Langmuir hydrogen dissociation approach in radiolabeling carbon nanotubes and graphene oxide
-
Gennadii A. Badun
,
Maria G. Chernysheva
Abstract
Carbon-based nanomaterials have piqued the interest of several researchers. At the same time, radioactive labeling is a powerful tool for studying processes in different systems, including biological and organic; however, the introduction of radioactive isotopes into carbon-based nanomaterial remains a great challenge. We have used the Langmuir hydrogen dissociation method to introduce tritium in single-walled carbon nanotubes and graphene oxide. The technique allows us to achieve a specific radioactivity of 107 and 27 Ci/g for single-layer graphene oxide and single-walled carbon nanotubes, respectively. Based on the analysis of characteristic Raman modes at 1350 and 1580 cm−1, a minimal amount of structural changes to the nanomaterials due to radiolabeling was observed. The availability of a simple, nondestructive, and economic technique for the introduction of radiolabels to single-walled carbon nanotubes and graphene oxide will ultimately expand the applicability of these materials.
Acknowledgement
This work was supported by Russian Foundation of Basic Research (14-03-00280, 15-33-70050, 16-08-00706).
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©2016 Walter de Gruyter GmbH, Berlin/Boston
Artikel in diesem Heft
- Frontmatter
- Cross sections for d-3H neutron interactions with samarium isotopes
- Decomposition studies of group 6 hexacarbonyl complexes. Part 2: Modelling of the decomposition process
- Recovery of Ra-223 from natural thorium irradiated by protons
- Synthesis of ordered mesoporous uranium dioxide by a nanocasting route
- Complexation of Bi3+, Ac3+, Y3+, Lu3+, La3+ and Eu3+ with benzo-diaza-crown ether with carboxylic pendant arms
- Magnesium ionophore II as an extraction agent for trivalent europium and americium
- Behavior of Cs in Grimsel granodiorite: sorption on main minerals and crushed rock
- Issues concerning the determination of solubility products of sparingly soluble crystalline solids: solubility of HfO2(cr)
- Langmuir hydrogen dissociation approach in radiolabeling carbon nanotubes and graphene oxide
Artikel in diesem Heft
- Frontmatter
- Cross sections for d-3H neutron interactions with samarium isotopes
- Decomposition studies of group 6 hexacarbonyl complexes. Part 2: Modelling of the decomposition process
- Recovery of Ra-223 from natural thorium irradiated by protons
- Synthesis of ordered mesoporous uranium dioxide by a nanocasting route
- Complexation of Bi3+, Ac3+, Y3+, Lu3+, La3+ and Eu3+ with benzo-diaza-crown ether with carboxylic pendant arms
- Magnesium ionophore II as an extraction agent for trivalent europium and americium
- Behavior of Cs in Grimsel granodiorite: sorption on main minerals and crushed rock
- Issues concerning the determination of solubility products of sparingly soluble crystalline solids: solubility of HfO2(cr)
- Langmuir hydrogen dissociation approach in radiolabeling carbon nanotubes and graphene oxide
