Abstract
The formation and transformation of crystalline chalcogenido metalates in ionic liquids as solvents is discussed as a new synthetic approach for the generation of novel materials. A comparison to conventional solvothermal reactions, classical high-temperature syntheses and chemical solution based approaches in common is discussed.
Acknowledgments
This work was supported by the Deutsche Forschungsgemeinschaft (DFG) within the framework of SPP1415, and the Leopoldina Nationale Akademie der Wissenschaften.
References
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©2017 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Graphical Synopsis
- Editorial
- Synthesis and characterization of metastable transition metal oxides and oxide nitrides
- Control of organic polymorph formation: crystallization pathways in acoustically levitated droplets
- Thermal annealing of natural, radiation-damaged pyrochlore
- The formation of CdS quantum dots and Au nanoparticles
- Crystalline chalcogenido metalates – synthetic approaches for materials synthesis and transformation
- Fundamental theoretical and practical investigations of the polymorph formation of small amphiphilic molecules, their co-crystals and salts
- A density-functional theory approach to the existence and stability of molybdenum and tungsten sesquioxide polymorphs
- The ZIF system zinc(II) 4,5-dichoroimidazolate: theoretical and experimental investigations of the polymorphism and crystallization mechanisms
- Element allotropes and polyanion compounds of pnicogenes and chalcogenes: stability, mechanisms of formation, controlled synthesis and characterization
- Structure and ion dynamics of mechanosynthesized oxides and fluorides
- Scaled-up solvothermal synthesis of nanosized metastable indium oxyhydroxide (InOOH) and corundum-type rhombohedral indium oxide (rh-In2O3)
- Development and application of novel NMR methodologies for the in situ characterization of crystallization processes of metastable crystalline materials
- Phase formation and stability in TiOx and ZrOx thin films: Extremely sub-stoichiometric functional oxides for electrical and TCO applications
- Investigations on the growth of bismuth oxido clusters and the nucleation to give metastable bismuth oxide modifications
- Divalent metal phosphonates – new aspects for syntheses, in situ characterization and structure solution
- Type-I silicon clathrates containing lithium
- Experimental and theoretical investigation of the chromium–vanadium–antimony system
- Synthesis and crystal structure of three new bismuth(III) arylsulfonatocarboxylates
- Snapshots of calcium carbonate formation – a step by step analysis
Articles in the same Issue
- Frontmatter
- Graphical Synopsis
- Editorial
- Synthesis and characterization of metastable transition metal oxides and oxide nitrides
- Control of organic polymorph formation: crystallization pathways in acoustically levitated droplets
- Thermal annealing of natural, radiation-damaged pyrochlore
- The formation of CdS quantum dots and Au nanoparticles
- Crystalline chalcogenido metalates – synthetic approaches for materials synthesis and transformation
- Fundamental theoretical and practical investigations of the polymorph formation of small amphiphilic molecules, their co-crystals and salts
- A density-functional theory approach to the existence and stability of molybdenum and tungsten sesquioxide polymorphs
- The ZIF system zinc(II) 4,5-dichoroimidazolate: theoretical and experimental investigations of the polymorphism and crystallization mechanisms
- Element allotropes and polyanion compounds of pnicogenes and chalcogenes: stability, mechanisms of formation, controlled synthesis and characterization
- Structure and ion dynamics of mechanosynthesized oxides and fluorides
- Scaled-up solvothermal synthesis of nanosized metastable indium oxyhydroxide (InOOH) and corundum-type rhombohedral indium oxide (rh-In2O3)
- Development and application of novel NMR methodologies for the in situ characterization of crystallization processes of metastable crystalline materials
- Phase formation and stability in TiOx and ZrOx thin films: Extremely sub-stoichiometric functional oxides for electrical and TCO applications
- Investigations on the growth of bismuth oxido clusters and the nucleation to give metastable bismuth oxide modifications
- Divalent metal phosphonates – new aspects for syntheses, in situ characterization and structure solution
- Type-I silicon clathrates containing lithium
- Experimental and theoretical investigation of the chromium–vanadium–antimony system
- Synthesis and crystal structure of three new bismuth(III) arylsulfonatocarboxylates
- Snapshots of calcium carbonate formation – a step by step analysis