Development and characterization of eco-friendly biopolymer gellan gum based electrolyte for electrochemical application
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Buvaneshwari Periyajeyam
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Vengadesh Krishna Manoharan
Abstract
Magnesium ion conducting eco-friendly biopolymer electrolyte based on gellan gum has been developed by solution casting technique and characterized by XRD, FTIR, DSC, AC impedance analysis and LSV. Amorphous nature of the polymer electrolyte has been confirmed by XRD analysis. FTIR analysis confirms the complex formation between gellan gum and magnesium nitrate salt. Glass transition temperature of the polymer electrolytes have been found in DSC analysis. Ionic conductivity of polymer electrolyte membrane has been analysized by AC impedance studies, polymer electrolyte 1.0 g gellan gum with 0.7 wt% Mg (NO3)2 has highest ionic conductivity 1.392 × 10−2 S/cm at room temperature. Evan’s polarization method attributes Mg+ cationic transference number as 0.342 for high conducting polymer electrolyte. The high conducting polymer membrane has electrochemical stability 3.58 V. Using this high conducting polymer electrolyte, magnesium ion battery is constructed and the battery performance was studied. The open circuit voltage is found as 1.99 V.
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: None declared.
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
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© 2022 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Material Properties
- Development and characterization of eco-friendly biopolymer gellan gum based electrolyte for electrochemical application
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Articles in the same Issue
- Frontmatter
- Material Properties
- Development and characterization of eco-friendly biopolymer gellan gum based electrolyte for electrochemical application
- Structural transitions and rheological properties of poly-d-lysine hydrobromide: effect of pH, salt, temperature, and shear rate
- Carbon dioxide adsorption onto modified polyvinyl chloride with ionic liquid
- Synergistic effect of organic-Zn(H2PO2)2 and lithium containing polyhedral oligomeric phenyl silse-squioxane on flame-retardant, thermal and mechanical properties of poly(ethylene terephthalate)
- Preparation and Assembly
- Network structural hardening of polypropylene matrix using hybrid of 0D, 1D and 2D carbon-ceramic nanoparticles with enhanced mechanical and thermomechanical properties
- An environment friendly hemp fiber modified with phytic acid for enhancing fire safety of automobile parts
- Flexible silicone rubber/carbon fiber/nano-diamond composites with enhanced thermal conductivity via reducing the interface thermal resistance
- In situ synthesis of Ag NPs in the galactomannan based biodegradable composite for the development of active packaging films
- Engineering and Processing
- Multi-objective optimization of injection molded parts with insert based on IFOA-GRNN-NSGA-II
