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Catalytic Degradation of Safranin T in Aqueous Medium Using Non-conventional Processes

  • V. Sydorchuk EMAIL logo , S. Khalameida , B. Charmas , J. Skubiszewska-Zięba , V. Zazhigalov and L. Davydenko
Published/Copyright: February 3, 2017
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Abstract

Eleven TiO2 powders as catalysts have been studied in process of safranin T degradation in aqueous medium using mechanochemical, microwave and ultrasonic techniques. The degree of degradation has been controlled by means of spectrophotometric analysis of safranin T solutions before and after treatment and total organic carbon measurements. XRD, DTA-TG and BET analysis, FTIR spectroscopy and mass spectrometry of initial and spent catalysts have been carried out for explanation of obtained results. It has been established that the catalytic activity of TiO2 under mechanochemical treatment depends on phase composition and dispersity (specific surface area). Particularly, catalytic activity of mono-phase titanias inversely depends on specific surface area of initial catalyst. Sono- and microwave catalytic degradation were less effective.

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Received: 2016-7-5
Revised: 2016-10-7
Accepted: 2016-10-13
Published Online: 2017-2-3
Published in Print: 2017-1-1

© 2017 by Walter De Gruyter GmbH

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