Startseite The accurate assessment of the chemical speciation of complex systems through multi-technique approaches
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The accurate assessment of the chemical speciation of complex systems through multi-technique approaches

  • Anna Baryłka , Beata Godlewska-Żyłkiewicz , Demetrio Milea EMAIL logo und Sofia Gama EMAIL logo
Veröffentlicht/Copyright: 23. April 2024
Pure and Applied Chemistry
Aus der Zeitschrift Pure and Applied Chemistry Band 96 Heft 4

Abstract

Chemical speciation studies, i.e., the study of the distribution of an element or compound among its various species in a system of interest, are of fundamental importance. Chemical speciation investigations can be performed mainly by either the direct measurement of the chemical species by different analytical techniques, or by chemical modeling through equilibrium thermodynamic data, based on the use of stability constants (and other thermodynamic parameters) of the formed species. For these purposes, a series of techniques can be used. As soon as the complexity of the systems of interest increases, the need for more detailed information arises. As such, a multi-technique approach is essential to derive complementary data to define a chemical system. In this tutorial review we analyzed the most common instrumental techniques employed for chemical speciation studies and equilibrium data analysis. The main advantages and disadvantages of potentiometry, voltammetry, coulometry, UV–vis spectrophotometry, spectrofluorimetry, NMR, EPR, ITC, HRMS and quantum mechanical calculations, together with brief mention to other less common techniques, are discussed together with a series of practical examples of their application. The main aim of this tutorial review is to provide a practical guide to all scientists interested in the field.

Keywords: Chemical speciation; equilibrium data analysis; ICSC-38; instrumental techniques; multi-technique approach; solution chemistry; solution equilibria; thermodynamic data
Corresponding authors: Demetrio Milea, Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali, CHIBIOFARAM, Università degli Studi di Messina, Viale F. Stagno d’Alcontres 31, 98166 Messina, Italy, e-mail: ; and Sofia Gama, C2TN – Centro de Ciências e Tecnologias Nucleares, Instituto Superior Técnico, Universidade de Lisboa, Estrada Nacional 10 (km 139.7), 2695-066, Bobadela LRS, Portugal, e-mail:
Article note: A collection of invited papers based on presentations at the 38th International Conference on Solution Chemistry.

Acknowledgments

The authors would like to thank the financial support from the National Science Centre (NCN), Poland, under the scope of the research project number 2020/39/B/ST4/03060 and COST (European Cooperation in Science and Technology), as this publication is based upon work from COST Action CA18202 – NECTAR, Network for Equilibria and Chemical Thermodynamics Advanced Research.

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Published Online: 2024-04-23
Published in Print: 2024-04-25

© 2024 IUPAC & De Gruyter

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Preface
  4. Avogadro Colloquia in Rome on “Vision and Opportunities of a Sustainable Hydrogen Society”
  5. Conference papers
  6. H2 in the energy transition
  7. Watching atoms at work during reactions
  8. Hydrogen production and conversion to chemicals: a zero-carbon puzzle?
  9. Rethinking chemical production with “green” hydrogen
  10. Hydrogen as an energy carrier: constraints and opportunities
  11. Shaping the future of green hydrogen: De Nora’s electrochemical technologies for fueling the energy transition
  12. In-situ and operando Grazing Incidence XAS: a novel set-up and its application to model Pd electrodes for alcohols oxidation
  13. Hydrogen storage and handling with hydrides
  14. Advanced polymer electrolyte membrane water electrolysis for power to gas applications
  15. Inkjet printed acrylate-urethane modified poly(3,4-ethylenedioxythiophene) flexible conductive films
  16. Cu(II) complexes using acylhydrazones or cyclen for biocidal antifouling coatings
  17. Randomly cross-linked amphiphilic copolymer networks of n-butyl acrylate and N,N-dimethylacrylamide: synthesis and characterization
  18. Roles of electrostatics and intermolecular electronic motions in the structural and spectroscopic features of hydrogen- and halogen-bonded systems
  19. The accurate assessment of the chemical speciation of complex systems through multi-technique approaches
https://doi.org/10.1515/pac-2024-0206
Schlagwörter für diesen Artikel
Chemical speciation; equilibrium data analysis; ICSC-38; instrumental techniques; multi-technique approach; solution chemistry; solution equilibria; thermodynamic data

Artikel in diesem Heft

  1. Frontmatter
  2. In this issue
  3. Preface
  4. Avogadro Colloquia in Rome on “Vision and Opportunities of a Sustainable Hydrogen Society”
  5. Conference papers
  6. H2 in the energy transition
  7. Watching atoms at work during reactions
  8. Hydrogen production and conversion to chemicals: a zero-carbon puzzle?
  9. Rethinking chemical production with “green” hydrogen
  10. Hydrogen as an energy carrier: constraints and opportunities
  11. Shaping the future of green hydrogen: De Nora’s electrochemical technologies for fueling the energy transition
  12. In-situ and operando Grazing Incidence XAS: a novel set-up and its application to model Pd electrodes for alcohols oxidation
  13. Hydrogen storage and handling with hydrides
  14. Advanced polymer electrolyte membrane water electrolysis for power to gas applications
  15. Inkjet printed acrylate-urethane modified poly(3,4-ethylenedioxythiophene) flexible conductive films
  16. Cu(II) complexes using acylhydrazones or cyclen for biocidal antifouling coatings
  17. Randomly cross-linked amphiphilic copolymer networks of n-butyl acrylate and N,N-dimethylacrylamide: synthesis and characterization
  18. Roles of electrostatics and intermolecular electronic motions in the structural and spectroscopic features of hydrogen- and halogen-bonded systems
  19. The accurate assessment of the chemical speciation of complex systems through multi-technique approaches
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