Influence of different metal ions on the assembly, structures, and properties of two complexes based on the semi-rigid bis(pyridyl)-bis(amide) ligand and 4,4′-oxybis(benzoic acid)
-
Hong-Yan Lin
,
Yuan Tian
Abstract
Two transitional metal complexes, [Zn(oba)(3-bpcd)]n (1) and [Cd(oba)(3-bpcd)0.5]n (2) [H2oba= 4,4′-oxybis(benzoic acid), 3-bpcd=N,N′-bis(pyridin-3-yl)cyclohexane-1,4-dicarboxamide], have been hydrothermally synthesized and structurally characterized by elemental analyses, infrared spectra, powder X-ray diffraction, thermogravimetric and single-crystal X-ray diffraction. Complex 1 possesses a three-fold interpenetrating network based on layers with a 4-connected sql topology. Complex 2 is a layered framework constructed by the oba anions and 3-bpcd ligands, which represents a binodal (3,4)-connected {62.10}{6} topology. The adjacent layers of complex 2 are further linked by hydrogen bonding interactions to build a three-dimensional supramolecular architecture. The differences of metal ions in coordination modes show a significant effect on the final structures of the Zn(II)/Cd(II) complexes. The photocatalytic activities and the fluorescence sensing properties of complexes 1 and 2 were investigated.
Acknowledgments
The support of the National Natural Science Foundation of China (Nos. 21501013, 21401010) and Program for Distinguished Professor of Liaoning Province (No. 2015399) are gratefully acknowledged.
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Supplementary Material:
The online version of this article offers supplementary material (https://doi.org/10.1515/znb-2017-0163).
©2018 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- In this Issue
- Influence of different metal ions on the assembly, structures, and properties of two complexes based on the semi-rigid bis(pyridyl)-bis(amide) ligand and 4,4′-oxybis(benzoic acid)
- Structural, spectral and docking studies of a coordination polymer of zinc(II) formed by a pyridine-derived linker
- The isolation and structural elucidation of a new iridoid glycoside from Cymbaria dahurica L.
- Two new alkylresorcinol derivatives from the leaves of Scyphocephalium ochocoa
- Synthesis and antimicrobial evaluation of some heterocyclic compounds from 3-aryl-1-phenyl-1H-pyrazole-4-carbaldehydes
- Studying the reactivity of N-2-(2-aminobenzoyl)-N-phenyl-hydrazinecarbothioamide toward some selected carbonyl compounds
- A Zn(II) complex from an imidazolyl-thiophene ligand: synthesis, structural characterization, and fluorescence
- A study on the reaction of 3-alkyl(aryl)imidazo[1,5-a]pyridines with ninhydrin
- Synthesis, structural characterization, and properties of Ag(I) complexes with N-donor ligands
Articles in the same Issue
- Frontmatter
- In this Issue
- Influence of different metal ions on the assembly, structures, and properties of two complexes based on the semi-rigid bis(pyridyl)-bis(amide) ligand and 4,4′-oxybis(benzoic acid)
- Structural, spectral and docking studies of a coordination polymer of zinc(II) formed by a pyridine-derived linker
- The isolation and structural elucidation of a new iridoid glycoside from Cymbaria dahurica L.
- Two new alkylresorcinol derivatives from the leaves of Scyphocephalium ochocoa
- Synthesis and antimicrobial evaluation of some heterocyclic compounds from 3-aryl-1-phenyl-1H-pyrazole-4-carbaldehydes
- Studying the reactivity of N-2-(2-aminobenzoyl)-N-phenyl-hydrazinecarbothioamide toward some selected carbonyl compounds
- A Zn(II) complex from an imidazolyl-thiophene ligand: synthesis, structural characterization, and fluorescence
- A study on the reaction of 3-alkyl(aryl)imidazo[1,5-a]pyridines with ninhydrin
- Synthesis, structural characterization, and properties of Ag(I) complexes with N-donor ligands
