Home Physical Sciences Polylithiation of Small Molecules. Synthesis and Structure of the Functional Lithium Phosphide [Li(TMEDA)]2[PhPCMe2 C5H4]
Article
Licensed
Unlicensed Requires Authentication

Polylithiation of Small Molecules. Synthesis and Structure of the Functional Lithium Phosphide [Li(TMEDA)]2[PhPCMe2 C5H4]

  • Ulrich Jürgen Bildmann and Gerhard Müller EMAIL logo
Published/Copyright: June 2, 2014
Become an author with De Gruyter Brill
Author Information Explore this Subject
Zeitschrift für Naturforschung B
From the journal Zeitschrift für Naturforschung B Volume 55 Issue 10

Abstract

Lithium Phosphides, Cyclopentadienides Treatment of 6,6-dimethylfulvene with LiPHPh in hexane/TMEDA (TMEDA = N,N,N′,N′- tetramethylethylenediamine) affords the monolithiated phosphinomethyl cyclopentadienide [Li(TMEDA)][PhHPCMe2C5H4] (1). Further reaction with LinBu in diethylether/TMEDA leads to the formation of the doubly lithiated phosphidomethyl cyclopentadienide [Li(TMEDA)]2[PhPCMe2C5H4] (2) whose crystal and molecular structure was determined (orthorhombic, space group P212121, a = 9.579(4), b = 12.788(2), c = 24.108(6) Å, Z = 4)

: Lithium Phosphides; Cyclopentadienides
Received: 2000-7-3
Published Online: 2014-6-2
Published in Print: 2000-10-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

Articles in the same Issue

  1. Gold Clustering at Dimethylsulfoximine Me2S(O)NH
  2. Polylithiation of Small Molecules. Synthesis and Structure of the Functional Lithium Phosphide [Li(TMEDA)]2[PhPCMe2 C5H4]
  3. Synthese und Kristallstrukturbestimmung von Silicium-Komplexen der Koordinationszahl sechs mit Dimethylpyridinen/ Syntheses and Crystal Structure Determination of Hexacoordinated Silicon-Complexes with Dimethylpyridines
  4. Synthese und Kristallstruktur von (Ph3PAu)4[AuMn(CO)5]2 und (Ph3PAu)3Re(CO)4/ Synthesis and Crystal Structure of (Ph3PAu)4 [AuMn(CO)5]2 and (Ph3PAu)3Re(CO)4
  5. Silylfurane und Bis(silyl)butadiine -Synthese, Lithiumderivate, Kristallstrukturen/ Silylfurans and Bis(silyl)butadiynes - Synthesis, Lithium Derivatives, Crystal Structures
  6. Reaktionen der Lithiumhydridosilylamide Me2(H)Si-N(Li)R (R = CMe3, SiMe3) mit Chlortrimethylstannan und Chlormethylsilanen Me4–nSiCln (n = 1-3)/ Reactions of Lithium Hydridosilylamides Me2(H)Si-N(Li)R (R = CMe3, SiMe3) with Chlorotrimethylstannane and Chloromethylsilanes Me4-nSiCln (n = 1 - 3)
  7. The Madelung Function of Elpasolites
  8. Tri(Terf-Butyl)plumbyl-phosphanes, Synthesis and Multinuclear Magnetic Resonance
  9. Metallkomplexe von biologisch wichtigen Liganden, CXXIX [1]. Palladium(II)-und Platin(II)-Komplexe von 4,4-disubstituierten Oxazolonen und C2-symmetrischen Bis(oxazolonen) Metal Complexes of Biologically Important Ligands, CXXIX [1]. Palladium(II) and Platinum(II) Complexes of 4,4-Disubstituted Oxazolones and of C2-Symmetric Bis(oxazolones)
  10. Diorgano(trichlorsiIyl)phosphane/ Diorgano(trichlorosilyl)phosphines
  11. Synthese und Komplexierung Phosphorylierter spacer-modifizierter Glucosederivate/ Synthesis and Complexation of Spacer Modified Phosphorylated Glucose Derivatives
  12. Synthesis and Structure of a Tetranuclear Nickel Complex of a 40-Membered Macrocyclic Octaamine-Tetrathiophenolate Ligand
  13. Preparation and Crystal Structure of a Mixed Metal Assembly [Ni(phen)3][Cu(H-1pap)]2(NO3) · 8 H2O Featuring Octahedral Cationic and Square-planar Anionic Modules
  14. Kristallstrukturen der Komplexe Von Quecksilber(Ii)Iodid und -Thiocyanat mit L,13-Bis(8-Chinolyl)-L,4,7,10,13-Pentaoxatridecan („Kryptand 5“)
  15. Synthesis, Complex Formation and Spectral Investigation of New Tritopic Bis(Crown Ether) Compounds Containing Recognition Sites for Sodium and Nickel Guest Cations*
  16. Long Chain Cinnamoic Acid Esters from Daphne Oleoides
  17. One-Pot Preparation of O-Xylylene Diamine and its Related Amines
  18. Notizen: Ca{Li2[Mn'N]2}: Kristallchemischer Brückenschlag Zwischen Lithium-Nitrido-Verbindungen und Borid-Carbiden des Typs M [B2C2]/ Ca{Li2[M nIN]2}: Link between Crystal Chemistry of Lithium Nitrido Compounds and Boride Carbides of the Type M [B2C2]
  19. N -Methoxyalkyl-Funktionalisierte α-Diketodiimide/ N -Methoxyalkyl Functionalized α-Diketodiimides
https://doi.org/10.1515/znb-2000-1002

