Startseite A doubly mononuclear cobalt(II) complex constructed with azide anions and a new coordination mode of the 2-(2-pyridylmethylamino) ethanesulfonic acid ligands: structure, conformation comparison and Hirshfeld surface analysis
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A doubly mononuclear cobalt(II) complex constructed with azide anions and a new coordination mode of the 2-(2-pyridylmethylamino) ethanesulfonic acid ligands: structure, conformation comparison and Hirshfeld surface analysis

  • Shu-Hui Chen EMAIL logo , Hai-Tao Song und Xia Xu
Veröffentlicht/Copyright: 27. November 2023
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 239 Heft 1-2

Abstract

A doubly mononuclear cobalt(II) complex [Co(Hpmt)2(N3)2]2 (1) (Hpmt = 2-(2-pyridylmethylamino)ethanesulfonic acid; N3 = azide anion) has been synthesized and structurally characterized. Single-crystal X-ray diffraction analysis showed that 1 has crystallized in orthorhombic crystal system, Cmc21 space group. In the two independent and identical complexes, the cobalt(II) centers are both hexa-coordinated in distorted CoN6 octahedrons. The reduced Schiff base ligand Hpmt displayed a new coordination mode of bidentate chelate (κ 2-N,N′). The careful comparisons between Hpmt upon coordination and as free acid form demonstrated that the conformation flexibility might be responsible for its multiple coordination modes. The N–H⋯O and C–H⋯N hydrogen bonds constructed the 3D network, and this mainly agreed with the Hirshfeld surface analysis results.

Keywords: cobalt(II) complex; 2-(2-pyridylmethylamino) ethanesulfonic acid; azide anion; flexible conformation; Hirshfeld surface analysis
Corresponding author: Shu-Hui Chen, Xinxiang Vocational and Technical College, Xinxiang, Henan Province, 473000, P.R. China; E-mail: .

Funding source: This work was supported by the private expense of all authors

Supplementary material

The CCDC number 612370 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via http://www.ccdc.cam.ac.uk/data_request/cif.

  1. Research ethics: All authors will strictly follow the research ethics and have no plagiarism, tampering and other academic misconducts.

  2. Author contributions: S-HC Methodology, Software, Writing - review & editing. H-TS Data curation, Writing - original draft. XX Formal analysis.

  3. Competing interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

  4. Research funding: This work was supported by the private expense of all authors.

  5. Data availability: Not applicable.

References

1. Arunadevi, A., Raman, N. Biological response of Schiff base metal complexes incorporating amino acids – a short review. J. Coord. Chem. 2020, 73, 2095–2116; https://doi.org/10.1080/00958972.2020.1824293.Suche in Google Scholar

2. Osmankovic, I., Turkusic, E., Zahirovic, A., Kralj, M., Uzelac, L., Kahrovic, E. CT DNA, BSA and antiproliferative activity of Ru(II) bipyridine complexes containing Schiff bases derived from amino acids. Croat. Chem. Acta 2022, 94, 148–157; https://doi.org/10.5562/cca3872.Suche in Google Scholar

3. Yorur-Goreci, C., Altas-Puntar, N., Toraman, A., Demirhan, N. Synthesis, spectral and thermal characterization, biological activity of a new amino acide ester containing substituted salicylaldimine Schiff base ligand and its Ru(II)bipyridyl complex. Main Group Chem. 2021, 20, 193–202; https://doi.org/10.3233/mgc-210032.Suche in Google Scholar

4. Pahontu, E., Ilies, D. C., Shova, S., Paraschivescu, C., Badea, M., Gulea, A., Rosu, T. Synthesis, characterization, crystal structure and antimicrobial activity of copper(II) complexes with the Schiff base derived from 2-hydroxy-4-methoxybenzaldehyde. Molecules 2015, 20, 5771–5792; https://doi.org/10.3390/molecules20045771.Suche in Google Scholar PubMed PubMed Central

5. Youssef, N. S., El Zahany, E. A., Ali, M. M. Synthesis, spectral, characterization, and anticancer activity of some binary and mixed ligand complexes of 4-methyl-2-pentanone thiosemicarbazone and some amino acids. Phosphorus Sulfur 2010, 185, 2171–2181; https://doi.org/10.1080/10426500903241739.Suche in Google Scholar

