Startseite Preparation of Activated Carbons from Walnut Shell by Fast Activation with H3PO4: Influence of Fluidization of Particles
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Preparation of Activated Carbons from Walnut Shell by Fast Activation with H3PO4: Influence of Fluidization of Particles

  • Xinyuan Gao , Long Wu , Wenjie Wan , Qing Xu und Zhanyong Li EMAIL logo
Veröffentlicht/Copyright: 19. September 2017
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Abstract

Activated carbons were produced from walnut shell by fast activation with H3PO4 in a spouted bed, and the influence of particles fluidization had been investigated. Experimental results showed that walnut shell particles with higher H3PO4 impregnation ratios would be agglomerated in spouted bed, and difficult to fluidize. Therefore, an amount of quartz sands were added to assist fluidization of H3PO4 impregnated walnut shell particles. The BET surface area of activated carbon prepared under fluidization would be obviously increased with H3PO4 impregnation ratio, reaching 1549.6 m2/g for the mass ratio of H3PO4 to walnut shell particles of 2 and activation temperature of 700°C. Meanwhile, both of the micro- and meso- pore volumes were increased. In addition, fluidization of particles had very little influence on activated carbon surface functional groups forming. It was found that the activated carbons contained more carbonyl groups (C = O), carboxyl groups (COOH) and some P-containing functional group.

Acknowledgements

The research is supported by International Joint Research and Development Project of Tianjin Talent Introduction and Science & Technology Cooperation Plan (14RCGFGX00850).

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Received: 2017-5-5
Accepted: 2017-9-6
Published Online: 2017-9-19

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