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An antimicrobial acrylic polyurethane coating with TiO2-Ag hybrid nanoparticles

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Published/Copyright: June 3, 2024
Pure and Applied Chemistry
From the journal Pure and Applied Chemistry Volume 96 Issue 8

Abstract

The purpose of this work is to fabricate the advanced organic antibacterial coating containing the strong photocatalytic nanomaterials. For this purpose, firstly the TiO2–Ag hybrid nanoparticles are synthesized by chemical reduction method. Then, the antibacterial coating based on acrylic polyol, polyisocyanate, and these TiO2–Ag hybrid nanoparticles has been prepared. Mechanical properties show that the optimal content of TiO2–Ag hybrid nanoparticles in the coating matrix is 2 wt%, with its abrasion resistance of 166.2 L/mil; impact strength of 195 kg cm; adhesion of size #1 and relative hardness of 0.78. In addition, FE-SEM analysis shows that the nanocomposite coating has a tight structure with homogeneous dispersion of TiO2–Ag nanoparticles in the polymer matrix. The paint film has good antibacterial activity and has great application prospects. Data from the antibacterial test indicates that in the presence of an acrylic polyurethane coating containing 2 wt% TiO2–Ag, the number of viable Escherichia coli decreased from 3.4 × 105 CFU/ml to 1.5 × 102 CFU/ml after 24 h of culture.

Keywords: Acrylic polyurethane coating; advanced materials for environmental protection; antibacterial activity; TiO2–Ag hybrid nanoparticles
Corresponding author: Thien Vuong Nguyen, VNU-University of Education, Vietnam National University, Hanoi, Vietnam; and Institute for Tropical Technology, VAST, 18 Hoang Quoc Viet, Cau Giay, Hanoi, Vietnam, E-mail:
Article note: A collection of invited papers on the advanced materials for environmental protection.

Funding source: Vietnam Academy of Science and Technology

Award Identifier / Grant number: Grant # NCPTVL.05/24-26

  1. Research funding: The authors would like to thank the funding provided by the Vietnam Academy of Science and Technology’s Foundation for Material Science (NCPTVL.05/24-26).

References

[1] M. M. M’Arimi, C. A. Mecha, A. K. Kiprop, R. Ramkat. Renew. Sustain. Energy Rev. 121, 109669 (2020), https://doi.org/10.1016/j.rser.2019.109669.Search in Google Scholar

[2] L. Li, M. Ma, S. Guan, H. Wu. Res. Chem. Intermed. 44, 4365 (2018), https://doi.org/10.1007/s11164-018-3392-2.Search in Google Scholar

[3] Y. Li, Y. Wang, L. Liu, D. Wang, W. Zhang. Environ. Sci. Pollut. Res. 21, 5177 (2014), https://doi.org/10.1007/s11356-013-2133-8.Search in Google Scholar PubMed

[4] T. Luttrell, S. Halpegamage, J. Tao, A. Kramer, E. Sutter, M. Batzill. Sci. Rep. 4, 4043 (2014), https://doi.org/10.1038/srep04043.Search in Google Scholar PubMed PubMed Central

[5] A. Karami. J. Iran. Chem. Soc. 7, S154 (2010), https://doi.org/10.1007/BF03246194.Search in Google Scholar

[6] J. Wang, R. Li, L. Zhang, Y. Xie, Z. Jiang, R. Xu. Russ. J. Inorg. Chem. 55, 692 (2010), https://doi.org/10.1134/S0036023610050074.Search in Google Scholar

[7] M. Qua, L. Xinchuan, X. Chao, X. Fan, W. Yongqian, M. Dawei. J. Electron. Mater. 46, 347 (2017), https://doi.org/10.1007/s11664-016-4966-7.Search in Google Scholar

[8] A. Phuruangrat, P. Dumrongrojthanath, O. Yayapao, J. Arin, S. Thongtem, T. Thongtem. Rare Met. 35, 390 (2016), https://doi.org/10.1007/s12598-015-0508-3.Search in Google Scholar

[9] A. Priya, R. Senthil, A. Selvi, P. Arunachalam, C. Senthil Kumar, J. Madhavan. Mater. Sci. Energy Technol. 3, 43 (2020), https://doi.org/10.1016/j.mset.2019.09.013.Search in Google Scholar

[10] L. Tang, J. Wang, X. Liu, X. Shu, Z. Zhang, J. Wang. Renewable Energy 138, 474 (2019), https://doi.org/10.1016/j.renene.2019.01.113.Search in Google Scholar

[11] K. Awazu, M. Fujimaki, C. Rockstuhl, J. Tominaga, H. Murakami, Y. Ohki, N. Yoshida, T. Watanabe. J. Am. Chem. Soc. 130, 1676 (2008), https://doi.org/10.1021/ja076503n.Search in Google Scholar PubMed

[12] C. B. Ong, L. Y. Ng, A. W. Mohammad. Renew. Sustain. Energy Rev. 81, 536 (2018), https://doi.org/10.1016/j.rser.2017.08.020.Search in Google Scholar