6. Jiang, Y. M., Li, J. M., Xie, F. Q., Wang, Y. F. Synthesis and crystal structure of an azide bridged binuclear zinc(II) dimer containing taurine Schiff base [Zn2(C8H9N2O3S)2·(N3)2·(H2O)2]2·2H2O. Chinese J. Struct. Chem. 2006, 25, 767–770.Suche in Google Scholar

7. Qin, X. Y., Zhang, S. H., Jiang, Y. M., Liu, J. C., Qin, J. H. Syntheses, crystal structures and antibacterial activities of [Cu2(C11H11NO5S)2(H2O)4]·5H2O and [Ni2(C11H11NO5S)2(H2O)4]·2H2O. J. Coord. Chem. 2009, 62, 427–439; https://doi.org/10.1080/00958970802298394.Suche in Google Scholar

8. Li, J. M., Jiang, Y. M., Li, C. Z., Zhang, S. H. Triaqua[2-(2-pyridylmethyleneamino) ethanesulfonato-κ3N,N’,O]nickel(II) perchlorate monohydrate. Acta Crystallogr. 2007, E63, m447–m449; https://doi.org/10.1107/s1600536806055929.Suche in Google Scholar

9. Zeng, J. L., Yu, S. B., Jiang, Y. M., Sun, L. X., Cao, Z., Yang, D. W. Synthesis and crystal structure of [Ni(L)(Phen)(H2O)]·3.75H2O. J. Chem. Crystallogr. 2010, 40, 761–764; https://doi.org/10.1007/s10870-010-9733-7.Suche in Google Scholar

10. Qin, X. Y., Zeng, J. L., Zhang, S. H., Jiang, Y. M. Synthesis and crystal structure of Schiff base compound [Zn(C10H9NO5S)(C12H8N2)(H2O)]·4.25H2O. Synth. React. Inorg. Met. 2012, 42, 915–919.10.1080/15533174.2011.618476Suche in Google Scholar

11. Casella, L., Gullotti, M. Coordination modes of histidine. 6. Transamination in the 2-formylpyridine-amino acid-metal ion systems. Stereochemistry of zinc(II) and copper(II) complexes of N-(2-pyridylmethylidene)amino acids. Inorg. Chem. 1983, 22, 2259–2266; https://doi.org/10.1021/ic00158a008.Suche in Google Scholar

12. Wagner, M. R., Walker, F. A. Spectroscopic study of 1:1 copper(II) complexes with Schiff base ligands derived from salicylaldehyde and L-histidine and its analogs. Inorg. Chem. 1983, 22, 3021–3028; https://doi.org/10.1021/ic00163a009.Suche in Google Scholar

13. Li, J. X., Jiang, Y. M., Li, H. Y. Bis[2-(2-pyridylmethylamino)ethanesulfonato-κ3N,N’,O] cobalt(II). Acta Crystallogr. 2006, E62, m2984–m2986; https://doi.org/10.1107/s1600536806042267.Suche in Google Scholar

14. Li, J. X., Jiang, Y. M., Chen, M. J. Bridging chlorides and hydroxides: syntheses and crystal structures of binuclear and tetranuclear NiII complexes derived from a reduced Schiff-base ligand 2-(2-pyridylmethylamino)ethanesulfonic acid. J. Coord. Chem. 2008, 61, 1765–1773; https://doi.org/10.1080/00958970701744274.Suche in Google Scholar

15. Li, J. X., Jiang, Y. M., Lian, B. R. Syntheses and crystal structures of two CuII Coordination isomers [Cu(pmt)2]·4H2O (1) and {[Cu(pmt)2]·2H2O}n (2). J. Chem. Crystallogr. 2008, 38, 711–715; https://doi.org/10.1007/s10870-008-9365-3.Suche in Google Scholar

16. Du, Z. X., Li, J. X. Crystal structure of catena-poly{[chloromercury(II)]-μ-[2-(2-pyridyl methylamino)ethanesulfonato-κ4N,N’,O:O’]}, [Hg(C8H11N2O3S)(Cl)]n. Z. Kristallogr. – New Cryst. Struct. 2008, 223, 211–212; https://doi.org/10.1524/ncrs.2008.0088.Suche in Google Scholar

17. Li, J. X., Jiang, Y. M., Wang, J. G. Poly[μ-azido-κ2N1:N3-μ-2-(2-pyridylmethylamino) ethanesulfonato-κ4N,N’,O:O’-copper(II)]. Acta Crystallogr. 2007, E63, m213–m215; https://doi.org/10.1107/s1600536806053475.Suche in Google Scholar

