Home Notizen: Ca{Li2[Mn'N]2}: Kristallchemischer Brückenschlag Zwischen Lithium-Nitrido-Verbindungen und Borid-Carbiden des Typs M [B2C2]/ Ca{Li2[M nIN]2}: Link between Crystal Chemistry of Lithium Nitrido Compounds and Boride Carbides of the Type M [B2C2]
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Notizen: Ca{Li2[Mn'N]2}: Kristallchemischer Brückenschlag Zwischen Lithium-Nitrido-Verbindungen und Borid-Carbiden des Typs M [B2C2]/ Ca{Li2[M nIN]2}: Link between Crystal Chemistry of Lithium Nitrido Compounds and Boride Carbides of the Type M [B2C2]

  • Jens Klatyk , Rainer Niewa and Rüdiger Kniep EMAIL logo
Published/Copyright: June 2, 2014
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Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 55 Issue 10

Abstract

The nitridom anganate(I) Ca{Li2[MnIN]2) (space group P4/mbm: a = 703.35(7), c = 383.19(6) pm; Z = 2) contains infinite linear chains 1∞=[MnIN2/22-] running along the [001] direction. The nitride species of the chains are further linked via three coordinated lithium to form planar 4.82-nets 2∞{Li2N24-} parallel (001). Ca2+ occupies the centers of the eight-membered rings of the planar nets. The 4.82-arrangement 2∞{Li2N24-} together with the stacking sequence ...AA... along [001] exhibit strong topological similarities with the anionic substructure 2∞[B2C22-] observed in the crystal structure of e.g. Ce[B2C2]

: Borid-Carbide; Nitridometallate; Niedervalente Verbindungen
Received: 2000-7-27
Published Online: 2014-6-2
Published in Print: 2000-10-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Gold Clustering at Dimethylsulfoximine Me2S(O)NH
  2. Polylithiation of Small Molecules. Synthesis and Structure of the Functional Lithium Phosphide [Li(TMEDA)]2[PhPCMe2 C5H4]
  3. Synthese und Kristallstrukturbestimmung von Silicium-Komplexen der Koordinationszahl sechs mit Dimethylpyridinen/ Syntheses and Crystal Structure Determination of Hexacoordinated Silicon-Complexes with Dimethylpyridines
  4. Synthese und Kristallstruktur von (Ph3PAu)4[AuMn(CO)5]2 und (Ph3PAu)3Re(CO)4/ Synthesis and Crystal Structure of (Ph3PAu)4 [AuMn(CO)5]2 and (Ph3PAu)3Re(CO)4
  5. Silylfurane und Bis(silyl)butadiine -Synthese, Lithiumderivate, Kristallstrukturen/ Silylfurans and Bis(silyl)butadiynes - Synthesis, Lithium Derivatives, Crystal Structures
  6. Reaktionen der Lithiumhydridosilylamide Me2(H)Si-N(Li)R (R = CMe3, SiMe3) mit Chlortrimethylstannan und Chlormethylsilanen Me4–nSiCln (n = 1-3)/ Reactions of Lithium Hydridosilylamides Me2(H)Si-N(Li)R (R = CMe3, SiMe3) with Chlorotrimethylstannane and Chloromethylsilanes Me4-nSiCln (n = 1 - 3)
  7. The Madelung Function of Elpasolites
  8. Tri(Terf-Butyl)plumbyl-phosphanes, Synthesis and Multinuclear Magnetic Resonance
  9. Metallkomplexe von biologisch wichtigen Liganden, CXXIX [1]. Palladium(II)-und Platin(II)-Komplexe von 4,4-disubstituierten Oxazolonen und C2-symmetrischen Bis(oxazolonen) Metal Complexes of Biologically Important Ligands, CXXIX [1]. Palladium(II) and Platinum(II) Complexes of 4,4-Disubstituted Oxazolones and of C2-Symmetric Bis(oxazolones)
  10. Diorgano(trichlorsiIyl)phosphane/ Diorgano(trichlorosilyl)phosphines
  11. Synthese und Komplexierung Phosphorylierter spacer-modifizierter Glucosederivate/ Synthesis and Complexation of Spacer Modified Phosphorylated Glucose Derivatives
  12. Synthesis and Structure of a Tetranuclear Nickel Complex of a 40-Membered Macrocyclic Octaamine-Tetrathiophenolate Ligand
  13. Preparation and Crystal Structure of a Mixed Metal Assembly [Ni(phen)3][Cu(H-1pap)]2(NO3) · 8 H2O Featuring Octahedral Cationic and Square-planar Anionic Modules
  14. Kristallstrukturen der Komplexe Von Quecksilber(Ii)Iodid und -Thiocyanat mit L,13-Bis(8-Chinolyl)-L,4,7,10,13-Pentaoxatridecan („Kryptand 5“)
  15. Synthesis, Complex Formation and Spectral Investigation of New Tritopic Bis(Crown Ether) Compounds Containing Recognition Sites for Sodium and Nickel Guest Cations*
  16. Long Chain Cinnamoic Acid Esters from Daphne Oleoides
  17. One-Pot Preparation of O-Xylylene Diamine and its Related Amines
  18. Notizen: Ca{Li2[Mn'N]2}: Kristallchemischer Brückenschlag Zwischen Lithium-Nitrido-Verbindungen und Borid-Carbiden des Typs M [B2C2]/ Ca{Li2[M nIN]2}: Link between Crystal Chemistry of Lithium Nitrido Compounds and Boride Carbides of the Type M [B2C2]
  19. N -Methoxyalkyl-Funktionalisierte α-Diketodiimide/ N -Methoxyalkyl Functionalized α-Diketodiimides
https://doi.org/10.1515/znb-2000-1018