[13] B. L. Martínez-Vargas, S. M. Durón-Torres, D. Bahena, J. L. Rodríguez-López, A. Picos. J. Phys. Chem. Solids 135, 109120 (2019), https://doi.org/10.1016/j.jpcs.2019.109120.Search in Google Scholar

[14] M. F. Abdel Messih, M. A. Ahmed, A. Soltan, S. Sobhy Anis. J. Phys. Chem. Solids 135, 109086 (2019), https://doi.org/10.1016/j.jpcs.2019.109086.Search in Google Scholar

[15] T. A. T. Pham, V. A. Tran, V. D. Le, M. V. Nguyen, D. D. Truong, X. T. Do. Int. J. Photoenergy 2020, 8897667 (2020), https://doi.org/10.1155/2020/8897667.Search in Google Scholar

[16] X. Tan, S. Zhou, H. Tao, W. Wang, Q. Wan, K. Zhang. J. Cent. South Univ. 26, 2011 (2019), https://doi.org/10.1007/s11771-019-4148-x.Search in Google Scholar

[17] S. Seong, I. S. Park, Y. C. Jung, T. Lee, S. Y. Kim, J. S. Park. Mater. Design 177, 107831 (2019), https://doi.org/10.1016/j.matdes.2019.107831.Search in Google Scholar

[18] G. O. Rabell, M. R. A. Cruz, I. Juárez-Ramírez. Mater. Sci. Semicond. Process. 134, 105985 (2021), https://doi.org/10.1016/j.mssp.2021.105985.Search in Google Scholar

[19] A. Saboor, S. M. Shah, H. Hussain. Mater. Sci. Semicond. Process. 93, 215 (2019), https://doi.org/10.1016/j.mssp.2019.01.009.Search in Google Scholar

[20] H. Liu, J. Feng, W. Jie. J. Mater. Sci. Mater. Electron. 28, 16585 (2017), https://doi.org/10.1007/s10854-017-7612-0.Search in Google Scholar

[21] Y. Xia, R. Gang, L. Xu, S. Huang, L. Zhou, J. Wang. Ceram. Int. 46, 1487 (2020), https://doi.org/10.1016/j.ceramint.2019.09.115.Search in Google Scholar

[22] S. S. Naik, S. J. Lee, T. Begildayeva, Y. Yu, H. Lee, M. Y. Choi. Environ. Pollut. 266, 115247 (2020), https://doi.org/10.1016/j.envpol.2020.115247.Search in Google Scholar PubMed

[23] A. M. El Saeed, M. Abd El-Fattah, A. M. Azzam. Dyes Pigm. 121, 282 (2015), https://doi.org/10.1016/j.dyepig.2015.05.037.Search in Google Scholar

[24] Y. Wattanodorn, R. Jenkan, P. Atorngitjawat, S. Wirasate. Polym. Test. 40, 163 (2014), https://doi.org/10.1016/j.polymertesting.2014.09.004.Search in Google Scholar

[25] A. Labbani Motlagh, S. Bastani, M. M. Hashemi. Prog. Org. Coat. 77, 502 (2014), https://doi.org/10.1016/j.porgcoat.2013.11.014.Search in Google Scholar

[26] T. N. L. Nguyen, T. Vy Do, T. V. Nguyen, P. Hung Dao, A. H. Nguyen, D. A. Dinh, T. A. Nguyen, T. K. A. Vo, T. Lu Le. Prog. Organ. Coat. 132, 15 (2019), https://doi.org/10.1016/j.porgcoat.2019.02.023.Search in Google Scholar

[27] T. V. Nguyen, T. V. Do, M. Hung Ha, K. L. Hai, T. Tam Le, T. N. L. Nguyen, X. T. Dam, Q. T. Vu, D. A. Dinh, C. D. Tran, P. Nguyen-Tri. Prog. Organ. Coat. 139, 105325 (2020), https://doi.org/10.1016/j.porgcoat.2019.105325.Search in Google Scholar

[28] T. L. The, T. V. Nguyen, T. A. Nguyen, T. T. H. Nguyen, H. Thai, D. A. Dinh, T. M. Nguyen. Mater. Chem. Phys. 232, 362 (2019), https://doi.org/10.1016/j.matchemphys.2019.05.001.Search in Google Scholar

[29] V. Do Truc, T. V. Nguyen, T. V. Vu, T. A. Nguyen, T. D. Ngo, T. Tam Le, T. Lu Le, L. T. Pham, D. T. Lam. ChemistrySelect 8, e202204966 (2023), https://doi.org/10.1002/slct.202204966.Search in Google Scholar

[30] T. V. Nguyen, V. Do Truc, T. A. Nguyen, T. L. Pham, D. L. Tran. J. Clust. Sci. 34, 3061 (2023), https://doi.org/10.1007/s10876-023-02448-1.Search in Google Scholar

[31] T. V. Do, M. N. Ha, T. A. Nguyen, H. T. Ha, T. V. Nguyen. Adsorpt. Sci. Technol. 2021, 7387160 (2021), https://doi.org/10.1155/2021/7387160.Search in Google Scholar

