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Synthesis and Structure of a Tetranuclear Nickel Complex of a 40-Membered Macrocyclic Octaamine-Tetrathiophenolate Ligand

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Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 55 Issue 10

Abstract

The syntheses and characterization of tetranuclear Ni complexes [(L2)Ni4][ClO4]4 (3) and [(L2)Ni4(NCS)4] (4) of a 40-membered macrocyclic octaamine-tetrathiophenolate ligand (L2)4- are described. Single-crystal X-ray structure analysis of 4 reveals well-separated molecules of the tetranuclear isothiocyanate complex [(L2) NiII4(NCS)4]. The four NiII centers are arranged in binuclear [N2Ni(μ2-SR)2NiN2(NCS)2] subunits containing distorted square-planar NiN2S2 and distorted octahedral NiN2S2(NCS)2 sites. The fact that the two isothiocyanate groups at the octahedral Ni site are in trans positions can be ascribed to the large ring size of the macrocycle

: Macrocyclic Ligands; Thiolate Ligand; Polynuclear Complexes
Received: 2000-7-7
Published Online: 2014-6-2
Published in Print: 2000-10-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Gold Clustering at Dimethylsulfoximine Me2S(O)NH
  2. Polylithiation of Small Molecules. Synthesis and Structure of the Functional Lithium Phosphide [Li(TMEDA)]2[PhPCMe2 C5H4]
  3. Synthese und Kristallstrukturbestimmung von Silicium-Komplexen der Koordinationszahl sechs mit Dimethylpyridinen/ Syntheses and Crystal Structure Determination of Hexacoordinated Silicon-Complexes with Dimethylpyridines
  4. Synthese und Kristallstruktur von (Ph3PAu)4[AuMn(CO)5]2 und (Ph3PAu)3Re(CO)4/ Synthesis and Crystal Structure of (Ph3PAu)4 [AuMn(CO)5]2 and (Ph3PAu)3Re(CO)4
  5. Silylfurane und Bis(silyl)butadiine -Synthese, Lithiumderivate, Kristallstrukturen/ Silylfurans and Bis(silyl)butadiynes - Synthesis, Lithium Derivatives, Crystal Structures
  6. Reaktionen der Lithiumhydridosilylamide Me2(H)Si-N(Li)R (R = CMe3, SiMe3) mit Chlortrimethylstannan und Chlormethylsilanen Me4–nSiCln (n = 1-3)/ Reactions of Lithium Hydridosilylamides Me2(H)Si-N(Li)R (R = CMe3, SiMe3) with Chlorotrimethylstannane and Chloromethylsilanes Me4-nSiCln (n = 1 - 3)
  7. The Madelung Function of Elpasolites
  8. Tri(Terf-Butyl)plumbyl-phosphanes, Synthesis and Multinuclear Magnetic Resonance
  9. Metallkomplexe von biologisch wichtigen Liganden, CXXIX [1]. Palladium(II)-und Platin(II)-Komplexe von 4,4-disubstituierten Oxazolonen und C2-symmetrischen Bis(oxazolonen) Metal Complexes of Biologically Important Ligands, CXXIX [1]. Palladium(II) and Platinum(II) Complexes of 4,4-Disubstituted Oxazolones and of C2-Symmetric Bis(oxazolones)
  10. Diorgano(trichlorsiIyl)phosphane/ Diorgano(trichlorosilyl)phosphines
  11. Synthese und Komplexierung Phosphorylierter spacer-modifizierter Glucosederivate/ Synthesis and Complexation of Spacer Modified Phosphorylated Glucose Derivatives
  12. Synthesis and Structure of a Tetranuclear Nickel Complex of a 40-Membered Macrocyclic Octaamine-Tetrathiophenolate Ligand
  13. Preparation and Crystal Structure of a Mixed Metal Assembly [Ni(phen)3][Cu(H-1pap)]2(NO3) · 8 H2O Featuring Octahedral Cationic and Square-planar Anionic Modules
  14. Kristallstrukturen der Komplexe Von Quecksilber(Ii)Iodid und -Thiocyanat mit L,13-Bis(8-Chinolyl)-L,4,7,10,13-Pentaoxatridecan („Kryptand 5“)
  15. Synthesis, Complex Formation and Spectral Investigation of New Tritopic Bis(Crown Ether) Compounds Containing Recognition Sites for Sodium and Nickel Guest Cations*
  16. Long Chain Cinnamoic Acid Esters from Daphne Oleoides
  17. One-Pot Preparation of O-Xylylene Diamine and its Related Amines
  18. Notizen: Ca{Li2[Mn'N]2}: Kristallchemischer Brückenschlag Zwischen Lithium-Nitrido-Verbindungen und Borid-Carbiden des Typs M [B2C2]/ Ca{Li2[M nIN]2}: Link between Crystal Chemistry of Lithium Nitrido Compounds and Boride Carbides of the Type M [B2C2]
  19. N -Methoxyalkyl-Funktionalisierte α-Diketodiimide/ N -Methoxyalkyl Functionalized α-Diketodiimides
https://doi.org/10.1515/znb-2000-1012

