Open-framework sodium uranyl selenate and sodium uranyl sulfate with protonated morpholino-N-acetic acid
-
Oleg I. Siidra
,
Evgeny V. Nazarchuk
Abstract
The reaction of sodium N-morpholine acetate with selenic and sulfuric acid and uranyl nitrate results in the formation of two novel open-framework compounds, |Na(Hmfa)|[(UO2)2(SeO4)3(H2O)](H2O)2 (NaUSe) and [Na2(SO3OH)(Hmfa)]|(UO2)(SO4)2| (NaUS), respectively. Despite identical synthetic procedures, sulfate structure dramatically differs from selenate compound. Their common feature is an open-framework featuring two-dimensional system of channels occupied by protonated morpholino-N-acetic acid species. Coordination of Na atoms is different. In NaUSe, [(UO2)2 (SeO4)3(H2O)]2− layers are pillared by {Na2O8(H2O)2(Hmfa)2} complexes to form a microporous framework. In NaUS, UO7 and SO4 polyhedra of [(UO2)(SO4)2]2− chains share common oxygen atoms with Na-centered tetrameric complexes providing a three-dimensional integrity of the structure. Both of the compounds are characterized by IR spectroscopy.
Acknowledgements
This work was financially supported by the Russian Science Foundation through the grant 16-17-10085. Technical support by the SPbSU X-ray Diffraction and Microscopy and Microanalysis Resource Centers is gratefully acknowledged.
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Supplementary Material
The online version of this article offers supplementary material (https://doi.org/10.1515/zkri-2018-2103).
©2019 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Graphical Synopsis
- Inorganic
- Temperature induced twinning in aragonite: transmission electron microscopy experiments and ab initio calculations
- Organic
- Crystal structures, Hirsfeld surface analysis and a computational study of four ethyl 2-oxo-2H-chromene-3-carboxylate derivatives: a survey of organyl 2-oxo-2H-chromene-3-carboxylate structures
- Non-covalent interactions observed in nevirapinium pentaiodide hydrate which include the rare I4–I−···O=C halogen bonding
- Open-framework sodium uranyl selenate and sodium uranyl sulfate with protonated morpholino-N-acetic acid
- Competition between coordination bonds and hydrogen bonding interactions in solvatomorphs of copper(II), cadmium(II) and cobalt(II) complexes with 2,2′-bipyridyl and acetate
- Crystallographic Computing
- Stress, strain and Raman shifts
Artikel in diesem Heft
- Frontmatter
- Graphical Synopsis
- Inorganic
- Temperature induced twinning in aragonite: transmission electron microscopy experiments and ab initio calculations
- Organic
- Crystal structures, Hirsfeld surface analysis and a computational study of four ethyl 2-oxo-2H-chromene-3-carboxylate derivatives: a survey of organyl 2-oxo-2H-chromene-3-carboxylate structures
- Non-covalent interactions observed in nevirapinium pentaiodide hydrate which include the rare I4–I−···O=C halogen bonding
- Open-framework sodium uranyl selenate and sodium uranyl sulfate with protonated morpholino-N-acetic acid
- Competition between coordination bonds and hydrogen bonding interactions in solvatomorphs of copper(II), cadmium(II) and cobalt(II) complexes with 2,2′-bipyridyl and acetate
- Crystallographic Computing
- Stress, strain and Raman shifts