[32] T. V. Nguyen, T. Vy Do, T. D. Ngo, T. A. Nguyen, L. T. Lu, Q. T. Vu, L. P. Thi, D. L. Tran. RSC Adv. 12, 23346 (2022), https://doi.org/10.1039/D2RA03546D.Search in Google Scholar

[33] T. V. Nguyen, V. Do Truc, L. P. Thi, D. L. Tran. Colloid Polym. Sci. 302, 225 (2024), https://doi.org/10.1007/s00396-023-05193-z.Search in Google Scholar

[34] N. L. Nguyen, T. M. L. Dang, T. A. Nguyen, H. T. Ha, T. V. Nguyen. J. Nanomater. 2021, 8493201 (2021), https://doi.org/10.1155/2021/8493201.Search in Google Scholar
Published Online: 2024-06-03
Published in Print: 2024-08-27

© 2024 IUPAC & De Gruyter

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Preface
  4. Special issue on “Advanced materials for environmental protection and sustainability in Asean countries”
  5. Special topic papers
  6. Nanocomposite nanofibrous membranes of graphene and graphene oxide: water remediation potential
  7. Selection of graphene as a conductive additive for biomass-based activated carbon electrode in capacitive deionization: acid-treated as a practical approach to reduce graphene content
  8. Biochar-based catalysts: a potential disposal of plant biomass from phytoremediation
  9. Bio-based aerogel composites of coconut pith-derived carbon and chitosan for efficient anionic dye-polluted water treatment
  10. Study on synthesizing the complex of sorafenib with 2-hydroxypropyl-β-cyclodextrin to enhance the anticancer activity of the drug substance
  11. An antimicrobial acrylic polyurethane coating with TiO2-Ag hybrid nanoparticles
  12. Efficient synthesis of tricaproin: catalyst and reaction optimization
  13. Enhanced photocatalytic and antibacterial properties of silver–zirconia nanoparticles for environmental pollution treatment
  14. Preparation of sulfur nanoparticles in chitosan-copper complex and investigation of its nematicidal activity against Pratylenchus pratensis in vitro
  15. Fabrication of cathode electrodes based on activated carbon, reduced-graphene for hybrid capacitive deionization technology
  16. Biodegradable thermochromic polylactic acid (PLA) sensor
  17. Effect of ground tyre rubber content on self-healing properties of natural rubber composites
  18. Preparation of composite based on MXene-Ti3C2 and coconutshell-derived activated carbon for desalination of brackish water
  19. Producing an antibacterial acrylic polyurethane coating with acylated mimosa tannins
  20. Effect of multi-walled carbon nanotubes reinforcement on self-healing performance of natural rubber
  21. Mechanical properties of web kapok/fiberglass-epoxy hybrid composites for marine structures
  22. Investigation on recycling and reprocessing ability of self-healing natural rubber based on ionic crosslink network
https://doi.org/10.1515/pac-2024-0019
Keywords for this article
Acrylic polyurethane coating; advanced materials for environmental protection; antibacterial activity; TiO2–Ag hybrid nanoparticles

Articles in the same Issue

  1. Frontmatter
  2. In this issue
  3. Preface
  4. Special issue on “Advanced materials for environmental protection and sustainability in Asean countries”
  5. Special topic papers
  6. Nanocomposite nanofibrous membranes of graphene and graphene oxide: water remediation potential
  7. Selection of graphene as a conductive additive for biomass-based activated carbon electrode in capacitive deionization: acid-treated as a practical approach to reduce graphene content
  8. Biochar-based catalysts: a potential disposal of plant biomass from phytoremediation
  9. Bio-based aerogel composites of coconut pith-derived carbon and chitosan for efficient anionic dye-polluted water treatment
  10. Study on synthesizing the complex of sorafenib with 2-hydroxypropyl-β-cyclodextrin to enhance the anticancer activity of the drug substance
  11. An antimicrobial acrylic polyurethane coating with TiO2-Ag hybrid nanoparticles
  12. Efficient synthesis of tricaproin: catalyst and reaction optimization
  13. Enhanced photocatalytic and antibacterial properties of silver–zirconia nanoparticles for environmental pollution treatment
  14. Preparation of sulfur nanoparticles in chitosan-copper complex and investigation of its nematicidal activity against Pratylenchus pratensis in vitro
  15. Fabrication of cathode electrodes based on activated carbon, reduced-graphene for hybrid capacitive deionization technology
  16. Biodegradable thermochromic polylactic acid (PLA) sensor
  17. Effect of ground tyre rubber content on self-healing properties of natural rubber composites
  18. Preparation of composite based on MXene-Ti3C2 and coconutshell-derived activated carbon for desalination of brackish water
  19. Producing an antibacterial acrylic polyurethane coating with acylated mimosa tannins
  20. Effect of multi-walled carbon nanotubes reinforcement on self-healing performance of natural rubber
  21. Mechanical properties of web kapok/fiberglass-epoxy hybrid composites for marine structures
  22. Investigation on recycling and reprocessing ability of self-healing natural rubber based on ionic crosslink network
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