Analysis and quantitative estimation of phenolic antioxidants in polypropylene packaging for fat products
-
Hakim Baloul
,
Naima Belhaneche-Bensemra
,
Ana Rodriguez Bernaldo De Quirós
Abstract
The aim of this work was to study the interactions between polypropylene (PP) food packaging for fatty products (margarine) and food simulant. For this purpose, a simulant (olive oil) was used in two different temperatures (20°C and 40°C). The interaction phenomena were investigated according to the rate of mass variation of PP samples with time and by using Fourier transform infrared spectroscopy, scanning electron microscopy and high-performance liquid chromatography (HPLC). The results showed the presence of two phenomena – migration of additives and sorption of the simulant, with the phenomena more pronounced at 40°C. Furthermore, the HPLC analysis identified the presence of Irganox 1010 and Irgafos 168 as antioxydants and allowed to carry out a kinetic study of Irganox 1010 migration. The concentration of Irganox 1010 decreased from 13.35 to 4.76 mg/kg at a temperature of 40°C and to 5.85 mg/kg at a temperature of 20°C after 10 days of contact with olive oil. The Irgafos 168 migration could not be evaluated because it is very sensitive to oxidation.
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Articles in the same Issue
- Frontmatter
- Material properties
- Structure mediation and ductility enhancement of poly(l-lactide) by random copolymer poly(d-lactide-co-ε-caprolactone)
- Morphological characterization, thermal, and mechanical properties of compatibilized high density polyethylene/polystyrene/organobentonite ternary nanocomposites
- Preparation and assembly
- Simultaneous toughening and reinforcing of cyanate ester/benzoxazine resins with improved mechanical and thermal properties by using hyperbranched polyesters
- Surface modification of Sb-SnO2/potassium titanate composite and their performance for acrylic coatings
- Poly (vinyl alcohol)/nano-diamond composite films and hydrogels prepared by gamma ray
- Engineering and processing
- Study on structures and properties of ultra-hot drawing UHMWPE fibers fabricated via dry spinning method
- Separation of CO2/CH4 and O2/N2 by polysulfone hollow fiber membranes: effects of membrane support properties and surface coating materials
- Electric field-induced alignment of MWCNTs during the processing of PP/MWCNT composites: effects on electrical, dielectric, and rheological properties
- A molecular modeling study for miscibility of polyimide/polythene mixing systems with/without compatibilizer
- Analysis and quantitative estimation of phenolic antioxidants in polypropylene packaging for fat products
- Effects of ultrasonic injection molding conditions on the plate processing characteristics of PMMA
