Startseite Adsorption of paratoluic acid on MIL-53 (Al) metal-organic framework, and response surface methodology optimization
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Adsorption of paratoluic acid on MIL-53 (Al) metal-organic framework, and response surface methodology optimization

  • Ali Ghalandari , Zohreh Saadati EMAIL logo , Ali Farajtabar und Bijan Mombeni Goodajdar
Veröffentlicht/Copyright: 30. September 2022
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International Journal of Chemical Reactor Engineering
Aus der Zeitschrift International Journal of Chemical Reactor Engineering Band 21 Heft 5

Abstract

In this study, an organic metal framework adsorbent was used to remove paratoluic acid from aqueous solutions. The effect of various parameters such as pH, initial concentration of paravoluic acid, contact time, and amount of adsorbent was investigated by experimental design method. Central composite design (CCD) was used to optimize paratoluic acid uptake. Initially, MIL-53 (Al) was synthesized, and characterized by X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR), spectroscopy, and thermogravimetry (TGA). The results of central composite design showed that pH is the most essential factor in the removal of paratoluic acid with MIL-53 (Al). The maximum removal efficiency of paratoluic acid by MIL-53 (Al) adsorbent is 93.67%, the optimal amount of adsorbent is 0.396 g, the optimal time is 35.67 min, the initial concentration is 11.12 mg L−1. The pH is 6.6 with the desired amount 1 is. Isothermal, and kinetic models have also examined. The maximum adsorption capacity was 132.05 (mg g−1), and the adsorption data of MIL-53 (Al) were well consistent with the quasi-second order, and Langmuir isotherm models.

Keywords: MIL-53 (Al); paratoluic acid; response surface methodology
Corresponding author: Zohreh Saadati, Department of Chemistry, Omidiyeh Branch, Islamic Azad University, Omidiyeh, Iran, E-mail:

Funding source: Islamic Azad University

Award Identifier / Grant number: Unassigned

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: We are grateful for the support, and cooperation of Omidiyeh Branch of Islamic Azad University, and Tondgouyan Petrochemical Branch.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2022-03-06
Accepted: 2022-09-11
Published Online: 2022-09-30

© 2022 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Frontmatter
  2. Articles
  3. Numerical study of post-combustion characteristic in a smelting reduction furnace
  4. Experimental study and modeling of denitrification in an MBBR reactor
  5. Experimental study on the influence of fuel-rich and fuel-lean coal/airflow ratio on aerodynamic characteristics of a 300MWe foster wheeler down-fired boiler
  6. Effect of La on the catalytic performance of mesoporous Ni/γ-Al2O3 catalysts for dry reforming of methane
  7. Adsorption of paratoluic acid on MIL-53 (Al) metal-organic framework, and response surface methodology optimization
  8. An intelligent dynamic setting control framework for a multimode impurity removal process
  9. Optimization of microwave-assisted synthesis process for water-soluble ammonium polyphosphate from urea phosphate and urea
  10. Oxidation of NMST to NMSBA catalyzed by Co/Mn/Br together with porous carbon made from coconut shell with acetic acid as an activator
  11. Influence of blast volume on hot blast distribution rule around the hearth circumferentially
https://doi.org/10.1515/ijcre-2022-0044
Schlagwörter für diesen Artikel
MIL-53 (Al); paratoluic acid; response surface methodology

Artikel in diesem Heft

  1. Frontmatter
  2. Articles
  3. Numerical study of post-combustion characteristic in a smelting reduction furnace
  4. Experimental study and modeling of denitrification in an MBBR reactor
  5. Experimental study on the influence of fuel-rich and fuel-lean coal/airflow ratio on aerodynamic characteristics of a 300MWe foster wheeler down-fired boiler
  6. Effect of La on the catalytic performance of mesoporous Ni/γ-Al2O3 catalysts for dry reforming of methane
  7. Adsorption of paratoluic acid on MIL-53 (Al) metal-organic framework, and response surface methodology optimization
  8. An intelligent dynamic setting control framework for a multimode impurity removal process
  9. Optimization of microwave-assisted synthesis process for water-soluble ammonium polyphosphate from urea phosphate and urea
  10. Oxidation of NMST to NMSBA catalyzed by Co/Mn/Br together with porous carbon made from coconut shell with acetic acid as an activator
  11. Influence of blast volume on hot blast distribution rule around the hearth circumferentially
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