Startseite Naturwissenschaften Structure and properties of phases from solid solutions YTIn1−x Al x (T = Ni and Cu)
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Structure and properties of phases from solid solutions YTIn1−x Al x (T = Ni and Cu)

  • Myroslava Horiacha EMAIL logo , Galyna Nychyporuk , Judith Bönnighausen , Frank Stegemann , Volodymyr Pavlyuk , Rainer Pöttgen und Vasyl’ Zaremba
Veröffentlicht/Copyright: 7. November 2022
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Zeitschrift für Kristallographie - Crystalline Materials
Aus der Zeitschrift Zeitschrift für Kristallographie - Crystalline Materials Band 238 Heft 1-2

Abstract

YNiIn and YCuIn form complete solid solutions YNiIn1−x Al x and YCuIn1−x Al x , which were characterized on the basis of X-ray powder diffraction. The ZrNiAl type crystal structures (space groups P 6 ‾ 2 m ) of YNiAl (a = 0.70386(9), c = 0.38327(4) nm, wR 2 = 0.0424), YNiIn0.77Al0.23 (a = 0.73895(9), c = 0.37707(4) nm, wR 2 = 0.0498) and YCuIn0.63Al0.37 (a = 0.73404(7), c = 0.39045(4) nm, wR 2 = 0.0314) were refined from the single crystal X-ray diffraction data. Exemplarily the electronic structure of YNiAl was studied, manifesting substantial Ni–Al bonding within the three-dimensional [NiAl] substructure. Comparison of YNiAl with isotypic YNiIn shows stronger Ni–Al bonding as compared to Ni–In. Magnetic susceptibility measurements of YNiIn1−x Al x (x = 0.1, 0.2, 0.7 and 0.9), YNiIn and YNiAl in the temperature range 3–300 K indicated Pauli paramagnetic behaviour with molar magnetic susceptibility of about 0.15–0.22 × 10−3 emu/mol.

Keywords: crystal growth; crystal structure; electronic structure; magnetic susceptibility
Corresponding author: Myroslava Horiacha, Inorganic Chemistry Department, Ivan Franko National University of Lviv, Kyryla and Mefodiya Street 6, 79005 Lviv, Ukraine, E-mail: ,

Funding source: Deutsche Forschungsgemeinschaft

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was financially supported by the Deutsche Forschungsgemeinschaft. M.H. is indebted to DAAD for a research stipend.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Supplementary Material

The online version of this article offers supplementary material (https://doi.org/10.1515/zkri-2022-0052).

Received: 2022-08-31
Accepted: 2022-10-17
Published Online: 2022-11-07
Published in Print: 2023-01-27

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Inorganic Crystal Structures (Original Paper)
  4. A contribution to the perrhenate crystal chemistry: the crystal structures of new CdTh[MoO4]3-type compounds
  5. Mixed-valent 1:1 oxidotellurates(IV/VI) of Na, K and Rb: superstructure and three-dimensional disorder
  6. Structure and properties of phases from solid solutions YTIn1−x Al x (T = Ni and Cu)
  7. Halide-sodalites: thermal behavior at low temperatures and local deviations from the average structure
  8. Structural study of ceramic samples of the PbTiO3–BaTiO3–BaZrO3 system with a high PbTiO3 content studied by the Rietveld method
  9. A novel crystallographic location of rattling atoms in filled Eu x Co4Sb12 skutterudites prepared under high-pressure conditions
  10. Magnesium and barium in two substructures: BaTMg2 (T = Pd, Ag, Pt, Au) and the isotypic cadmium compound BaAuCd2 with MgCuAl2 type structure
  11. Organic and Metalorganic Crystal Structures (Original Paper)
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https://doi.org/10.1515/zkri-2022-0052
Schlagwörter für diesen Artikel
crystal growth; crystal structure; electronic structure; magnetic susceptibility

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Inorganic Crystal Structures (Original Paper)
  4. A contribution to the perrhenate crystal chemistry: the crystal structures of new CdTh[MoO4]3-type compounds
  5. Mixed-valent 1:1 oxidotellurates(IV/VI) of Na, K and Rb: superstructure and three-dimensional disorder
  6. Structure and properties of phases from solid solutions YTIn1−x Al x (T = Ni and Cu)
  7. Halide-sodalites: thermal behavior at low temperatures and local deviations from the average structure
  8. Structural study of ceramic samples of the PbTiO3–BaTiO3–BaZrO3 system with a high PbTiO3 content studied by the Rietveld method
  9. A novel crystallographic location of rattling atoms in filled Eu x Co4Sb12 skutterudites prepared under high-pressure conditions
  10. Magnesium and barium in two substructures: BaTMg2 (T = Pd, Ag, Pt, Au) and the isotypic cadmium compound BaAuCd2 with MgCuAl2 type structure
  11. Organic and Metalorganic Crystal Structures (Original Paper)
  12. Synthesis, structure, and photocatalytic properties of a two-dimensional uranyl organic framework
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