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Modification of kaolinite/muscovite clay for the removal of Pb(II) ions from aqueous media

  • Samuel Tetteh ORCID logo EMAIL logo , Albert Ofori , Andrew Quashie , Sirpa Jääskeläinen and Sari Suvanto
Published/Copyright: March 31, 2022
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Abstract

Natural clay extracted from the Central Region of Ghana was used for this study. Energy dispersive X-ray and powder X-ray diffraction analysis showed the composition of the clay to be 67.5% kaolinite and 32.5% muscovite. The samples were successfully modified by H2SO4 and NaOH activation. They were also characterized by scanning electron microscopic and Fourier transformed-infrared spectrophotometric techniques. Batch adsorption studies revealed that the samples are effective adsorbents for the removal of Pb(II) ions from aqueous media. Factors studied include contact time, pH, effect of ionic strength and the mass of adsorbent. Generally, the alkali activated samples had the highest adsorptive capacity followed by the acid activated clay. The kinetics of the adsorption process fitted the pseudo-second order model and the adsorption isotherm conformed to the Langmuir as well as the Freundlich models. All the experiments were carried out at room temperature (303 K).


Corresponding author: Samuel Tetteh, Department of Chemistry, School of Physical Sciences, University of Cape Coast, Cape Coast, Ghana, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Published Online: 2022-03-31

© 2022 Walter de Gruyter GmbH, Berlin/Boston

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