Startseite Characterization and Evaluation of Sorbent Materials Obtained from Orange Peel as an Alternative of Sustainable Materials for Water Treatment
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Characterization and Evaluation of Sorbent Materials Obtained from Orange Peel as an Alternative of Sustainable Materials for Water Treatment

  • Ana Karen Tovar , María José Arano , Obed Domínguez und Irma Robles EMAIL logo
Veröffentlicht/Copyright: 15. August 2017
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International Journal of Chemical Reactor Engineering
Aus der Zeitschrift International Journal of Chemical Reactor Engineering Band 15 Heft 5

Abstract

Sorbent orange peel based materials activated using NaOH and H3PO4 were prepared and evaluated in order to compare sorbent efficiency, and related to their physicochemical properties. Results of physicochemical characterization demonstrated there are significant changes on surface that promotes an adsorption behavior depending on the activation method. FTIR analysis shows decreasing signal of water at 3422 cm−1 of water, hemicellulose and pectin due to activation process, another decreasing signal is observed at at 1626 cm−1 for CC bond, while an increasing pick is observed at 1435 cm−1 which corresponds to methoxyl groups belonging to cellulosic compounds. Analysis of sorption equilibrium indicated 78 % of methyl orange sorption in orange dry peel (OP) which was sorbed after 5 hour, compared to 84 % and 98 % using 0.1 M activated sorbent material 2(AM2) and 0.6 M activated sorbent material 3 (AM3) H3PO4 respectively, this process was carried out during the first 90 min of sorption process. NaOH activated sorbent material 1 (AM1) promoted 20 % to 65 % sorption. orange dry peel (OP), activated sorbent material 2 (AM2) and activated sorbent material 3 (AM3) obeyed a pseudo-second order kinetic model, while activated sorbent material 1 (AM1) obeys a pseudo-first order model. Sorption equilibrium of methyl orange resulted as follows, orange dry peel (OP) followed a Freundlich equilibrium model, activated sorbent material 1 (AM1) a Langmuir model, while activated sorbent material 2 (AM2) and activated sorbent material 3 (AM3) to Hill model. Activated sorbent materials with H3PO4 showed 750–770 mg/g of methyl orange which represent high sorption capacities. Orange peel sorbent material previously activated with H3PO4 represents a good alternative to reduce water pollution, and also residues of orange peel could be reduced by this alternative treatment.

Keywords: kinetic; isotherm; sorbent materials; orange peel; valorization

Acknowledgements

Authors thank to Centro de Investigación y Desarrollo Tecnológico en Electroquimica (CIDETEQ) for the facilities to carry out the present research. Ana Karen Tovar is grateful to Consejo Nacional de Ciencia y Tecnología de los Estados Unidos Mexicanos (CONACYT) for her scholarship.

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Published Online: 2017-8-15

© 2017 Walter de Gruyter GmbH, Berlin/Boston

Artikel in diesem Heft

  1. Editorial
  2. Special Issue in Honor of J. Alberto Ochoa-Tapia
  3. Research Articles
  4. The Scientific Achievements of J. Alberto Ochoa-Tapia
  5. Volume Averaged Equations for Mass Transport and Reaction for In-Situ Combustion
  6. Non-Isothermal Effectiveness Factor for Catalytic Particles with Non-Fickian Diffusion
  7. Finite Time Estimation for Switched Nonlinear Systems: Application to Stirred Tank Bioreactor
  8. Numerical Solution for a System of Fractional Differential Equations with Applications in Fluid Dynamics and Chemical Engineering
  9. Characterization and Evaluation of Sorbent Materials Obtained from Orange Peel as an Alternative of Sustainable Materials for Water Treatment
  10. Metal complexes supported on activated carbon as catalysts for the hydrogenation of anthracene
  11. Iron Supported on Ion Exchange Resin as Source of Iron for Fenton Reagent: A Heterogeneous or a Homogeneous Fenton Reagent Generation?
  12. Stokes Flow Inside Topographically Patterned Microchannel Using Boundary Element Method
  13. Degradation and Mineralization of a Cationic Dye by a Sequential Photo-Sono Catalytic Process
  14. Preparation of Mo/HZSM-5/Bentonite Catalyst for Methane Aromatization in a Fluidized Bed Reactor
  15. On the Understanding of the Adsorption of 2-Phenylethanol on Polyurethane-Keratin based Membranes
  16. La-, Mn- and Fe-Doped Zirconia Washcoats Deposited on Monolithic Reactors via Sol-Gel Method: Characterization and Evaluation of their Mass Transfer Phenomena and Kinetics in Trichloroethylene Combustion
  17. State Estimation Based on Nonlinear Observer for Hydrogen Production in a Photocatalytic Anaerobic Bioreactor
https://doi.org/10.1515/ijcre-2017-0013
Schlagwörter für diesen Artikel
kinetic; isotherm; sorbent materials; orange peel; valorization

Artikel in diesem Heft

  1. Editorial
  2. Special Issue in Honor of J. Alberto Ochoa-Tapia
  3. Research Articles
  4. The Scientific Achievements of J. Alberto Ochoa-Tapia
  5. Volume Averaged Equations for Mass Transport and Reaction for In-Situ Combustion
  6. Non-Isothermal Effectiveness Factor for Catalytic Particles with Non-Fickian Diffusion
  7. Finite Time Estimation for Switched Nonlinear Systems: Application to Stirred Tank Bioreactor
  8. Numerical Solution for a System of Fractional Differential Equations with Applications in Fluid Dynamics and Chemical Engineering
  9. Characterization and Evaluation of Sorbent Materials Obtained from Orange Peel as an Alternative of Sustainable Materials for Water Treatment
  10. Metal complexes supported on activated carbon as catalysts for the hydrogenation of anthracene
  11. Iron Supported on Ion Exchange Resin as Source of Iron for Fenton Reagent: A Heterogeneous or a Homogeneous Fenton Reagent Generation?
  12. Stokes Flow Inside Topographically Patterned Microchannel Using Boundary Element Method
  13. Degradation and Mineralization of a Cationic Dye by a Sequential Photo-Sono Catalytic Process
  14. Preparation of Mo/HZSM-5/Bentonite Catalyst for Methane Aromatization in a Fluidized Bed Reactor
  15. On the Understanding of the Adsorption of 2-Phenylethanol on Polyurethane-Keratin based Membranes
  16. La-, Mn- and Fe-Doped Zirconia Washcoats Deposited on Monolithic Reactors via Sol-Gel Method: Characterization and Evaluation of their Mass Transfer Phenomena and Kinetics in Trichloroethylene Combustion
  17. State Estimation Based on Nonlinear Observer for Hydrogen Production in a Photocatalytic Anaerobic Bioreactor
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