Preparation of nano-SiO2 compound antioxidant and its antioxidant effect on polyphenylene sulfide
-
Wenxin Han
,
Jingyi Ren
Abstract
Polyphenylene sulfide (PPS) is easily oxidized at high temperature, which greatly limits its applications. In this study, a nano-SiO2 compound antioxidant (SiO2-g-AO) was prepared and incorporated into PPS by melt compounding to obtain PPS/SiO2-g-AO composites. SiO2-g-AO was prepared by reacting 3-(3,5-di-tert-butyl-4-hydroxyphenyl) (antioxidant AO) with an aminosilane coupling agent (KH792). Fourier transform infrared (FTIR) spectroscopy, energy dispersive spectroscopy (EDS) and thermogravimetric analysis (TGA) confirmed that the antioxidant AO was successfully immobilized on the surface of SiO2 and the thermal stability was improved. Scanning electron microscopy (SEM) images showed that SiO2-g-AO was uniformly dispersed in PPS. It has been found that the crystallinity and mechanical properties of PPS composites improved, and the dynamic oxidation induction temperature (OIT) increased in the range of 16.7°C–21.1°C. A synergistic anti-oxidation model of nanoparticles and antioxidants, namely a multi-stage antioxidant system, was established by comprehensive analysis of experimental results. The synergistic anti-oxidation model provides a new idea for the antioxidant modification of polymer composites.
Acknowledgments
The authors are grateful for the support by Shanxi Provincial Science and Technology Department Major Special Project (grant no. 2013SK02), Shanxi Province Science Foundation for Youths (grant no. 201601D202032) and Shanxi Province Applied Basic Research Project (grant no. 201801D221129).
References
[1] Mellace A, Hanson JE, Griepenburg J. Chem. Mat. 2005, 17, 1812–1817.10.1021/cm048376pSearch in Google Scholar
[2] Cao L, Deng S, He Z, Lin Z, Li M, Zhang P, Li W. J. Therm. Anal. Calorim. 2016, 125, 927–934.10.1007/s10973-016-5484-9Search in Google Scholar
[3] Deng S, Cao L, Lin Z, Qiu W, Liang K, Li W. Thermochim. Acta 2014, 584, 51–57.10.1016/j.tca.2014.03.017Search in Google Scholar
[4] Díez-Pascual AM, Naffakh M. Mater. Chem. Phys. 2012, 131, 605–614.10.1016/j.matchemphys.2011.10.025Search in Google Scholar
[5] Kim NH, Kuila T, Kim KM, Nahm SH, Lee JH. Polym. Test. 2012, 31, 537–545.10.1016/j.polymertesting.2012.02.006Search in Google Scholar
[6] Rahate AS, Nemade KR, Waghuley SA. Rev. Chem. Eng. 2013, 29, 471–489.10.1515/revce-2012-0021Search in Google Scholar
[7] Budgell DR, Day M, Cooney JD. Polym. Degrad. Stabil. 1994, 43, 109–115.10.1016/0141-3910(94)90232-1Search in Google Scholar
[8] Hawkins RT. Macromolecules 1976, 9, 189–194.10.1021/ma60050a001Search in Google Scholar
[9] Park M, Hee Lee K, Rim Choe C, Jo W. Polym. Eng. Sci. 1994, 34, 81–85.10.1002/pen.760340202Search in Google Scholar
[10] Tanthapanichakoon W, Hata M, Nitta KH, Furuuchi M, Otani Y. Polym. Degrad. Stabil. 2006, 91, 2614–2621.10.1016/j.polymdegradstab.2006.05.005Search in Google Scholar
[11] Sugama T. Mater. Lett. 2000, 43, 185–191.10.1016/S0167-577X(99)00257-8Search in Google Scholar
[12] Wan JX, Qin YF, Li SB, Wang XH. Adv. Mat. Res. 2011, 332–334, 1045–1048.10.4028/www.scientific.net/AMR.332-334.1045Search in Google Scholar
[13] Xing J, Deng B, Liu Q. Fiber Polym. 2014, 15, 1685–1693.10.1007/s12221-014-1685-7Search in Google Scholar
[14] Sugama T. Mater. Lett. 2006, 60, 2700–2706.10.1016/j.matlet.2006.01.111Search in Google Scholar
[15] Sheng XQ, Zhang RP, Niu M, Yang H, Dai JM, Gao LB. Adv. Mater. Res. 2011, 287–290, 2590–2597.10.4028/www.scientific.net/AMR.287-290.2590Search in Google Scholar
[16] Chang CY, Ju SP, Chang JW, Huang SC, Yang HW. RSC Adv. 2014, 4, 26074–26080.10.1039/c4ra02907kSearch in Google Scholar
[17] Lian D, Dai J, Zhang R, Niu M, Huang Y. Polym. Degrad. Stabil. 2016, 129, 77–86.10.1016/j.polymdegradstab.2016.04.004Search in Google Scholar
[18] Lian DD, Zhang RP, Lu JJ, Dai JM. High Perform. Polym. 2018, 30, 328–338.10.1177/0954008317696346Search in Google Scholar
[19] Echazu MIA, Olivetti CE, Peralta I, Alonso MR, Anesini C, Perez CJ, Alvarez GS, Desimone MF. Colloids Surf., B 2018, 169, 82–91.10.1016/j.colsurfb.2018.05.015Search in Google Scholar PubMed
[20] Fu Y, Yang C, Lvov YM, Zhang LQ, Wang WC. Chem. Eng. J. 2017, 328, 536–545.10.1016/j.cej.2017.06.142Search in Google Scholar
[21] Lin J, Luo YF, Zhong BC, Hu DC, Jia ZX, Jia DM. Appl. Surf. Sci. 2018, 441, 798–806.10.1016/j.apsusc.2018.02.086Search in Google Scholar
[22] Ravinayagam V, Jermy BR. J. Nanopart. Res. 2017, 19, 190–197.10.1007/s11051-017-3874-ySearch in Google Scholar
