Ytterbium valence ordering in the low-temperature superstructure of Yb2Pd2Cd
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Jutta Kösters
Abstract
The intermetallic ytterbium compound Yb2Pd2Cd shows a structural phase transition at ∼150 K. The structures of the room-temperature (Mo2B2Fe type, P4/mbm, a = 757.07(7), c = 371.99(4) pm, wR2 = 0.0620, 272 F 2 values, 12 variables) and low-temperature (new type, P4/mbm, a = 747.26(4), c = 741.46(4) pm, wR2 = 0.0384, 511 F 2 values, 19 variables) modifications were refined from single crystal X-ray diffractometer data. The superstructure formation corresponds to an isomorphic transition of index 2. The driving force for the structural phase transition is an ytterbium charge ordering (the superstructure exhibits two crystallographically independent ytterbium sites) with a much higher degree of divalent ytterbium in the low-temperature modification. The striking structural feature concerns the ytterbium–palladium coordination with different Yb–Pd distances: longer ones for predominantly divalent Yb1 (2 × 284.7 and 4 × 296.1 pm, ∅ = 292.3 pm) and shorter ones for trivalent Yb2 (2 × 277.5 and 4 × 288.4 pm, ∅ = 284.8 pm).
Acknowledgments
We thank Dr. A. Doğan for selecting the single.
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Research ethics: Not applicable.
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Author contributions: All authors have accepted responsibility for the entire content of this submitted manuscript and approved the submission.
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Competing interests: The authors declare no conflicts of interest regarding this article.
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Research funding: This research was funded by Universität Münster.
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Data availability: Data is available from the corresponding author on well-founded request.
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© 2023 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- In this issue
- Inorganic Crystal Structures (Original Paper)
- Ytterbium valence ordering in the low-temperature superstructure of Yb2Pd2Cd
- The HfFe2Si2 type silicides ScT2Si2 (T = Ru, Rh, Os) – structure and solid-state 29Si/45Sc NMR spectroscopy
- Finding the ‘Goldilocks Zone’: cationic size and tilting of carbodiimide and cyanamide anions
- High-pressure/high-temperature synthesis of the first walstromite-analogue borate Tm2CrB3O9
- Organic and Metalorganic Crystal Structures (Original Paper)
- A doubly mononuclear cobalt(II) complex constructed with azide anions and a new coordination mode of the 2-(2-pyridylmethylamino) ethanesulfonic acid ligands: structure, conformation comparison and Hirshfeld surface analysis
- Crystal structures of а series of 1-substituted imidazol-4,5-dicarboxylic acids
- A bibliographic survey of the structural chemistry of the Group 13 dithiophosphates and dithiophosphinates
Artikel in diesem Heft
- Frontmatter
- In this issue
- Inorganic Crystal Structures (Original Paper)
- Ytterbium valence ordering in the low-temperature superstructure of Yb2Pd2Cd
- The HfFe2Si2 type silicides ScT2Si2 (T = Ru, Rh, Os) – structure and solid-state 29Si/45Sc NMR spectroscopy
- Finding the ‘Goldilocks Zone’: cationic size and tilting of carbodiimide and cyanamide anions
- High-pressure/high-temperature synthesis of the first walstromite-analogue borate Tm2CrB3O9
- Organic and Metalorganic Crystal Structures (Original Paper)
- A doubly mononuclear cobalt(II) complex constructed with azide anions and a new coordination mode of the 2-(2-pyridylmethylamino) ethanesulfonic acid ligands: structure, conformation comparison and Hirshfeld surface analysis
- Crystal structures of а series of 1-substituted imidazol-4,5-dicarboxylic acids
- A bibliographic survey of the structural chemistry of the Group 13 dithiophosphates and dithiophosphinates
