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Simultaneous toughening and reinforcing of cyanate ester/benzoxazine resins with improved mechanical and thermal properties by using hyperbranched polyesters

  • Abdeldjalil Zegaoui , Mehdi Derradji , Ruikun Ma , Wan-an Cai , Aboubakr Medjahed , Wen-bin Liu EMAIL logo , Abdul Qadeer Dayo , Jun Wang , Li-li Zhang and Youcef Ramdani
Published/Copyright: August 7, 2018
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Journal of Polymer Engineering
From the journal Journal of Polymer Engineering Volume 38 Issue 9

Abstract

In the present study, the influence of incorporating various amounts of hyperbranched polyester (HBPE) into thermosetting resin blends composed of cyanate ester (CE) and benzoxazine (BOZ) resins was investigated for their structural, morphological, mechanical, and thermal properties. The FTIR spectra revealed that the CE/BOZ resin had reacted with the functional groups of HBPE, and the SEM test confirmed the morphological changes from a smooth surface that was observed for the virgin CE/BOZ resin to a rough surface for the maximum HBPE content. Moreover, the mechanical and thermal properties were found to be pointedly enhanced as we increased the content of HBPE. These remarkable enhancements may be due to the chemical structure of the HBPE which could form a cross-linked structure through a strong hydrogen bonding with the CE/BOZ resin. As a result, a considerable amount of applied mechanical load can be absorbed, and in parallel, the thermal stability can also be improved. We believe that the HBPE can be a good toughener for the CE/BOZ resins that could possibly expand their range of applications in various industrial sectors.

Keywords: benzoxazine; cyanate ester; hyperbranched polyester (HBPE); mechanical properties; thermal properties

Funding source: National Natural Science Foundation of China

Award Identifier / Grant number: 51773048

Funding source: Natural Science Foundation of Heilongjiang Province

Award Identifier / Grant number: E2017022

Funding statement: The authors greatly appreciate the financial support from the National Natural Science Foundation of China (project no. 51773048), the Natural Science Foundation of Heilongjiang Province (Funder Id 10.13039/501100005046, project no. E2017022), and the Fundamental Research Funds for the Central Universities (project nos. HEUCF201724, HEUCF201791).

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Received: 2017-10-24
Accepted: 2018-04-26
Published Online: 2018-08-07
Published in Print: 2018-10-25

©2018 Walter de Gruyter GmbH, Berlin/Boston

Articles in the same Issue

  1. Frontmatter
  2. Material properties
  3. Structure mediation and ductility enhancement of poly(l-lactide) by random copolymer poly(d-lactide-co-ε-caprolactone)
  4. Morphological characterization, thermal, and mechanical properties of compatibilized high density polyethylene/polystyrene/organobentonite ternary nanocomposites
  5. Preparation and assembly
  6. Simultaneous toughening and reinforcing of cyanate ester/benzoxazine resins with improved mechanical and thermal properties by using hyperbranched polyesters
  7. Surface modification of Sb-SnO2/potassium titanate composite and their performance for acrylic coatings
  8. Poly (vinyl alcohol)/nano-diamond composite films and hydrogels prepared by gamma ray
  9. Engineering and processing
  10. Study on structures and properties of ultra-hot drawing UHMWPE fibers fabricated via dry spinning method
  11. Separation of CO2/CH4 and O2/N2 by polysulfone hollow fiber membranes: effects of membrane support properties and surface coating materials
  12. Electric field-induced alignment of MWCNTs during the processing of PP/MWCNT composites: effects on electrical, dielectric, and rheological properties
  13. A molecular modeling study for miscibility of polyimide/polythene mixing systems with/without compatibilizer
  14. Analysis and quantitative estimation of phenolic antioxidants in polypropylene packaging for fat products
  15. Effects of ultrasonic injection molding conditions on the plate processing characteristics of PMMA
https://doi.org/10.1515/polyeng-2017-0376
Keywords for this article
benzoxazine; cyanate ester; hyperbranched polyester (HBPE); mechanical properties; thermal properties

Articles in the same Issue

  1. Frontmatter
  2. Material properties
  3. Structure mediation and ductility enhancement of poly(l-lactide) by random copolymer poly(d-lactide-co-ε-caprolactone)
  4. Morphological characterization, thermal, and mechanical properties of compatibilized high density polyethylene/polystyrene/organobentonite ternary nanocomposites
  5. Preparation and assembly
  6. Simultaneous toughening and reinforcing of cyanate ester/benzoxazine resins with improved mechanical and thermal properties by using hyperbranched polyesters
  7. Surface modification of Sb-SnO2/potassium titanate composite and their performance for acrylic coatings
  8. Poly (vinyl alcohol)/nano-diamond composite films and hydrogels prepared by gamma ray
  9. Engineering and processing
  10. Study on structures and properties of ultra-hot drawing UHMWPE fibers fabricated via dry spinning method
  11. Separation of CO2/CH4 and O2/N2 by polysulfone hollow fiber membranes: effects of membrane support properties and surface coating materials
  12. Electric field-induced alignment of MWCNTs during the processing of PP/MWCNT composites: effects on electrical, dielectric, and rheological properties
  13. A molecular modeling study for miscibility of polyimide/polythene mixing systems with/without compatibilizer
  14. Analysis and quantitative estimation of phenolic antioxidants in polypropylene packaging for fat products
  15. Effects of ultrasonic injection molding conditions on the plate processing characteristics of PMMA
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