A Zn(II) complex from an imidazolyl-thiophene ligand: synthesis, structural characterization, and fluorescence
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Abstract
The hydrothermal reaction of ZnSO4 with 2,5-di(1H-imidazol-4-yl)thiophene (L) at 100°C yields a new complex [Zn(L)(SO4)]n (1). Complex 1 has been characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental and thermogravimetric analyses. It crystallizes in the monoclinic system, space group P21/c with Z=4, and shows a (44.62) network structure. Complex 1 shows fluorescence. Single crystals of L·2H2O were accidentally obtained in hydrothermal reaction attempts of L with MnCl2 at 120°C.
Acknowledgments
The authors gratefully acknowledge Natural Science Foundation for Universities in Jiangsu Province (16KJB150005) and Huaiyin Institute of Technology (15HGZ006 and 491713325) for financial support of this work.
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Articles in the same Issue
- Frontmatter
- In this Issue
- Influence of different metal ions on the assembly, structures, and properties of two complexes based on the semi-rigid bis(pyridyl)-bis(amide) ligand and 4,4′-oxybis(benzoic acid)
- Structural, spectral and docking studies of a coordination polymer of zinc(II) formed by a pyridine-derived linker
- The isolation and structural elucidation of a new iridoid glycoside from Cymbaria dahurica L.
- Two new alkylresorcinol derivatives from the leaves of Scyphocephalium ochocoa
- Synthesis and antimicrobial evaluation of some heterocyclic compounds from 3-aryl-1-phenyl-1H-pyrazole-4-carbaldehydes
- Studying the reactivity of N-2-(2-aminobenzoyl)-N-phenyl-hydrazinecarbothioamide toward some selected carbonyl compounds
- A Zn(II) complex from an imidazolyl-thiophene ligand: synthesis, structural characterization, and fluorescence
- A study on the reaction of 3-alkyl(aryl)imidazo[1,5-a]pyridines with ninhydrin
- Synthesis, structural characterization, and properties of Ag(I) complexes with N-donor ligands
