaks of the Ag(I) cluster are attributed to ligand-centered luminescence.
Acknowledgments
The present research was supported by the Foundation of a Hundred Youth Talents Training Program of Lanzhou Jiaotong University (Grant No. 152022), Natural Science Foundation of Gansu Province (Grant No. 17JR5RA090) and The Development of Instrument & Equipment Function and Technical Innovation Project of CAS (Grant No. 2018gl03).
References
[1] J. Chen, T. Teng, L. Kang, X. L. Chen, X. Y. Wu, R. M. Yu, C. Z. Lu, Inorg. Chem.2016, 55, 9528.10.1021/acs.inorgchem.6b00068Search in Google Scholar PubMed
[2] D. Kakizoe, M. Nishikawa, T. Degawa, T. Tsubomura, Inorg. Chem. Front.2016, 3, 1381.10.1039/C6QI00254DSearch in Google Scholar
[3] H. L. Wu, Y. H. Zhang, C. Y. Chen, J. W. Zhang, Y. C. Bai, F. R. Shi, X. L. Wang, New. J. Chem.2014, 38, 3688.10.1039/C4NJ00503ASearch in Google Scholar
[4] H. L. Wu, Z. H. Yang, C. Y. Chen, J. W. Zhang, H. Zhang, H. P. Peng, F. Wang, J. Coord. Chem.2016, 69, 1076.10.1080/00958972.2016.1145212Search in Google Scholar
[5] H. J. Du, W. L. Zhang, C. H. Wang, Y. Li, Y. Y. Niu, H. W. Hou, Inorg. Chem. Commun.2015, 54, 45.10.1016/j.inoche.2015.02.005Search in Google Scholar
[6] D. Li, X. Sun, N. Shao, G. Zhang, S. Li, H. P. Zhou, J. Y. Wu, Y. P. Tian, Polyhedron2015, 93, 17.10.1016/j.poly.2015.03.027Search in Google Scholar
[7] H. L. Wu, J. K. Yuan, Y. Bai, G. L. Pan, H. Wang, J. Kong, X. Y. Fan, H. M. Liu, Dalton Trans.2012, 41, 8829.10.1039/c2dt30512gSearch in Google Scholar PubMed
[8] S. Kulovi, S. Dalbera, S. Das, E. Zangrando, H. Puschmann, S. Dalai, ChemistrySelect2017, 2, 9029.10.1002/slct.201701697Search in Google Scholar
[9] J. Lee, Y. Kang, N. S. Cho, K. M. Park, Cryst. Growth Des.2016, 16, 996.10.1021/acs.cgd.5b01544Search in Google Scholar
[10] S. S. Mao, K. S. Shen, X. K. Shi, Y. L. Xu, H. L. Wu, Appl. Organomet. Chem.2017, 31, e3747.10.1002/aoc.3747Search in Google Scholar
[11] D. Sun, S. Yuan, H. Wang, H. F. Lu, S. Y. Feng, D. F. Sun, Chem. Commun.2013, 49, 6152.10.1039/c3cc42741bSearch in Google Scholar PubMed
[12] S. Khatua, S. Goswami, S. Biswas, K. Tomar, H. S. Jena, S. Konar, Chem. Mater.2015, 27, 5349.10.1021/acs.chemmater.5b01773Search in Google Scholar
[13] S. Roy, A. Baral, A. Banerjee, ACS Appl. Mater. Interfaces2014, 6, 4050.10.1021/am4055645Search in Google Scholar PubMed
[14] T. G. Schaaff, R. L. Whetten, J. Phys. Chem. B2000, 104, 2630.10.1021/jp993691ySearch in Google Scholar
[15] H. L. Wu, S. O. Aderinto, Y. L. Xu, H. Zhang, Z. H. Yang, J. Chem. Res.2016, 40, 492.10.3184/174751916X14665109046089Search in Google Scholar
[16] S. Perruchas, X. F. L. Goff, S. Maron, I. Maurin, F. Guillen, A. Garcia, T. Gacoin, J. P. Boilot, J. Am. Chem. Soc.2010, 132, 10967.10.1021/ja103431dSearch in Google Scholar PubMed
[17] H. L. Wu, F. Wang, F. R. Shi, Z. H. Yang, H, Zhang, H. P. Peng, Transition. Met. Chem.2015, 40, 555.10.1007/s11243-015-9948-8Search in Google Scholar
[18] R. Visbal, I. Ospino, J. M. Lópezdeluzuriaga, A. Laguna, M. C. Gimeno, J. Am. Chem. Soc.2013, 135, 4712.10.1021/ja401523xSearch in Google Scholar PubMed
[19] Y. L. Xu, H. L. Wu, H, Zhang, S. O. Aderinto, Z. H. Yang, J. Coord. Chem.2016, 69, 2988.10.1080/00958972.2016.1218484Search in Google Scholar
