Abstract
The present work studies the removal of colored components from date syrup by activated carbon powder. The clarification process was carried out at an experimental batch set up and the role of activated carbon content, temperature and residence time was investigated on adsorption efficiency. The experimental data were analyzed by intra-particle diffusion, pseudo first- and second-order models. The adsorption capacity of activated carbon increases with increase of process temperature. Adsorption kinetics could be best modeled by the pseudo second-order model. Also, Langmuir isotherm describes the equilibrium data variation better than Freundlich and Temkin equations. The feasibility of adsorption was evaluated by measuring color removal at three temperatures and Van’t Hoff equation was used for computation of Gibbs energy. Thermodynamically, the process is endothermic accompanied with increase in randomness and decrease in Gibbs energy. Finally, the optimum temperature for clarification of date syrup was determined to be 50°C.
Acknowledgement
The authors would like to thank Shahd-Bab-Pars Company for contribution in preparing date syrup.
References
1. Hassan ML, Bras J, Hassan EA, Silard C, Mauret E. Enzyme-assisted isolation of microfibrillated cellulose from date palm fruit stalks. Ind Crop Prod 2014;55:102–8.10.1016/j.indcrop.2014.01.055Search in Google Scholar
2. Amira EA, Guido F, Behija SE, Manel I, Nesrine Z, Ali F, et al. Chemical and aroma volatile compositions of date palm (Phoenix dactylifera L.) Fruits at three maturation stages. Food Chem 2011;127:1744–5.4.10.1016/j.foodchem.2011.02.051Search in Google Scholar
3. Fahad J, Kashif G, Mehmet O. Physicochemical properties and mineral contents of seven different date fruit (Phoenix dactylifera L.) Varieties growing from Saudi Arabia. Environ Monit Assess 2013;186:2165–70.10.1007/s10661-013-3526-3Search in Google Scholar
4. Gabsi K, Trigui M, Barrington S, Helal AN, Taherian AR. Evaluation of rheological properties of date syrup. J Food Eng 2013;117:165–72.10.1016/j.jfoodeng.2013.02.017Search in Google Scholar
5. Borchani C, Besbes S, Blecker C, Masmoudi M, Baati R, Attia H. Chemical properties of 11 date cultivars and their corresponding fiber extracts. Afr J Biotechnol 2009;9:4096–105.Search in Google Scholar
6. Ahmed J, Ramaswamy HS. Physico-chemical properties of commercial date pastes (Phoenix dactylifera). J Food Eng 2006;76:348–52.10.1016/j.jfoodeng.2005.05.033Search in Google Scholar
7. Al-Farsi MA. Clarification of date juice. Int J Food Sci Technol 2003;38:241–5.10.1046/j.1365-2621.2003.00669.xSearch in Google Scholar
8. Abbès F, Kchaou W, Blecker C, Ongena M, Lognay G, Attia H, et al. Effect of processing conditions on phenolic compounds and antioxidant properties of date syrup. Ind Crop Prod 2013;44:634–42.10.1016/j.indcrop.2012.09.008Search in Google Scholar
9. Gökmen V, Serpen A. Equilibrium and kinetic studies on the adsorption of dark colored compounds from apple juice using adsorbent resin. J Food Eng 2002;53:221–7.10.1016/S0260-8774(01)00160-1Search in Google Scholar
10. Echavarraia AP, Pagan J, Ibarz A. Melanoidins formed by Maillard reaction in food and their biological activity. Food Eng Rev 2012;4:203–23.10.1007/s12393-012-9057-9Search in Google Scholar
11. Arslanoğlu FN, Kar F, Arslan N. Adsorption of dark coloured compounds from peach pulp by using powdered-activated carbon. J Food Eng 2005;71:156–63.10.1016/j.jfoodeng.2004.10.029Search in Google Scholar
12. Lassoued I, Jridi M, Nasri R, Dammak A, Hajji M, Nasri M, et al. Characteristics and functional properties of gelatin from thornback ray skin obtained by pepsin-aided process in comparison with commercial Halal bovine gelatin. Food Hydrocolloids 2014;41:309–18.10.1016/j.foodhyd.2014.04.029Search in Google Scholar
