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Synthesis and crystal structure of three new bismuth(III) arylsulfonatocarboxylates

  • Martin Albat , Andrew Kentaro Inge and Norbert Stock EMAIL logo
Published/Copyright: January 20, 2017
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Zeitschrift für Kristallographie - Crystalline Materials
From the journal Zeitschrift für Kristallographie - Crystalline Materials Volume 232 Issue 1-3

Abstract

Three new bismuth arylsulfonatocarboxylates [Bi(OH)(SB)] (1), [Bi4(ST)2(HST)O2(H2O)2]·H2O (2) and [Bi4(ST)2O3(H2O)2] (3) were synthesized under solvothermal reaction conditions at 180°C using the potassium or sodium salt of 4-sulfobenzoic acid (H2SB) and 2-sulfoterephthalic acid (H3ST), respectively. The compounds were characterized in detail and the crystal structures were determined from single crystal X-ray diffraction data. Phase purity was confirmed by powder X-ray diffraction and elemental analysis. Structural comparisons to the only three other known bismuth sulfonatocarboxylates are presented. Due to the higher reaction temperatures employed for the synthesis of the title compounds a higher degree of condensation of the BiOx polyhedra (X=7 or 8) to tetrameric units, 1D chains or a 2D layer is observed. Connection through the organic linker molecules leads to the formation of 3D coordination polymers in all three title compounds.

Keywords: bismuth; coordination polymer; sulfonatocarboxylates

Acknowledgements

A.K.I. is supported by the Knut and Alice Wallenberg Foundation (KAW) through the MAX IV postdoctoral scholarship. Financial support by the Deutsche Forschungsgemeinschaft (DFG) within the framework of the priority program 1415 “Crystalline Non-Equilibrium Phases” is greatfully acknowledged.

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Supplemental Material:

The online version of this article (DOI: 10.1515/zkri-2016-1980) offers supplementary material, available to authorized users.

Received: 2016-6-10
Accepted: 2016-11-20
Published Online: 2017-1-20
Published in Print: 2017-2-1

©2017 Walter de Gruyter GmbH, Berlin/Boston

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https://doi.org/10.1515/zkri-2016-1980
Keywords for this article
bismuth; coordination polymer; sulfonatocarboxylates

Articles in the same Issue

  1. Frontmatter
  2. Graphical Synopsis
  3. Editorial
  4. Synthesis and characterization of metastable transition metal oxides and oxide nitrides
  5. Control of organic polymorph formation: crystallization pathways in acoustically levitated droplets
  6. Thermal annealing of natural, radiation-damaged pyrochlore
  7. The formation of CdS quantum dots and Au nanoparticles
  8. Crystalline chalcogenido metalates – synthetic approaches for materials synthesis and transformation
  9. Fundamental theoretical and practical investigations of the polymorph formation of small amphiphilic molecules, their co-crystals and salts
  10. A density-functional theory approach to the existence and stability of molybdenum and tungsten sesquioxide polymorphs
  11. The ZIF system zinc(II) 4,5-dichoroimidazolate: theoretical and experimental investigations of the polymorphism and crystallization mechanisms
  12. Element allotropes and polyanion compounds of pnicogenes and chalcogenes: stability, mechanisms of formation, controlled synthesis and characterization
  13. Structure and ion dynamics of mechanosynthesized oxides and fluorides
  14. Scaled-up solvothermal synthesis of nanosized metastable indium oxyhydroxide (InOOH) and corundum-type rhombohedral indium oxide (rh-In2O3)
  15. Development and application of novel NMR methodologies for the in situ characterization of crystallization processes of metastable crystalline materials
  16. Phase formation and stability in TiOx and ZrOx thin films: Extremely sub-stoichiometric functional oxides for electrical and TCO applications
  17. Investigations on the growth of bismuth oxido clusters and the nucleation to give metastable bismuth oxide modifications
  18. Divalent metal phosphonates – new aspects for syntheses, in situ characterization and structure solution
  19. Type-I silicon clathrates containing lithium
  20. Experimental and theoretical investigation of the chromium–vanadium–antimony system
  21. Synthesis and crystal structure of three new bismuth(III) arylsulfonatocarboxylates
  22. Snapshots of calcium carbonate formation – a step by step analysis
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