Assessment of the Efficiency of Aliquat 336+Rice Bran Oil for Separation of Acrylic Acid from Aqueous Solution Using Reactive Extraction
-
Himangshu Mondal
,
Kanti Kumar Athankar
and
Kailas L. Wasewar
Abstract
Biomass is an attractive target in process development for the emerging renewable resources based bio-refinery industry. Due to the ample range of application of acrylic acid, its production through bio-route received more awareness in scientific fraternity. In this view, an attempted was made to study the reactive extraction of acrylic acid with aliquat 336 in rice bran oil. Moreover, Box-Behnken matrix was employed to corroborate the effects of process variables viz. concentration of acrylic acid [CAA]aq, concentration of aliquat 336 [CR4N+Cl], and temperature on the extraction efficiency (η%). In physical extraction, average extraction efficiency was found in the order as: 43.55 > 35.36 > 29.14 at 303 K, 323 K, and 343 K respectively in rice bran oil. The correlation coefficient, R2 = 0.988 % indicates the appropriateness of proposed model to predict the extraction efficiency in terms of independent variables, and the predicted values were found in close agreement with that of experimental results. Further, R2(Pred) = 0.806 is in reasonable agreement with the R2(Adj) = 0.972. The optimum conditions for extraction of acrylic acid using aliquat 336 as an extractant in rice bran oil are [CAA]aq = 0.0.5 (mol/kg); [CR4N+Cl] = 1.98 (mol/kg); temperature = 323 K and the model predicted extraction efficiency 77.5 % was found to be an excellent fit with the experimental value 75 %. Further, number of theoretical stages was found to be 3 and S/F ratio 0.247.
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Articles in the same Issue
- Experiment and Dynamic Simulation of PIG Motion during Pigging Operation in a Slope Pipeline
- Solar Radiation Effect on a Magneto Nanofluid Flow in a Porous Medium with Chemically Reactive Species
- Mathematical Modeling of Ethane Cracking Furnace of Olefin Plant with Coke Formation Approach
- Entropy Generation and Activation Energy Impact on Radiative Flow of Viscous Fluid in Presence of Binary Chemical Reaction
- Exploration of Chemical Reaction Effects on Entropy Generation in Heat and Mass Transfer of Magneto-Jeffery Liquid
- Response Surface Methodology Optimization for Photodegradation of Methylene Blue in a ZnO Coated Flat Plate Continuous Photoreactor
- Modeling of Fluid Bed Reactor of Ethylene Di Chloride Production in Abadan Petrochemical Based on Three-Phase Hydrodynamic Model
- Optimization and Reaction Kinetics Studies on Copper-Cobalt Catalyzed Liquid Phase Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Dimethylfuran
- Role of Fe(III) and Oxalic Acid in the photo-Fenton System for 3-Methylphenol Degradation in Aqueous Solution under Natural and Artificial Light
- Assessment of the Efficiency of Aliquat 336+Rice Bran Oil for Separation of Acrylic Acid from Aqueous Solution Using Reactive Extraction