18. Li, J. X., Jiang, Y. M., Wang, J. G. Catena-poly[[(thiocyanato-κN)copper(II)]-[2-(2-pyridyl methylamino)ethanesulfonato-κ5N,N’,O:O’:O’’]]. Acta Crystallogr. 2007, E63, m601–m603.10.1107/S1600536807003303Suche in Google Scholar

19. Leong, W. L., Vittal, J. J. Synthesis, characterization and structures of copper(II) complexes containing carboxylate and sulfonate groups. J. Incl. Phenom. Macrocycl. Chem. 2011, 71, 557–566; https://doi.org/10.1007/s10847-011-0015-6.Suche in Google Scholar

20. Bruker. Apex-II CCD Single Crystal X-Ray Diffractometer; Bruker AXS Corporation: Germany, 2004.Suche in Google Scholar

21. Sheldrick, G. M. Sadabs, Program for Absorption Correction of the Area Detector Data; University of Göttingen: Germany, 1996.Suche in Google Scholar

22. Sheldrick, G. M. Shelxs97, Program for Crystal Structure Solution; University of Göttingen: Germany, 1997.Suche in Google Scholar

23. Sheldrick, G. M. Shelxl97, Program for Crystal Structure Refinement; University of Göttingen: Germany, 1997.Suche in Google Scholar

24. Wolff, S. K., Grimwood, D. J., McKinnon, J. J., Jayatilaka, D., Spackman, M. A. Crystal Explorer 2.0; University of Western Australia: Perth, Australia, 2007.Suche in Google Scholar

25. Allen, F. H., Kennard, O., Watson, D. G., Brammer, L., Orpen, A. G., Taylor, R. J. J. Chem. Soc. Perkin Trans. 1987, 2, S1–S19; https://doi.org/10.1039/p298700000s1.Suche in Google Scholar

26. McKinnon, J. J., Spackman, M. A., Mitchell, A. S. Novel tools for visualizing and exploring intermolecular interactions in molecular crystals. Acta Crystallogr. 2004, B60, 627–668; https://doi.org/10.1107/s0108768104020300.Suche in Google Scholar

27. Anzaldo-Olivares, B., Arroyo, M., Ramírez-Monroy, A., Bernès, S. Tris(1H-benzimidazol-2-ylmethyl)amine methanol trisolvate. IUCrData 2020, 5, x200281; https://doi.org/10.1107/s2414314620002813.Suche in Google Scholar

28. Stapf, M., Seichtera, W., Mazika, M. Crystal structures of monohydrate and methanol solvate compounds of {1-[(3,5-bis{[(4,6-dimethylpyridin-2-yl)amino]methyl}-2,4,6-tri ethylbenzyl)amino]cyclopentyl}methanol. Acta Crystallogr. 2020, E76, 1679–1683; https://doi.org/10.1107/s2056989020012554.Suche in Google Scholar PubMed PubMed Central

29. Velázquez-Carmona, M. Á., Bernès, S., Ríos-Merino, F. J., Reyes Ortega, Y. Crystal structure of trans-N,N’-bis(3,5-di-tert-butyl-2-hydroxyphenyl)oxamide methanol monosolvate. Acta Crystallogr. 2016, E72, 918–921; https://doi.org/10.1107/s205698901600880x.Suche in Google Scholar

30. Li, J. X., Ge, S., Lu, Y. J., Quan, K. Y., Wu, L. B., Wang, A. R. A new copper(II) complex containing triclopyr: one-pot crystallization, structure, conformation and Hirshfeld surface analyses. Z. Kristallogr. 2023, 238, 129–137; https://doi.org/10.1515/zkri-2022-0063.Suche in Google Scholar

31. Li, J. X., Zhang, Y. H., Du, Z. X., Feng, X. One-pot solvothermal synthesis of mononuclear and oxalate-bridged binuclear nickel compounds: structural analyses, conformation alteration and magnetic properties. Inorg. Chim. Acta 2022, 530, 120697; https://doi.org/10.1016/j.ica.2021.120697.Suche in Google Scholar

32. Li, J. X., Xiong, L. Y., Xu, X. J., Liu, C., Wang, Z. G. The synthesis, crystal structure and conformation analysis of triclopyr ethyl ester. Z. Kristallogr. 2022, 237, 385–391; https://doi.org/10.1515/zkri-2022-0047.Suche in Google Scholar