[23] Zhang JH, Zhang H, Wang ST, Liu MJ. Polym. Degrad. Stabil. 2017, 144, 93–99.10.1016/j.polymdegradstab.2017.08.006Search in Google Scholar
[24] Chen J, Yang MS, Zhang SM. Composites, Part A 2011, 42, 471–477.10.1016/j.compositesa.2011.01.006Search in Google Scholar
[25] Li H, Liang T, Li F, Wu W, Lai X, Guo J, Zeng X. Polym. Compos. 2017, 38, 1241–1247.10.1002/pc.23688Search in Google Scholar
[26] Liu P, Tang H, Lu M, Gao C, Wang F, Ding Y, Zhang S, Yang M. Polym. Degrad. Stabil. 2017, 135, 1–7.10.1016/j.polymdegradstab.2016.10.013Search in Google Scholar
[27] Zhong B, Jia Z, Hu D, Luo Y, Jia D. Composites, Part A 2015, 78, 303–310.10.1016/j.compositesa.2015.08.030Search in Google Scholar
[28] Dintcheva NT, Arrigo R, Carroccio S, Curcuruto G, Guenzi M, Gambarotti C, Filippone G. Eur. Polym. J. 2016, 75, 525–537.10.1016/j.eurpolymj.2016.01.002Search in Google Scholar
[29] Dintcheva NT, Arrigo R, Morici E, Gambarotti C, Carroccio S, Cicogna F, Filippone G. Composites, Part B 2015, 82, 196–204.10.1016/j.compositesb.2015.07.017Search in Google Scholar
[30] Fu Y, Yang C, Lvov YM, Zhang L, Wang W. Chem. Eng. J. 2017, 328, 536–445.10.1016/j.cej.2017.06.142Search in Google Scholar
[31] Shi X, Wang J, Jiang B, Yang Y. Polymer 2013, 54, 1167–1176.10.1016/j.polymer.2012.12.062Search in Google Scholar
[32] Xiaowei G, Guangjun H, Zhongzhong Q, Ding Y, Zhang S, Wang D, Yang M. Polymer 2007, 48, 7309–7315.10.1016/j.polymer.2007.10.015Search in Google Scholar
[33] Doan VA, Nobukawa S, Ohtsubo S, Tada T, Yamaguchi M. J. Appl. Polym. Sci. 2013, 128, 1848–1853.Search in Google Scholar
[34] Limwanich W, Phetsuk S, Meepowpan P, Kungwan N,Punyodom W. Chiang Mai J. Sci. 2016, 43, 329–338.Search in Google Scholar
[35] Lian DD, Dai JM, Zhang RP, Niu M. J. Therm. Anal. Calorim. 2017, 129, 377–390.10.1007/s10973-017-6196-5Search in Google Scholar
[36] Schmid M, Ritter A, Affolter S. J. Therm. Anal. Calorim. 2006, 83, 367–371.10.1007/s10973-005-7142-5Search in Google Scholar
[37] Schmid M, Affolter S. Polym. Test. 2003, 22, 419–428.10.1016/S0142-9418(02)00122-8Search in Google Scholar
© 2019 Walter de Gruyter GmbH, Berlin/Boston
Articles in the same Issue
- Frontmatter
- Material properties
- Thermal stability of xanthan gum biopolymer and its application in salt-tolerant bentonite water-based mud
- Thermal stability and dynamic mechanical behavior of functional multiphase boride ceramics/epoxy composites
- Influence of radiation-crosslinking on the elongation behaviour of glass-fibre-filled sheets in the thermoforming process
- Physicochemical and biological investigation of oxygen plasma modified electrospun polyurethane scaffolds for connective tissue engineering application
- Role of polymer/polymer and polymer/drug specific interactions in drug delivery systems
- Preparation and assembly
- Development of antimicrobial and antifouling nanocomposite membranes by a phase inversion technique
- Preparation of nano-SiO2 compound antioxidant and its antioxidant effect on polyphenylene sulfide
- Influence of mixing energy on the solid-state behavior and clay fraction threshold of PA12/C30B® nanocomposites
- Engineering and processing
- Analysis of the formation of gap-based leakages in polymer-metal electronic systems with labyrinth seals
- Effect of gas on the polymer temperature in external gas-assisted injection molding
Articles in the same Issue
- Frontmatter
- Material properties
- Thermal stability of xanthan gum biopolymer and its application in salt-tolerant bentonite water-based mud
- Thermal stability and dynamic mechanical behavior of functional multiphase boride ceramics/epoxy composites
- Influence of radiation-crosslinking on the elongation behaviour of glass-fibre-filled sheets in the thermoforming process
- Physicochemical and biological investigation of oxygen plasma modified electrospun polyurethane scaffolds for connective tissue engineering application
- Role of polymer/polymer and polymer/drug specific interactions in drug delivery systems
- Preparation and assembly
- Development of antimicrobial and antifouling nanocomposite membranes by a phase inversion technique
- Preparation of nano-SiO2 compound antioxidant and its antioxidant effect on polyphenylene sulfide
- Influence of mixing energy on the solid-state behavior and clay fraction threshold of PA12/C30B® nanocomposites
- Engineering and processing
- Analysis of the formation of gap-based leakages in polymer-metal electronic systems with labyrinth seals
- Effect of gas on the polymer temperature in external gas-assisted injection molding