Articles in the same Issue

  1. Gold Clustering at Dimethylsulfoximine Me2S(O)NH
  2. Polylithiation of Small Molecules. Synthesis and Structure of the Functional Lithium Phosphide [Li(TMEDA)]2[PhPCMe2 C5H4]
  3. Synthese und Kristallstrukturbestimmung von Silicium-Komplexen der Koordinationszahl sechs mit Dimethylpyridinen/ Syntheses and Crystal Structure Determination of Hexacoordinated Silicon-Complexes with Dimethylpyridines
  4. Synthese und Kristallstruktur von (Ph3PAu)4[AuMn(CO)5]2 und (Ph3PAu)3Re(CO)4/ Synthesis and Crystal Structure of (Ph3PAu)4 [AuMn(CO)5]2 and (Ph3PAu)3Re(CO)4
  5. Silylfurane und Bis(silyl)butadiine -Synthese, Lithiumderivate, Kristallstrukturen/ Silylfurans and Bis(silyl)butadiynes - Synthesis, Lithium Derivatives, Crystal Structures
  6. Reaktionen der Lithiumhydridosilylamide Me2(H)Si-N(Li)R (R = CMe3, SiMe3) mit Chlortrimethylstannan und Chlormethylsilanen Me4–nSiCln (n = 1-3)/ Reactions of Lithium Hydridosilylamides Me2(H)Si-N(Li)R (R = CMe3, SiMe3) with Chlorotrimethylstannane and Chloromethylsilanes Me4-nSiCln (n = 1 - 3)
  7. The Madelung Function of Elpasolites
  8. Tri(Terf-Butyl)plumbyl-phosphanes, Synthesis and Multinuclear Magnetic Resonance
  9. Metallkomplexe von biologisch wichtigen Liganden, CXXIX [1]. Palladium(II)-und Platin(II)-Komplexe von 4,4-disubstituierten Oxazolonen und C2-symmetrischen Bis(oxazolonen) Metal Complexes of Biologically Important Ligands, CXXIX [1]. Palladium(II) and Platinum(II) Complexes of 4,4-Disubstituted Oxazolones and of C2-Symmetric Bis(oxazolones)
  10. Diorgano(trichlorsiIyl)phosphane/ Diorgano(trichlorosilyl)phosphines
  11. Synthese und Komplexierung Phosphorylierter spacer-modifizierter Glucosederivate/ Synthesis and Complexation of Spacer Modified Phosphorylated Glucose Derivatives
  12. Synthesis and Structure of a Tetranuclear Nickel Complex of a 40-Membered Macrocyclic Octaamine-Tetrathiophenolate Ligand
  13. Preparation and Crystal Structure of a Mixed Metal Assembly [Ni(phen)3][Cu(H-1pap)]2(NO3) · 8 H2O Featuring Octahedral Cationic and Square-planar Anionic Modules
  14. Kristallstrukturen der Komplexe Von Quecksilber(Ii)Iodid und -Thiocyanat mit L,13-Bis(8-Chinolyl)-L,4,7,10,13-Pentaoxatridecan („Kryptand 5“)
  15. Synthesis, Complex Formation and Spectral Investigation of New Tritopic Bis(Crown Ether) Compounds Containing Recognition Sites for Sodium and Nickel Guest Cations*
  16. Long Chain Cinnamoic Acid Esters from Daphne Oleoides
  17. One-Pot Preparation of O-Xylylene Diamine and its Related Amines
  18. Notizen: Ca{Li2[Mn'N]2}: Kristallchemischer Brückenschlag Zwischen Lithium-Nitrido-Verbindungen und Borid-Carbiden des Typs M [B2C2]/ Ca{Li2[M nIN]2}: Link between Crystal Chemistry of Lithium Nitrido Compounds and Boride Carbides of the Type M [B2C2]
  19. N -Methoxyalkyl-Funktionalisierte α-Diketodiimide/ N -Methoxyalkyl Functionalized α-Diketodiimides
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