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Efficient enrichment of U(VI) by two-dimensional layered transition metal carbide composite

  • Yun Zhou , Huai-Xin Hao , Tian-Hao Dong , Xu-Feng Ni , Yi-Chen Hu , Jia-Ju Ma , Jun-Qiang Yang , Ke-Liang Shi , Guo-Jian Duan and Tong-Huan Liu EMAIL logo
Published/Copyright: May 2, 2022
Radiochimica Acta
From the journal Radiochimica Acta Volume 110 Issue 5

Abstract

With the rapid development of nuclear energy, how to safely and efficiently dispose of radioactive waste solution has become an urgent environmental problem of public concern. It is of great significance to construct a new type of high-efficiency adsorbent material to recover uranium from nuclear waste solution. In this work, the Ti3C2Tx material (an emerging two-dimensional inorganic layered material) with a stable layered structure was used as the matrix, and the amidoxime functionalized MXene composite material (PAO/Ti3C2Tx) was synthesized by in-situ polymerization. The amidoxime-functionalized Ti3C2Tx showed excellent capacity to capture U(VI), with a maximum adsorption capacity of 98.04 mg/g at 25 °C, which was significantly better than that of Ti3C2Tx, and the adsorption selectivity for U(VI) was greatly improved. The adsorption was conformed to Langmuir isotherm model and pseudo-second-order kinetic model. In addition, the adsorbed UO22+ could be effectively desorbed by 0.1 M HNO3, and the adsorption performance of PAO/Ti3C2Tx did not decrease significantly after 5 adsorption/desorption cycles. The results of ionic strength experiment, FT-IR, SEM, and XPS jointly indicated that adsorption mechanism of U(VI) on PAO/Ti3C2Tx was the combined effect of the amidoxime group and -O and -OH active groups on the surface of Ti3C2Tx, mainly inner complexation. These advantages make PAO/Ti3C2Tx composite a highly potential U(VI) adsorbent with great application prospects.

Keywords: adsorption; amidoximation; mechanism; PAO/Ti3C2Tx; uranium (VI)
Corresponding author: Tong-Huan Liu, Frontier Science Center for Rare Isotopes, Lanzhou University, Lanzhou 730000, P. R. China; School of Nuclear Science and Technology, Lanzhou University, 730000, Lanzhou, P. R. China; and Key Laboratory of Special Function Materials and Structure Design, Ministry of Education, Lanzhou University, 730000, Lanzhou, P. R. China, E-mail:
Y.Z. and H.H. contributed equally to this work.

Funding source: National Natural Science Foundation of China

Award Identifier / Grant number: 21762001

Award Identifier / Grant number: 22061132004

Funding source: Fundamental Research Funds for the Central Universities

Award Identifier / Grant number: lzujbky-2021-kb06

Funding source: Gansu University of Chinese Medicine

Award Identifier / Grant number: 2021CX43

Award Identifier / Grant number: 21JR1RA265

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This research was funded by the National Natural Science Foundation of China (No. 21762001 and 22061132004), Fundamental Research Funds for the Central Universities (lzujbky-2021-kb06) and Science and Technology Projects of Gansu Province (21JR1RA265) Gansu University of Chinese Medicine Postgraduate Innovation Fund Projects (2021CX43) [1].

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Supplementary Material

The online version of this article offers supplementary material (https://doi.org/10.1515/ract-2021-1130).

Received: 2021-11-24
Accepted: 2022-03-03
Published Online: 2022-05-02
Published in Print: 2022-05-25

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Original Papers
  3. Spectroscopic investigation of the different complexation and extraction properties of diastereomeric diglycolamide ligands
  4. Influence of plutonium oxidation state on the formation of molecular hydrogen, nitrous acid and nitrous oxide from alpha radiolysis of nitric acid solution
  5. Efficient enrichment of U(VI) by two-dimensional layered transition metal carbide composite
  6. Application of artificial neural networks for predicting the isotopic composition of high burn-up solid plutonium sample using the 90–105 keV gamma-spectrum region
  7. Efficient and selective adsorption of U(VI) by succinic acid modified iron oxide adsorbent
  8. Electrochemical reduction of uranium and rhenium in hydrochloric acid system
  9. A sensitive improved method for analyzing diffusion coefficients of Cs in compacted bentonite with different lengths
  10. Adsorption behavior of chromium in an aqueous suspension of δ-alumina in absence and in presence of humic substances
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https://doi.org/10.1515/ract-2021-1130
Keywords for this article
adsorption; amidoximation; mechanism; PAO/Ti3C2Tx; uranium (VI)

Articles in the same Issue

  1. Frontmatter
  2. Original Papers
  3. Spectroscopic investigation of the different complexation and extraction properties of diastereomeric diglycolamide ligands
  4. Influence of plutonium oxidation state on the formation of molecular hydrogen, nitrous acid and nitrous oxide from alpha radiolysis of nitric acid solution
  5. Efficient enrichment of U(VI) by two-dimensional layered transition metal carbide composite
  6. Application of artificial neural networks for predicting the isotopic composition of high burn-up solid plutonium sample using the 90–105 keV gamma-spectrum region
  7. Efficient and selective adsorption of U(VI) by succinic acid modified iron oxide adsorbent
  8. Electrochemical reduction of uranium and rhenium in hydrochloric acid system
  9. A sensitive improved method for analyzing diffusion coefficients of Cs in compacted bentonite with different lengths
  10. Adsorption behavior of chromium in an aqueous suspension of δ-alumina in absence and in presence of humic substances
  11. A novel theranostic probe [111In]In-DO3A-NHS-nimotuzumab in glioma xenograft
  12. Lead-free Sb-based polymer composite for γ-ray shielding purposes
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