Articles in the same Issue

  1. Gold Clustering at Dimethylsulfoximine Me2S(O)NH
  2. Polylithiation of Small Molecules. Synthesis and Structure of the Functional Lithium Phosphide [Li(TMEDA)]2[PhPCMe2 C5H4]
  3. Synthese und Kristallstrukturbestimmung von Silicium-Komplexen der Koordinationszahl sechs mit Dimethylpyridinen/ Syntheses and Crystal Structure Determination of Hexacoordinated Silicon-Complexes with Dimethylpyridines
  4. Synthese und Kristallstruktur von (Ph3PAu)4[AuMn(CO)5]2 und (Ph3PAu)3Re(CO)4/ Synthesis and Crystal Structure of (Ph3PAu)4 [AuMn(CO)5]2 and (Ph3PAu)3Re(CO)4
  5. Silylfurane und Bis(silyl)butadiine -Synthese, Lithiumderivate, Kristallstrukturen/ Silylfurans and Bis(silyl)butadiynes - Synthesis, Lithium Derivatives, Crystal Structures
  6. Reaktionen der Lithiumhydridosilylamide Me2(H)Si-N(Li)R (R = CMe3, SiMe3) mit Chlortrimethylstannan und Chlormethylsilanen Me4–nSiCln (n = 1-3)/ Reactions of Lithium Hydridosilylamides Me2(H)Si-N(Li)R (R = CMe3, SiMe3) with Chlorotrimethylstannane and Chloromethylsilanes Me4-nSiCln (n = 1 - 3)
  7. The Madelung Function of Elpasolites
  8. Tri(Terf-Butyl)plumbyl-phosphanes, Synthesis and Multinuclear Magnetic Resonance
  9. Metallkomplexe von biologisch wichtigen Liganden, CXXIX [1]. Palladium(II)-und Platin(II)-Komplexe von 4,4-disubstituierten Oxazolonen und C2-symmetrischen Bis(oxazolonen) Metal Complexes of Biologically Important Ligands, CXXIX [1]. Palladium(II) and Platinum(II) Complexes of 4,4-Disubstituted Oxazolones and of C2-Symmetric Bis(oxazolones)
  10. Diorgano(trichlorsiIyl)phosphane/ Diorgano(trichlorosilyl)phosphines
  11. Synthese und Komplexierung Phosphorylierter spacer-modifizierter Glucosederivate/ Synthesis and Complexation of Spacer Modified Phosphorylated Glucose Derivatives
  12. Synthesis and Structure of a Tetranuclear Nickel Complex of a 40-Membered Macrocyclic Octaamine-Tetrathiophenolate Ligand
  13. Preparation and Crystal Structure of a Mixed Metal Assembly [Ni(phen)3][Cu(H-1pap)]2(NO3) · 8 H2O Featuring Octahedral Cationic and Square-planar Anionic Modules
  14. Kristallstrukturen der Komplexe Von Quecksilber(Ii)Iodid und -Thiocyanat mit L,13-Bis(8-Chinolyl)-L,4,7,10,13-Pentaoxatridecan („Kryptand 5“)
  15. Synthesis, Complex Formation and Spectral Investigation of New Tritopic Bis(Crown Ether) Compounds Containing Recognition Sites for Sodium and Nickel Guest Cations*
  16. Long Chain Cinnamoic Acid Esters from Daphne Oleoides
  17. One-Pot Preparation of O-Xylylene Diamine and its Related Amines
  18. Notizen: Ca{Li2[Mn'N]2}: Kristallchemischer Brückenschlag Zwischen Lithium-Nitrido-Verbindungen und Borid-Carbiden des Typs M [B2C2]/ Ca{Li2[M nIN]2}: Link between Crystal Chemistry of Lithium Nitrido Compounds and Boride Carbides of the Type M [B2C2]
  19. N -Methoxyalkyl-Funktionalisierte α-Diketodiimide/ N -Methoxyalkyl Functionalized α-Diketodiimides
Sign up now to receive a 20% welcome discount
Institutional Access
How does access work?
Winner of the OpenAthens UX Award 2026
Winner of the OpenAthens UX Award 2026
Have an idea on how to improve our website?
Please write us.
© 2026 De Gruyter Brill
Downloaded on 4.3.2026 from https://www.degruyterbrill.com/document/doi/10.1515/znb-2000-1002/html
Scroll to top button