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Electrical Conduction in Transition-Metal Salts

  • M.A. Grado-Caffaro EMAIL logo und M. Grado-Caffaro
Veröffentlicht/Copyright: 17. Februar 2016

Abstract

We predict that a given transition-metal salt as, for example, a K2CuCl4·2H2O–type compound, can behave as an electrical conductor in the paramagnetic case. In fact, we determine the electrical conductance in a salt of this type. This conductance is found to be quantised in agreement with previous well-known results. Related mathematical expressions in the context of superexchange interaction are obtained. In addition, we determine the corresponding (macroscopically viewed) current density and the associated electron wave functions.


Corresponding author: M.A. Grado-Caffaro, Scientific Consultants, c/o Julio Palacios 11, 9-B, 28029, Madrid, Spain, E-mail:

References

[1] M. A. Grado-Caffaro and M. Grado-Caffaro, Mod. Phys. Lett. B 16, 751 (2002).10.1142/S021798490200424XSuche in Google Scholar

[2] M. A. Grado-Caffaro and M. Grado-Caffaro, Mod. Phys. Lett. B 18, 909 (2004).10.1142/S0217984904007281Suche in Google Scholar

[3] M. A. Grado-Caffaro and M. Grado-Caffaro, Acta Phys. Pol. A 128, 394 (2015).10.12693/APhysPolA.128.394Suche in Google Scholar

[4] H. K. Rockstad, Solid State Commun. 9, 2233 (1971).10.1016/0038-1098(71)90637-5Suche in Google Scholar

[5] Y. Tokura and N. Nagaosa, Science 288, 462 (2000).10.1126/science.288.5465.462Suche in Google Scholar

[6] S. C. Bhargava, S. Singh, A. H. Morrish, and Z. W. Li, Solid State Commun. 116, 575 (2000).10.1016/S0038-1098(00)00378-1Suche in Google Scholar

[7] W. J. Looyestijn, T. O. Klaassen, and N. J. Poulis, Physica B 97, 33 (1979).10.1016/0378-4363(79)90004-4Suche in Google Scholar

[8] N. D. Moon, K. H. Lee, and S. H. Choh, Can. J. Phys. 63, 946 (1985).Suche in Google Scholar

[9] J. Zaanen and G. A. Sawatzky, Can. J. Phys. 65, 1262 (1987).10.1139/p87-201Suche in Google Scholar

[10] S. Vulfson, Molecular Magnetochemistry, Taylor and Francis, London 1998.Suche in Google Scholar

[11] J. Tersoff, D. R. Hamann, Phys. Rev. B 31, 805 (1985).10.1103/PhysRevB.31.805Suche in Google Scholar PubMed

[12] J. A. Stroscio, R. M. Feenstra, and A. P. Fein, Phys. Rev. Lett. 57, 2579 (1986).10.1103/PhysRevLett.57.2579Suche in Google Scholar

[13] R. M. Feenstra, J. A. Stroscio, J. Tersoff, and A. P. Fein, Phys. Rev. Lett. 58, 1192 (1987).10.1103/PhysRevLett.58.1192Suche in Google Scholar

[14] J. A. Stroscio, D. T. Pierce, A. Davies, R. J. Celotta, and M. Weinert, Phys. Rev. Lett. 75, 2960 (1995).10.1103/PhysRevLett.75.2960Suche in Google Scholar

[15] W. J. Looyestijn, Ph.D. Thesis, University of Leiden, Leiden, The Netherlands, 1979.Suche in Google Scholar

[16] A. Soldatov, N. Bogolubov Jr., and S. Kruchinin, Condens. Matter. Phys. 9, 151 (2006).10.5488/CMP.9.1.151Suche in Google Scholar

[17] V. Ermakov, S. Kruchinin, H. Hori, and A. Fujiwara, Int. J. Mod. Phys. B 21, 1827 (2007).10.1142/S0217979207037053Suche in Google Scholar

[18] S. Kruchinin and H. Nagao, Int. J. Mod. Phys. B 26, 1230013 (2012).10.1142/S0217979212300137Suche in Google Scholar

[19] M. Apostol, Phys. Lett. A 372, 5093 (2008).10.1016/j.physleta.2008.05.061Suche in Google Scholar

[20] M. A. Grado-Caffaro and M. Grado-Caffaro, Nano 7, 1250019 (2012).10.1142/S1793292012500191Suche in Google Scholar

Received: 2015-12-25
Accepted: 2016-1-17
Published Online: 2016-2-17
Published in Print: 2016-4-1

©2016 by De Gruyter

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