Startseite Synthesis of a novel silicone based copolymeric surfactant and application in emulsion polymerization
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Synthesis of a novel silicone based copolymeric surfactant and application in emulsion polymerization

  • Hamid Javaherian Naghash EMAIL logo und Mohammad Hossein Sheikhbahaei
Veröffentlicht/Copyright: 23. November 2013
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Abstract

A novel silicone-containing acrylic monomer, trimethylsiloxybutoxy dimethylsiloxybutyl acrylate (TSBA) and diethylene glycol monoallyl ether (DGME) was synthesized successfully. Then, a novel copolymeric surfactant was prepared by the free radical polymerization of TSBA and DGME in the presence of dioxane and azobisisobutyronitrile (AIBN) as a solvent and initiator, respectively. Next, a series of polyvinyl acetate (PVAc), 2-ethylhexyl acrylate (2-EHA) and polystyrene (PSt) latexes were successfully synthesized, each one throughout by the emulsion copolymerization in the presence of a copolymeric surfactant. This copolymeric surfactant exhibited excellent surface activity and the surface tension decreased with an increase in the concentration of the copolymeric surfactant.


Corresponding author: Hamid Javaherian Naghash, Department of Chemistry, Shahreza Branch, Islamic Azad University, P.O. Box 311-86145, Shahreza, Isfahan, I. R. Iran, e-mail:

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Received: 2013-7-3
Accepted: 2013-9-20
Published Online: 2013-11-23
Published in Print: 2013-12-01

©2013 by Walter de Gruyter Berlin Boston

Heruntergeladen am 3.12.2025 von https://www.degruyterbrill.com/document/doi/10.1515/polyeng-2013-0156/pdf?lang=de
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