Articles in the same Issue

  1. Gold Clustering at Dimethylsulfoximine Me2S(O)NH
  2. Polylithiation of Small Molecules. Synthesis and Structure of the Functional Lithium Phosphide [Li(TMEDA)]2[PhPCMe2 C5H4]
  3. Synthese und Kristallstrukturbestimmung von Silicium-Komplexen der Koordinationszahl sechs mit Dimethylpyridinen/ Syntheses and Crystal Structure Determination of Hexacoordinated Silicon-Complexes with Dimethylpyridines
  4. Synthese und Kristallstruktur von (Ph3PAu)4[AuMn(CO)5]2 und (Ph3PAu)3Re(CO)4/ Synthesis and Crystal Structure of (Ph3PAu)4 [AuMn(CO)5]2 and (Ph3PAu)3Re(CO)4
  5. Silylfurane und Bis(silyl)butadiine -Synthese, Lithiumderivate, Kristallstrukturen/ Silylfurans and Bis(silyl)butadiynes - Synthesis, Lithium Derivatives, Crystal Structures
  6. Reaktionen der Lithiumhydridosilylamide Me2(H)Si-N(Li)R (R = CMe3, SiMe3) mit Chlortrimethylstannan und Chlormethylsilanen Me4–nSiCln (n = 1-3)/ Reactions of Lithium Hydridosilylamides Me2(H)Si-N(Li)R (R = CMe3, SiMe3) with Chlorotrimethylstannane and Chloromethylsilanes Me4-nSiCln (n = 1 - 3)
  7. The Madelung Function of Elpasolites
  8. Tri(Terf-Butyl)plumbyl-phosphanes, Synthesis and Multinuclear Magnetic Resonance
  9. Metallkomplexe von biologisch wichtigen Liganden, CXXIX [1]. Palladium(II)-und Platin(II)-Komplexe von 4,4-disubstituierten Oxazolonen und C2-symmetrischen Bis(oxazolonen) Metal Complexes of Biologically Important Ligands, CXXIX [1]. Palladium(II) and Platinum(II) Complexes of 4,4-Disubstituted Oxazolones and of C2-Symmetric Bis(oxazolones)
  10. Diorgano(trichlorsiIyl)phosphane/ Diorgano(trichlorosilyl)phosphines
  11. Synthese und Komplexierung Phosphorylierter spacer-modifizierter Glucosederivate/ Synthesis and Complexation of Spacer Modified Phosphorylated Glucose Derivatives
  12. Synthesis and Structure of a Tetranuclear Nickel Complex of a 40-Membered Macrocyclic Octaamine-Tetrathiophenolate Ligand
  13. Preparation and Crystal Structure of a Mixed Metal Assembly [Ni(phen)3][Cu(H-1pap)]2(NO3) · 8 H2O Featuring Octahedral Cationic and Square-planar Anionic Modules
  14. Kristallstrukturen der Komplexe Von Quecksilber(Ii)Iodid und -Thiocyanat mit L,13-Bis(8-Chinolyl)-L,4,7,10,13-Pentaoxatridecan („Kryptand 5“)
  15. Synthesis, Complex Formation and Spectral Investigation of New Tritopic Bis(Crown Ether) Compounds Containing Recognition Sites for Sodium and Nickel Guest Cations*
  16. Long Chain Cinnamoic Acid Esters from Daphne Oleoides
  17. One-Pot Preparation of O-Xylylene Diamine and its Related Amines
  18. Notizen: Ca{Li2[Mn'N]2}: Kristallchemischer Brückenschlag Zwischen Lithium-Nitrido-Verbindungen und Borid-Carbiden des Typs M [B2C2]/ Ca{Li2[M nIN]2}: Link between Crystal Chemistry of Lithium Nitrido Compounds and Boride Carbides of the Type M [B2C2]
  19. N -Methoxyalkyl-Funktionalisierte α-Diketodiimide/ N -Methoxyalkyl Functionalized α-Diketodiimides
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