13. Soto ML, Moure A, Domínguez H, Parajó JC. Charcoal adsorption of phenolic compounds present in distilled grape pomace. J Food Eng 2008;84:156–63.10.1016/j.jfoodeng.2007.04.030Search in Google Scholar
14. Mudoga HL, Yucel H, Kincal NS. Decolorization of sugar syrups using commercial and sugar beet pulp based activated carbons. Bioresource Technol 2008;99:3528–33.10.1016/j.biortech.2007.07.058Search in Google Scholar PubMed
15. Arslanoğlu FN, Kar F, Arslan N. Adsorption of dark coloured compounds from peach pulp by using granular activated carbon. J Food Eng 2005;68:409–17.10.1016/j.jfoodeng.2004.06.017Search in Google Scholar
16. Caqueret V, Bostyn S, Cagnon B, Fauduet H. Purification of sugar beet vinasse – adsorption of polyphenolic and dark colored compounds on different commercial activated carbons. Bioresource Technol 2008;99:5814–21.10.1016/j.biortech.2007.10.009Search in Google Scholar PubMed
17. Nasehi SM, Ansari S, Sarshar M. Removal of dark colored compounds from date syrup using activated carbon: A kinetic study. J Food Eng 2012;111:490–5.10.1016/j.jfoodeng.2012.02.037Search in Google Scholar
18. Saha P, Chowdhury S, Gupta S, Kumar I. Insight into adsorption equilibrium, kinetics and thermodynamics of malachite green onto clayey soil of Indian origin. Chem Eng J 2010;165:874–82.10.1016/j.cej.2010.10.048Search in Google Scholar
19. Lagergren S. Zur theorie der sogenannten adsorption geloster stoff. K Sven Vetensk Akad Handl 1898;24:1–39.Search in Google Scholar
20. Soetaredjo FE, Ismadji S, Santoso SP, Ki OL, Kurniawan A, Ju YH. Recovery of catechin and epicatechin from sago waste effluent: study of kinetic and binary adsorption isotherm studies. Chem Eng J 2013;231:406–13.10.1016/j.cej.2013.07.048Search in Google Scholar
21. Subramanyam B, Das B. Linearized and non-linearized isotherm models comparative study on adsorption of aqueous phenol solution in soil. Int J Environ Sci Technol 2009;6:633–40.10.1007/BF03326104Search in Google Scholar
22. Goldberg S. Equations and models describing adsorption processes in soils. Soil Sci Soc Am J 2005;8:489–517.10.2136/sssabookser8.c10Search in Google Scholar
23. Tosun İ. Ammonium removal from aqueous solutions by clinoptilolite: determination of isotherm and thermodynamic parameters and comparison of kinetics by the double exponential model and conventional kinetic models. Int J Environ Res Publ Health 2012;9:970–84.10.3390/ijerph9030970Search in Google Scholar PubMed PubMed Central
24. Ahmed MJ, Theydan SK. Equilibrium isotherms, kinetics and thermodynamics studies of phenolic compounds adsorption on palm-tree fruit stones. Ecotox Environ Safe 2012;84:39–45.10.1016/j.ecoenv.2012.06.019Search in Google Scholar PubMed
25. Febrianto J, Kosasih AN, Sunarso J, Ju YH, Indraswati N, Ismadji S. Equilibrium and kinetic studies in adsorption of heavy metals using biosorbent: A summary of recent studies. J Hazard Mater 2009;162:616–45.10.1016/j.jhazmat.2008.06.042Search in Google Scholar PubMed
26. Ahmad AA, Hameed BH, Ahmad AL. Equilibrium and kinetics of disperse dye adsorption on activated carbon prepared from rattan sawdust by chemical activation. International Conference on Environment, Malaysia, 2008; December 15–17.Search in Google Scholar
27. Czepirski L, Balys MR, Komorowska-Czepirska E. Some generalization of Langmuir adsorption isotherm. Int J Chem 2000;3:30–59.Search in Google Scholar
