Recent advances on structural, thermal, vibrational, optical, phase transitions, and catalysis properties of alkylenediammonium halogenometallate materials (Metal: Bi, Sb, Halogen: Cl, Br, I)

Ali Ouasri

doi:10.1515/revic-2022-0012

Article

Recent advances on structural, thermal, vibrational, optical, phase transitions, and catalysis properties of alkylenediammonium halogenometallate materials (Metal: Bi, Sb, Halogen: Cl, Br, I)

Ali Ouasri

Published/Copyright: July 7, 2022

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From the journal Reviews in Inorganic Chemistry Volume 43 Issue 2

Abstract

This paper aims to review recent advances on synthesis, crystal structures, thermal, spectroscopic, phase transitions, optical, dielectric, and catalysis properties of hydrate and anhydrous alkylenediammonium halogenometallates materials (Metal: Bi, Sb, Halogen: Cl, Br, I). These hybrid materials present rich structural diversities based on octahedra forming infinite zero dimensional, 1-dimensional chains, 2-dimensional layers, discrete bioctahedra, and discrete tetramer units. The effect, contribution and importance of hydrogen bonding N–H … X (X: Cl, Br, I) are reviewed in terms of solid state relationship. Particularly, a comparative study is made on hydrate and anyhdrous aliphatic chlorobismuthates with alkylenediammonium ⁺NH₃(CH₂)_nNH₃⁺ based on structural data and V/Z variation with (CH₂)_n chains (n = 2–8, 12), and variation of BiCl₆³⁻ Raman frequencies modes versus (CH₂)_n chains (n = 3–8). Hydrate salts with (n = 3, 12) consist of isolated BiCl₆³⁻ anions and two water molecules, against others ones with isolated anionic chains [BiCl₅²⁻]_n or Bi₂Cl₁₀⁴⁻ dimers, formed by distorted octahedra BiCl₆³⁻ sharing corners, vices or edges. The reviewed optical and electronic band gaps suggested interesting compounds with band gaps (1.85–2.4 eV), as suitable materials in optoelectronic properties, photoactive layer in solution-processed photovoltaics, and bio-imaging or photovoltaic applications. It was concluded that iodobismuthate salts have generally the lowest bands gap, compared to that of bromo and chlorobismuthate slats. Catalysis proprieties are reviewed n fast (RhB) degradation under dark conditions for (C₄N₂H₇)₄Bi₂Cl₁₀, (C₅H₉N₂)BiI₄, and {(H-BPA)₄·[(BiI₆)I₁₃]·2I₃}_n, and in organic salts synthesis under solvent-free conditions. Herein NH₃(CH₂)_nNH₃BiCl₅ (n = 5–7) salts were used as highly efficient catalysts, which is a novel tendency in chlorobismuthate researchs in the green chemistry field.

Keywords: alkylenediammonium; band gap; catalysis; crystal structure; halogenometallate; phase transition

Corresponding author: Ali Ouasri, Laboratoire (ReSIP), Centre Régional des Métiers de l’Education et de la Formation, Madinat Al Irfane, Souissi, BP 6210 Rabat, Morocco, E-mail: aouasri@yahoo.fr

Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: None declared.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2022-04-15

Accepted: 2022-06-24

Published Online: 2022-07-07

Published in Print: 2023-06-27

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Articles in the same Issue

https://doi.org/10.1515/revic-2022-0012

Keywords for this article

alkylenediammonium; band gap; catalysis; crystal structure; halogenometallate; phase transition