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Synthesis, Characterisation and Dissociation of a Glycinate Bridged Trinuclear Co(III)-Cu(II)-Co(III) Complex
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Ν. N. Das
Veröffentlicht/Copyright:
1. Januar 2003
Abstract
A trinuclear complex, [{(NH3)5Co(O2CCH2NH)}2Cu](ClO4)6.2H2O has been synthesised using mononuclear glycinato(pentaammine)cobalt(III) Perchlorate and characterised by various physicochemical methods. The kinetic study by stopped-flow spectrophotometer indicated that the dissociation of the trinuclear complex occurred mainly through an acid catalysed path.
Published Online: 2003-1-1
Published in Print: 2003-1-1
© 2014 by Walter de Gruyter Berlin/Boston
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Artikel in diesem Heft
- Kinetics and Mechanism of the Reaction of Ninhydrin with Chromium(III)-tryptophan Complex in Absence and Presence of Surfactants
- Site of Bond Breaking in mer-(Dihapto-[60]fullerene) (Dihapto-1,2-Bis-(DiphenyIphosphino)ethane Tricarbonyl Tungsten(0)
- Kinetic and mechanistic studies of mono(terpyridine)- to bis(terpyridine)-nickel(II) complex formation reactions involving a range of substituted 2,2′:6′,2″-terpyridine ligands: an investigation of π-stacking interactions in outer-sphere complexes.
- Kinetics and mechanism of reaction of α-picolinic acid with dichloro-{2-(arylazo)- heterocycle}palladium(II) complexes
- Simulation of Complex Chemical Kinetics
- Kinetics and Mechanisms of the Reduction of Chromium(VI) by 2-Mercaptoethanesulfonic Acid in Aqueous Solution: Difference in the Mechanistic Process of Reduction with Noncarboxylate Thiols
- Salt Effects on Reactivity for Substitution Reactions of Pentacyanoferrate(II) Complexes
- Substitution of aqua ligands from ds-[Pt(en)(H2O)2](ClO4)2 and cis-[Pt(dmen)(H2O)2](ClO4)2 (en = ethylenediamine, dmen = Ν,Ν′-dimethylethylenediamine) by glutathione (reduced) (GSH) in aqueous medium - A Kinetic And Mechanistic Study.
- Synthesis, Characterisation and Dissociation of a Glycinate Bridged Trinuclear Co(III)-Cu(II)-Co(III) Complex
- Notes for Contributors. Inorganic Reaction Mechanisms (IRM)
Schlagwörter für diesen Artikel
cobalt(III);
copper(II);
glycinate;
trinuclear complex;
dissociation kinetics
Artikel in diesem Heft
- Kinetics and Mechanism of the Reaction of Ninhydrin with Chromium(III)-tryptophan Complex in Absence and Presence of Surfactants
- Site of Bond Breaking in mer-(Dihapto-[60]fullerene) (Dihapto-1,2-Bis-(DiphenyIphosphino)ethane Tricarbonyl Tungsten(0)
- Kinetic and mechanistic studies of mono(terpyridine)- to bis(terpyridine)-nickel(II) complex formation reactions involving a range of substituted 2,2′:6′,2″-terpyridine ligands: an investigation of π-stacking interactions in outer-sphere complexes.
- Kinetics and mechanism of reaction of α-picolinic acid with dichloro-{2-(arylazo)- heterocycle}palladium(II) complexes
- Simulation of Complex Chemical Kinetics
- Kinetics and Mechanisms of the Reduction of Chromium(VI) by 2-Mercaptoethanesulfonic Acid in Aqueous Solution: Difference in the Mechanistic Process of Reduction with Noncarboxylate Thiols
- Salt Effects on Reactivity for Substitution Reactions of Pentacyanoferrate(II) Complexes
- Substitution of aqua ligands from ds-[Pt(en)(H2O)2](ClO4)2 and cis-[Pt(dmen)(H2O)2](ClO4)2 (en = ethylenediamine, dmen = Ν,Ν′-dimethylethylenediamine) by glutathione (reduced) (GSH) in aqueous medium - A Kinetic And Mechanistic Study.
- Synthesis, Characterisation and Dissociation of a Glycinate Bridged Trinuclear Co(III)-Cu(II)-Co(III) Complex
- Notes for Contributors. Inorganic Reaction Mechanisms (IRM)
