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Iron Supported on Ion Exchange Resin as Source of Iron for Fenton Reagent: A Heterogeneous or a Homogeneous Fenton Reagent Generation?

  • Orlando García-Rodríguez , Jennifer A. Bañuelos , Luis A. Godínez , Hortencia C. Arredondo Valdez , Evelyn Zamudio , Victor Ramírez and Francisco J. Rodríguez-Valadez EMAIL logo
Published/Copyright: August 31, 2017

Abstract

The aim of this work is to discuss the relative contribution of homogeneous and heterogeneous Fenton processes in the treatment of Orange II dye solutions at pH 3 and 7 using an ion exchange resin as iron support. While at pH 3, 99% of the colour was removed, under neutral conditions a decoloration of 56% was observed. Studying the release of iron from the resin, we found a concentration of 1.49 mg/L of ferric ion and 0.31 mg/L of ferrous ion at pH 3 and 1.08 mg/L and 0.11 mg/L at pH 7, revealing that as expected, dissolution of iron ions at pH 3 is larger. Using these concentrations in a homogeneous process, 45% of the colour can be removed at pH 3 and 10% at pH 7, so it was infered that there is an effect of the iron that is still supported on the resin. In this way, a mixed homogeneous/heterogeneous mechanism could be proposed. While the experimental data for the desorption of iron at pH 3 was well suited to a pseudo second order kinetic model, the desorption of iron at pH 7 was fit to pseudo-first order kinetics. Experimental results of dye decolorization were on the other hand, fitted to a pseudo first order kinetics.

Acknowledgements

The authors acknowledge the Mexican National Council for Science and Technology (CONACYT) for financial support of this work (Grants 106590 and 339451). O. García-Rodríguez and H.C. Arredondo Valdez, also thank CONACYT for a graduate and a post-foctoral fellowship, respectively.

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Published Online: 2017-8-31

© 2017 Walter de Gruyter GmbH, Berlin/Boston

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