Synthesis, structural characterization, and properties of Ag(I) complexes with N-donor ligands
-
Xiao-Hong Zhu
,
Xiao-Chun Cheng
Abstract
New silver complex [Ag(pz)(CF3SO3)] (1) was formed by the coordination reaction of AgCF3SO3 with pyrazine (pz) in the presence of 2-[(S)-4-isopropyl-2-oxazolyl] quinoline (L). When AgBF4 was used instead of AgCF3SO3 as the starting material, complex 2 [Ag(L)(CH3CN)](BF4) was obtained. Complexes 1 and 2 are characterized by single-crystal X-ray diffraction, IR spectroscopy and elemental, and thermogravimetric analysis. Complex 1 shows a 3D framework structure with uni-nodal eight-connected (424.64) topology while complex 2 displays a discrete mononuclear structure. The nonlinear optical properties of 2 were investigated.
Acknowledgments
The authors gratefully acknowledge the Natural Science Foundation for Universities in Jiangsu Province (16KJB150005) and Huaiyin Institute of Technology (15HGZ006 and 491713325) for financial support of this work.
References
[1] J. Li, S. Chen, L. Y. Jiang, Y. S. Li, B. Li, Cryst. Growth Des. 2018, 18, 1931.10.1021/acs.cgd.7b01701Search in Google Scholar
[2] T. R. Cook, Y. R. Zheng, P. J. Stang, Chem. Rev. 2013, 113, 734.10.1021/cr3002824Search in Google Scholar PubMed PubMed Central
[3] M. Hardy, N. Struch, F. Topić, G. Schnakenburg, K. Rissanen, A. Lützen, Inorg. Chem. 2018, 57, 3507.10.1021/acs.inorgchem.7b02516Search in Google Scholar PubMed
[4] H. W. Kuai, G. C. Lv, C. Hou, W. Y. Sun, J. Solid State Chem. 2015, 223, 2.10.1016/j.jssc.2014.02.028Search in Google Scholar
[5] Y. Zhang, M. S. Sigman, J. Am. Chem. Soc. 2007, 129, 3076.10.1021/ja070263uSearch in Google Scholar PubMed
[6] H. W. Kuai, X. C. Cheng, D. H. Li, T. Hu, X. H. Zhu, J. Solid State Chem. 2015, 228, 65.10.1016/j.jssc.2015.04.021Search in Google Scholar
[7] H. W. Kuai, J. J. Xia, H. Y. Sang, Inorg. Chem. Commun. 2016, 72, 73.10.1016/j.inoche.2016.08.011Search in Google Scholar
[8] V. A. Blatov, IU Cr. Comp. Comm. Newsletter2006, 7, 4.Search in Google Scholar
[9] S. Z. Hu, Z. H. Zhou, K. R. Tsai, Acta Phys. Chim. Sin. 2003, 19, 1073.10.3866/PKU.WHXB20031118Search in Google Scholar
[10] Z. Su, Z. S. Bai, J. Xu, T. A. Okamura, G. X. Liu, Q. Chu, X. F. Wang, W. Y. Sun, N. Ueyama, Cryst. Eng. Commun.2009, 11, 873.10.1039/b822394gSearch in Google Scholar
[11] Saint, Program for Data Extraction and Reduction, Bruker AXS, Inc., Madison, Wisconsin (USA) 2001.Search in Google Scholar
[12] G. M. Sheldrick, Sadabs, Program for Bruker Area Detector Absorption Correction, University of Göttingen, Göttingen (Germany) 1997.Search in Google Scholar
[13] G. M. Sheldrick, Shelxs/l-97, Programs for the Determination of Crystal Structures, University of Göttingen, Göttingen (Germany) 1997.Search in Google Scholar
[14] G. M. Sheldrick, Acta Crystallogr. 1990, A46, 467.10.1107/S0108767390000277Search in Google Scholar
[15] G. M. Sheldrick, Acta Crystallogr. 2008, A64, 112.10.1107/S0108767307043930Search in Google Scholar PubMed
©2018 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- In this Issue
- Influence of different metal ions on the assembly, structures, and properties of two complexes based on the semi-rigid bis(pyridyl)-bis(amide) ligand and 4,4′-oxybis(benzoic acid)
- Structural, spectral and docking studies of a coordination polymer of zinc(II) formed by a pyridine-derived linker
- The isolation and structural elucidation of a new iridoid glycoside from Cymbaria dahurica L.
- Two new alkylresorcinol derivatives from the leaves of Scyphocephalium ochocoa
- Synthesis and antimicrobial evaluation of some heterocyclic compounds from 3-aryl-1-phenyl-1H-pyrazole-4-carbaldehydes
- Studying the reactivity of N-2-(2-aminobenzoyl)-N-phenyl-hydrazinecarbothioamide toward some selected carbonyl compounds
- A Zn(II) complex from an imidazolyl-thiophene ligand: synthesis, structural characterization, and fluorescence
- A study on the reaction of 3-alkyl(aryl)imidazo[1,5-a]pyridines with ninhydrin
- Synthesis, structural characterization, and properties of Ag(I) complexes with N-donor ligands
Articles in the same Issue
- Frontmatter
- In this Issue
- Influence of different metal ions on the assembly, structures, and properties of two complexes based on the semi-rigid bis(pyridyl)-bis(amide) ligand and 4,4′-oxybis(benzoic acid)
- Structural, spectral and docking studies of a coordination polymer of zinc(II) formed by a pyridine-derived linker
- The isolation and structural elucidation of a new iridoid glycoside from Cymbaria dahurica L.
- Two new alkylresorcinol derivatives from the leaves of Scyphocephalium ochocoa
- Synthesis and antimicrobial evaluation of some heterocyclic compounds from 3-aryl-1-phenyl-1H-pyrazole-4-carbaldehydes
- Studying the reactivity of N-2-(2-aminobenzoyl)-N-phenyl-hydrazinecarbothioamide toward some selected carbonyl compounds
- A Zn(II) complex from an imidazolyl-thiophene ligand: synthesis, structural characterization, and fluorescence
- A study on the reaction of 3-alkyl(aryl)imidazo[1,5-a]pyridines with ninhydrin
- Synthesis, structural characterization, and properties of Ag(I) complexes with N-donor ligands
