Effect of different boron sources on the copper borates in solid-state synthesis
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Fatma Tugce Senberber Dumanli
,
Sibel Kavci Karaagac
,
Azmi Seyhun Kipcak
und
Emek Moroydor Derun
Abstract
The copper borate of CuB2O4 in tetragonal form was successfully synthesized as a single-phase by using a solid-state method without using any modifying agent. For the designed experimental procedure, the optimized reaction conditions were estimated as a reaction temperature of 950 °C, reaction time of 240 min, argon atmosphere and Cu:B ratio of 1:5. The possible reaction mechanism estimated for both boron sources of boric acid and boron oxide. In both sets, the lower ratios of Cu:B supported CuB2O4 formation. In the use of boric acid as a boron source, higher reaction yield percentages (98 %) and lower particle sizes were determined. The micron-scale rounded particles were observed in morphological analyses and the particles were shaped in homogeneity in the use of boron oxide as a boron source. The specific FT-IR peaks were observed at the band values of 1190, 1035, 988, 945, 890, 695, 631, 540 and 479 cm−1. The experimental results highlighted the probable use of solid-state in the copper borate synthesis.
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Research ethics: Not applicable.
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Author contribution: The authors have accepted responsibility for the entire content of this manuscript and approved its submission.
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Competing interests: The authors state no conflict of interest.
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Research funding: None declared.
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Data availability: The raw data can be obtained on request from the corresponding author.
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© 2023 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- In this issue
- Inorganic Crystal Structures (Original Paper)
- Colloidal nanocrystal synthesis of alkaline earth metal sulfides for solution-processed solar cell contact layers
- Crystal structures of biocompatible Mg-, Zn-, and Co-whitlockites synthesized via one-step hydrothermal reaction
- (Ca0.95Cd0.10)Pd2Cd3, SrPd2Cd3 and (Eu0.95Cd0.10)Pd2Cd3 with YNi2Al3 type structure – crystal chemistry and magnetic hyperfine interactions
- Ni3Sn4 and FeAl2 as vacancy variants of the W-type (“bcc”) structure
- A new layered potassium-based molybdenum–tungsten monophosphate: synthesis, crystal structure, XPS and magnetic studies
- Effect of different boron sources on the copper borates in solid-state synthesis
- Uranyl silicate nanotubules in Rb2[(UO2)2O(Si3O8)]: synthesis and crystal structure
Artikel in diesem Heft
- Frontmatter
- In this issue
- Inorganic Crystal Structures (Original Paper)
- Colloidal nanocrystal synthesis of alkaline earth metal sulfides for solution-processed solar cell contact layers
- Crystal structures of biocompatible Mg-, Zn-, and Co-whitlockites synthesized via one-step hydrothermal reaction
- (Ca0.95Cd0.10)Pd2Cd3, SrPd2Cd3 and (Eu0.95Cd0.10)Pd2Cd3 with YNi2Al3 type structure – crystal chemistry and magnetic hyperfine interactions
- Ni3Sn4 and FeAl2 as vacancy variants of the W-type (“bcc”) structure
- A new layered potassium-based molybdenum–tungsten monophosphate: synthesis, crystal structure, XPS and magnetic studies
- Effect of different boron sources on the copper borates in solid-state synthesis
- Uranyl silicate nanotubules in Rb2[(UO2)2O(Si3O8)]: synthesis and crystal structure