[20] S. S. Mao, H. Zhang, K. S. Shen, Y. L. Xu, X. K. Shi, H. L. Wu, Polyhedron2017, 134, 336.10.1016/j.poly.2017.06.042Search in Google Scholar
[21] A. Castineiras, R. Pedrido, Inorg. Chem.2009, 48, 4847.10.1021/ic900062ySearch in Google Scholar PubMed
[22] D. Sun, F. J. Liu, R. B. Huang, L. S. Zheng, Inorg. Chem.2011, 50, 12393.10.1021/ic201746qSearch in Google Scholar PubMed
[23] S. C. K. Hau, P. S. Cheng, T. C. W. Mak, J. Am. Chem. Soc.2012, 134, 2922.10.1021/ja211438qSearch in Google Scholar PubMed
[24] S. Igawa, M. Hashimoto, I. Kawata, M. Hoshino, M. Osawa, Inorg. Chem.2012, 51, 5805.10.1021/ic300333cSearch in Google Scholar PubMed
[25] S. Roy, H. M. Titi, B. K. Tripuramallu, N. Bhunia, R. Verma, I. Goldberg, Cryst. Growth Des.2016, 16, 2814.10.1021/acs.cgd.6b00151Search in Google Scholar
[26] D. J. Eisler, R. J. Puddephatt, Inorg. Chem.2006, 45, 7295.10.1021/ic060865zSearch in Google Scholar PubMed
[27] H. Zhang, Y. L. Xu, H. L. Wu, S. O. Aderinto, X. Y. Fan, RSC Adv.2016, 6, 83697.10.1039/C6RA09733BSearch in Google Scholar
[28] H. J. Hao, D. Sun, Y. H. Li, F. J. Liu, R. B. Huang, L. S. Zheng, Cryst. Growth Des.2011, 11, 3564.10.1021/cg200534xSearch in Google Scholar
[29] X. Tang, S. S. Mao, X. K. Shi, K. S. Shen, H. L. Wu, Z. Naturforsch.2017, 72b, 281.10.1515/znb-2016-0233Search in Google Scholar
[30] C. M. Che, M. C. Tse, M. C. W. Chan, K. K. Cheung, D. L. Phillips, K. H. Leung, J. Am. Chem. Soc.2000, 122, 2464.10.1021/ja9904890Search in Google Scholar
[31] O. S. Jung, Y. J. Kim, Y. Lee, S. W. K. And, S. N. Choi, Crystal Growth Des.2004, 4, 23.10.1021/cg0341048Search in Google Scholar
[32] Smart, Saint, Sadabs, Bruker AXS Inc., Madison, WI (USA) 2000.Search in Google Scholar
[33] G. M. Sheldrick, Shelxtl, Siemens Analytical X-ray Instruments Inc., Madison, WI (USA) 1996.Search in Google Scholar
[34] Y. Q. Wei, K. C. Wu, B. T. Zhuang, Z. F. Zhou, M. X. Zhang, C. P. Liu, Z. Anorg. Allg. Chem.2005, 631, 1532.10.1002/zaac.200400524Search in Google Scholar
[35] H. L. Wu, Z. H. Yang, F. Wang, H. Zhang, H. P. Peng, C. P. Wang, Res. Chem. Intermed.2016, 42, 2473.10.1007/s11164-015-2162-7Search in Google Scholar
[36] H. L. Wu, Y. H. Zhang, H. Wang, Y. C. Bai, F. R. Shi, X. L. Wang, Z. H. Yang, J. Coord. Chem.2014, 67, 1771.10.1080/00958972.2014.917632Search in Google Scholar
[37] H. L. Wu, J. W. Zhang, C. Y. Chen, H. Zhang, H. P. Peng, F. Wang, Z. H. Yang, New J. Chem.2015, 39, 7172.10.1039/C5NJ01684CSearch in Google Scholar
[38] W. K. Dong, J. C. Ma, Y. J. Dong, L. C. Zhu, Y. Zhang, Polyhedron2016, 115, 228.10.1016/j.poly.2016.05.017Search in Google Scholar
[39] G. L. Pan, Y. C. Bai, H. Wang, J. Kong, F. R. Shi, Y. H. Zhang, X. L. Wang, H. L. Wu, Z. Naturforsch.2013, 68b, 257.10.5560/znb.2013-2339Search in Google Scholar
[40] X. Q. Song, P. P. Liu, Y. A. Liu, J. J. Zhou, X. L. Wang, Dalton Trans.2016, 45, 8154.10.1039/C6DT00212ASearch in Google Scholar PubMed
[41] L. Yang, D. R. Powell, R. P. Houser, Dalton Trans.2007, 9, 955.10.1039/B617136BSearch in Google Scholar PubMed
[42] B.-K. Teo, J. C. Calabrese, Inorg. Chem.1976, 15, 2474.10.1021/ic50164a032Search in Google Scholar
[43] B.-K. Teo, J. C. Calabrese, J. Am. Chem. Soc.1975, 97, 1256.10.1021/ja00838a057Search in Google Scholar