33. Li, J. X., Du, Z. X., Zhang, L. L., Liu, D. L., Pan, Q. Y. Doubly mononuclear cocrystal and oxalato-bridged binuclear copper compounds containing flexible 2-((3,5,6-trichloropyridin-2-yl)oxy)acetate tectons: synthesis, crystal analysis and magnetic properties. Inorg. Chim. Acta 2020, 512, 119890; https://doi.org/10.1016/j.ica.2020.119890.Suche in Google Scholar

34. Li, J. X., Du, Z. X. A binuclear cadmium(II) cluster based on π···π stacking and halogen···halogen interactions: synthesis, crystal analysis and fluorescent properties. J. Clust. Sci. 2020, 31, 507–511; https://doi.org/10.1007/s10876-019-01666-w.Suche in Google Scholar

35. Li, J. X., Lu, Y. J., Quan, K. Y., Wu, L. B., Feng, X., Wang, W. Z. One-pot cocrystallization of mononuclear and 1D cobalt(II) complexes based on flexible triclopyr and 2,2′-bipyridine coligands: structural analyses conformation comparison, non-covalent interactions and magnetic properties. J. Mol. Struct. 2024, 1297, 136830; https://doi.org/10.1016/j.molstruc.2023.136830.Suche in Google Scholar

36. Li, J. X., Du, Z. X., Pan, Q. Y., Zhang, L. L., Liu, D. L. The first 3,5,6-trichloropyridine-2-oxyacetate bridged manganese coordination polymer with features of π···π stacking and halogen···halogen interactions: synthesis, crystal analysis and magnetic properties. Inorg. Chim. Acta 2020, 509, 119677; https://doi.org/10.1016/j.ica.2020.119677.Suche in Google Scholar

37. Li, J. X., Jiang, Y. M., Liao, B. L. 2-(2-Pyridylmethylammonio)ethanesulfonate dihydrate. Acta Crystallogr. 2006, E62, o5609–o5611; https://doi.org/10.1107/s1600536806047568.Suche in Google Scholar

Supplementary Material

This article contains supplementary material (https://doi.org/10.1515/zkri-2023-0031).

Received: 2023-08-15
Accepted: 2023-11-08
Published Online: 2023-11-27
Published in Print: 2024-01-29

© 2023 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

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  2. In this issue
  3. Inorganic Crystal Structures (Original Paper)
  4. Ytterbium valence ordering in the low-temperature superstructure of Yb2Pd2Cd
  5. The HfFe2Si2 type silicides ScT2Si2 (T = Ru, Rh, Os) – structure and solid-state 29Si/45Sc NMR spectroscopy
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  7. High-pressure/high-temperature synthesis of the first walstromite-analogue borate Tm2CrB3O9
  8. Organic and Metalorganic Crystal Structures (Original Paper)
  9. A doubly mononuclear cobalt(II) complex constructed with azide anions and a new coordination mode of the 2-(2-pyridylmethylamino) ethanesulfonic acid ligands: structure, conformation comparison and Hirshfeld surface analysis
  10. Crystal structures of а series of 1-substituted imidazol-4,5-dicarboxylic acids
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https://doi.org/10.1515/zkri-2023-0031
Schlagwörter für diesen Artikel
cobalt(II) complex; 2-(2-pyridylmethylamino) ethanesulfonic acid; azide anion; flexible conformation; Hirshfeld surface analysis

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Inorganic Crystal Structures (Original Paper)
  4. Ytterbium valence ordering in the low-temperature superstructure of Yb2Pd2Cd
  5. The HfFe2Si2 type silicides ScT2Si2 (T = Ru, Rh, Os) – structure and solid-state 29Si/45Sc NMR spectroscopy
  6. Finding the ‘Goldilocks Zone’: cationic size and tilting of carbodiimide and cyanamide anions
  7. High-pressure/high-temperature synthesis of the first walstromite-analogue borate Tm2CrB3O9
  8. Organic and Metalorganic Crystal Structures (Original Paper)
  9. A doubly mononuclear cobalt(II) complex constructed with azide anions and a new coordination mode of the 2-(2-pyridylmethylamino) ethanesulfonic acid ligands: structure, conformation comparison and Hirshfeld surface analysis
  10. Crystal structures of а series of 1-substituted imidazol-4,5-dicarboxylic acids
  11. A bibliographic survey of the structural chemistry of the Group 13 dithiophosphates and dithiophosphinates
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