Metal-Organic Frameworks as bio- and heterogeneous catalyst supports for biodiesel production
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Yetzin Rodríguez Mejía
, Fernando Romero Romero
, Murali Venkata Basavanag Unnamatla
, Maria Fernanda Ballesteros Rivas
Abstract
As biodiesel (BD)/Fatty Acid Alkyl Esters (FAAE) is derived from vegetable oils and animal fats, it is a cost-effective alternative fuel that could complement diesel. The BD is processed from different catalytic routes of esterification and transesterification through homogeneous (alkaline and acid), heterogeneous and enzymatic catalysis. However, heterogeneous catalysts and biocatalysts play an essential role towards a sustainable alternative to homogeneous catalysts applied in biodiesel production. The main drawback is the supporting material. To overcome this, currently, Metal-Organic Frameworks (MOFs) have gained significant interest as supports for catalysts due to their extremely high surface area and numerous binding sites. This review focuses on the advantages of using various MOFs structures as supports for heterogeneous catalysts and biocatalysts for the eco-friendly biodiesel production process. The characteristics of these materials and their fabrication synthesis are briefly discussed. Moreover, we address in a general way basic items ranging from biodiesel synthesis to applied catalysts, giving great importance to the enzymatic part, mainly to the catalytic mechanism in esterification/transesterification reactions. We provide a summary with recommendations based on the limiting factors.
Acknowledgements
YRM acknowledges CONACYT for the support granted with CVU number 745564.
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: None declared.
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Conflict of interest statement: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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© 2022 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Metal organic frameworks (MOFS) as non-viral carriers for DNA and RNA delivery: a review
- Advances in facet-dependent photocatalytic properties of BiOCl catalyst for environmental remediation
- Recent advances on structural, thermal, vibrational, optical, phase transitions, and catalysis properties of alkylenediammonium halogenometallate materials (Metal: Bi, Sb, Halogen: Cl, Br, I)
- Transition metal complexes with strong and long-lived excited state absorption: from molecular design to optical power limiting behavior
- Metal-Organic Frameworks as bio- and heterogeneous catalyst supports for biodiesel production
Artikel in diesem Heft
- Frontmatter
- Metal organic frameworks (MOFS) as non-viral carriers for DNA and RNA delivery: a review
- Advances in facet-dependent photocatalytic properties of BiOCl catalyst for environmental remediation
- Recent advances on structural, thermal, vibrational, optical, phase transitions, and catalysis properties of alkylenediammonium halogenometallate materials (Metal: Bi, Sb, Halogen: Cl, Br, I)
- Transition metal complexes with strong and long-lived excited state absorption: from molecular design to optical power limiting behavior
- Metal-Organic Frameworks as bio- and heterogeneous catalyst supports for biodiesel production