Acoustic parameter investigation of polyvinyl acetate with acetic acid using ultrasonic technique
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Baljinder Kaur
Abstract
Density, viscosity and ultrasonic velocity of polyvinyl acetate with acetic acid have been measured at a temperature of 299K for different concentrations. Density and viscosity have been measured for a binary liquid mixture with a specific gravity bottle and a viscometer. Ultrasonic velocity has been measured using a single crystal interferometer at a frequency of 2 MHz. Ultrasonic velocities for the binary mixture at 1 MHz and 2 MHz was compared by taking some values from the literature. The sound velocity (V), density (ρ) and viscosity (η) were used to calculate the parameters such as adiabatic compressibility (β), acoustic impedance (Z), intermolecular free length (Lf), ultrasonic attenuation (α/f2) and relaxation time (τ). The variations of experimentally obtained parameters indicate the presence of molecular interaction between the molecules of the mixture. The ultrasonic velocity increased with an increase in concentration. Solute-solvent interaction is further confirmed by viscosity values, which increased with increasing concentration suggesting more association between solute and solvent molecules. The linear variations in Rao’s constant and Wada’s constant suggest the absence of complex formation.
References
[1] Yu KH, Rhee JM. Bull. Korean Chem. Soc. 2002, 23, 633–636.Suche in Google Scholar
[2] Krishnamurthi P, Balamuralikrishnan S. J. Convergence Eng. Technol. Sci. 2009, 1, 23.Suche in Google Scholar
[3] Priya CS, Nithya S, Velraj G, Kannappan AN. Int. J. Adv. Sci. Technol. 2010, 18, 59–72.Suche in Google Scholar
[4] Jacobson B. Acta Chem. Scand. 1952, 6, 1485–1498.Suche in Google Scholar
[5] Jacobson B, Heedman PA. Acta Chem. Scand. 1953, 7, 705–712.Suche in Google Scholar
[6] Venis R, Rajkumar R. J. Chem. Pharm. Res. Res. 2011, 3, 878–885.Suche in Google Scholar
[7] Nath G, Sahu S, Paikaray R. Ind. J. Phys. 2009, 83, 1567–1574.Suche in Google Scholar
[8] Selvakumar M, Krishna. Ind. J. Pure Appl. Phys. 2008, 46, 712.Suche in Google Scholar
[9] Saxena R, Bhatt S. Int. J. Chem. 2010, 2, 164.Suche in Google Scholar
[10] Singh P, Bhatt SC. J. Appl. Phys. Res. 2010, 2, 35.Suche in Google Scholar
[11] Yadava SS. Chem. Mater. Sci. 1995, 126, 529.Suche in Google Scholar
[12] Venis R, Rajkumar R. J. Chem. Pharm. Res. 2011, 3, 878–885.Suche in Google Scholar
[13] Vadamalar R, Mani D, Balakrishnan R. Res. J. Chem. Sci. 2011, 1, 79–82.Suche in Google Scholar
[14] Arivazhagan G, Mahalakshmi M, Jeenathus Zahira SA. Ind. J. Phys. 2012, 86, 493–496.Suche in Google Scholar
[15] Selvakumar M, Krishna. Ind. J. Pure Appl. Phys. 2008, 46, 712–718.Suche in Google Scholar
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Artikel in diesem Heft
- Masthead
- Masthead
- Original articles
- Solvent-initiator compatibility and sensitivity of conversion of styrene homo-polymerization
- Synthesis and effect of secondary dopant on the conductivity of conducting polymer polyaniline
- Potential utilization of recycled PET in comparison with liquid crystalline polymer as an additive for HDPE based composite fibers: Comparative investigation on mechanical performance of cross-ply laminates
- Study on the effect of virgin and recycled chloroprene rubber (vCR and rCR) on the properties of natural rubber/chloroprene rubber (NR/CR) blends
- Synthesis of a novel silicone based copolymeric surfactant and application in emulsion polymerization
- Post-irradiation effects on gamma-irradiated nylon 6,12 fibers
- Preparation and properties of sodium alginate films
- Study on crystallization and compatibility of nitrile butadiene rubber (NBR)/polyoxymethlene (POM) blends modified by a polyether polyol
- Polyamide grafting onto ethylene-vinyl alcohol copolymer
- Acoustic parameter investigation of polyvinyl acetate with acetic acid using ultrasonic technique
- Electrospun cellulosic structure nanofibre based on rice straw
- Function of silicon oil in the castor oil based rigid polyurethane foams