[44] G. J. S. Venter, A. Roodt, R. Meijboom, Inorg. Chim. Acta2009, 362, 2475.10.1016/j.ica.2008.11.004Search in Google Scholar
[45] B.-K. Teo, J. C. Calabrese, Inorg. Chem.1976, 15, 2467.10.1021/ic50164a031Search in Google Scholar
[46] Y. A. Wanniarachchi, M. A. Khan, L. M. Slaughter, Organometallics2004, 23, 5881.10.1021/om0493098Search in Google Scholar
[47] B.-K. Teo, J. C. Calabrese, J. Chem. Soc., Chem. Commun.1976, 185.10.1039/C39760000185Search in Google Scholar
[48] F. Chen, S. W. Oh, R. E. Wasylishen, Can. J. Chem.2009, 87, 1090.10.1139/V09-076Search in Google Scholar
[49] D. Zhang, S. Zhou, Z. M. Li, Q. R. Wang, L. H. Weng, Dalton Trans.2013, 42, 12020.10.1039/c3dt50957eSearch in Google Scholar PubMed
[50] G. A. Bowmaker, Effendy, R. D. Hart, J. D. Kildea, A. H. White, Aust. J. Chem.1997, 50, 653.10.1071/C96039Search in Google Scholar
[51] Y. Song, R. Q. Fan, S. Gao, X. M. Wang, P. Wang, Y. L. Yang, Y. L. Wang, Inorg. Chem. Commun.2015, 53, 34.10.1016/j.inoche.2015.01.004Search in Google Scholar
[52] Z. P. Deng, Z. B. Zhu, S. Gao, L. H. Huo, H. Zhao, S. W. Ng, Dalton Trans.2009, 6552.10.1039/b907389bSearch in Google Scholar PubMed
[53] L. Valencia, R. Bastida, A. Macas, M. Vicentea, P. Perez-Louridob, New J. Chem.2005, 29, 424.10.1039/B416342GSearch in Google Scholar
[54] Q. X. Liu, Q. Wei, R. Liu, X. J. Zhao, Z. X. Zhao, RSC Adv.2015, 5, 28435.10.1039/C4RA14340JSearch in Google Scholar
[55] J. Huang, Z. P. Deng, Y. H. Xiao, L. H. Huo, S. N. Zhao, F. Y. Ge, S. Gao, Dalton Trans.2015, 44, 5837.10.1039/C5DT00265FSearch in Google Scholar PubMed
[56] L. Q. Chai, J. Y. Zhang, L. C. Chen, Y. X. Li, L. J. Tang, Res. Chem. Intermed.2016, 42, 3473.10.1007/s11164-015-2226-8Search in Google Scholar
[57] H. L. Wu, H. P. Peng, Y. H. Zhang, F. Wang, H. Zhang, C. P. Wang, Z. H. Yang, Appl. Organomet. Chem.2015, 29, 44.Search in Google Scholar
[58] H. L. Wu, Y. H. Zhang, J. W. Zhang, Z. H. Yang, C. Y. Chen, H. P. Peng, F. Wang, Transition. Met. Chem.2015, 40, 145.10.1007/s11243-014-9900-3Search in Google Scholar
[59] L. Q. Chai, L. J, Tang, L. C. Chen, J. J. Huang, Polyhedron2017, 122, 228.10.1016/j.poly.2016.11.032Search in Google Scholar
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Articles in the same Issue
- Frontmatter
- In this Issue
- Analysis of two [2]catenanes based on electron densities from invariom refinement and results from DFT calculations
- Orthoamide und Iminiumsalze, XCVa. Umsetzungen von Orthoamiden von Alkin-Carbonsäuren mit Acetophenonen und Acetophenon-Phenylhydrazonen
- Metal-free, air-promoted, radical-mediated arylation of benzoquinone with phenylhydrazines
- Three-component condensation reaction of various aldehydes, dimedone and malononitrile catalyzed by boric acid in water in comparison with multifunctional ionic liquids as green catalytic systems
- Synthesis, characterization, and electrochemical study of a mononuclear Cu(II) complex with a 4-acyl pyrazolone ligand
- Synthesis of LaCoO3 powder by a combined mechanical/thermal process
- Preparation and molecular structures of N′-(2-heteroarylmethylidene)-3-(3-pyridyl)acrylohydrazides
- A new modification of [Ag4Br4(PPh3)4]: synthesis, structure and properties
- Magnetic and magnetocaloric properties of the coloured Heusler phases GdAg2Mg and REAgAuMg (RE=Gd, Tb, Dy)