28. Ho YS, Porter JF, Mckay G. Equilibrium isotherm studies for the sorption of divalent metal ions onto peat: copper, nickel and lead single component system. Water Air Soil Poll 2000;141:1–33.10.1023/A:1021304828010Search in Google Scholar
29. Villa-Velez HA, Váquiro HA, Bon J, Telis-Romero J. Thermodynamic properties of banana waste by analytical derivation of desorption isotherms. Int J Food Eng 2012;8:1–19.10.1515/1556-3758.2191Search in Google Scholar
30. Stuart BH. Infrared spectroscopy: Fundamentals and applications. University of Technology, Sydney, Australia John Wiley & Sons, Ltd. 2004;71–152.10.1002/0470011149Search in Google Scholar
31. Liu X, Xu Z, Gao Y, Yang B, Zhao J, Wang L. Adsorption characteristics of anthocyanins from purple-fleshed potato (Solanum tuberosum Jasim) extract on macroporous resins. Int J Food Eng 2007;3:1–16.10.2202/1556-3758.1230Search in Google Scholar
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Articles in the same Issue
- Frontmatter
- Research Articles
- Numerical Solution of a Nonlinear Diffusion Model for Soybean Hydration with Moving Boundary
- Simulation and Performance of a Solar Drying Unit with Storage for Aromatic and Medicinal Plants
- Preparation of Nano-curcumin with Enhanced Dissolution Using Ultrasonic-Assisted Supercritical Anti-solvent Technique
- Effect of Various Concentration of β-Cyclodextrin Inclusion Complexes Containing trans-Cinnamaldehyde by Molecular Self-Assembly
- Effects of Amount of Batter in Baking Cup on Muffin Quality
- Influence of Tapioca Starch on Thermal Properties of Wheat Flour-Based Batter and Quality of Fried Battered Chicken Wingsticks
- Clarification of Date Syrup by Activated Carbon: Investigation on Kinetics, Equilibrium Isotherm, and Thermodynamics of Interactions
- Changes in Some Quality Properties of Kefir during Storage and Inhibition Effect of Water Soluble Extracts on Angiotensin-I Converting Enzyme Purified by Human Plasma
- Drying Characteristics and Assessment of Physicochemical and Microstructural Properties of Dried Culinary Banana Slices
- Multi-Objective Optimization of the Pasteurization Process of Pumpkin Cubes Packaged in Glass Jars
- Mathematical Modeling of Thin-Layer Solar Drying for Yarrow, Coriander and Hollyhock
- Shorter Communication
- Drying Kinetics of American Ginseng Slices in Thin-layer Air Impingement Dryer
Articles in the same Issue
- Frontmatter
- Research Articles
- Numerical Solution of a Nonlinear Diffusion Model for Soybean Hydration with Moving Boundary
- Simulation and Performance of a Solar Drying Unit with Storage for Aromatic and Medicinal Plants
- Preparation of Nano-curcumin with Enhanced Dissolution Using Ultrasonic-Assisted Supercritical Anti-solvent Technique
- Effect of Various Concentration of β-Cyclodextrin Inclusion Complexes Containing trans-Cinnamaldehyde by Molecular Self-Assembly
- Effects of Amount of Batter in Baking Cup on Muffin Quality
- Influence of Tapioca Starch on Thermal Properties of Wheat Flour-Based Batter and Quality of Fried Battered Chicken Wingsticks
- Clarification of Date Syrup by Activated Carbon: Investigation on Kinetics, Equilibrium Isotherm, and Thermodynamics of Interactions
- Changes in Some Quality Properties of Kefir during Storage and Inhibition Effect of Water Soluble Extracts on Angiotensin-I Converting Enzyme Purified by Human Plasma
- Drying Characteristics and Assessment of Physicochemical and Microstructural Properties of Dried Culinary Banana Slices
- Multi-Objective Optimization of the Pasteurization Process of Pumpkin Cubes Packaged in Glass Jars
- Mathematical Modeling of Thin-Layer Solar Drying for Yarrow, Coriander and Hollyhock
- Shorter Communication
- Drying Kinetics of American Ginseng Slices in Thin-layer Air Impingement Dryer