Iron Supported on Ion Exchange Resin as Source of Iron for Fenton Reagent: A Heterogeneous or a Homogeneous Fenton Reagent Generation?
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Orlando García-Rodríguez
Abstract
The aim of this work is to discuss the relative contribution of homogeneous and heterogeneous Fenton processes in the treatment of Orange II dye solutions at pH 3 and 7 using an ion exchange resin as iron support. While at pH 3, 99% of the colour was removed, under neutral conditions a decoloration of 56% was observed. Studying the release of iron from the resin, we found a concentration of 1.49 mg/L of ferric ion and 0.31 mg/L of ferrous ion at pH 3 and 1.08 mg/L and 0.11 mg/L at pH 7, revealing that as expected, dissolution of iron ions at pH 3 is larger. Using these concentrations in a homogeneous process, 45% of the colour can be removed at pH 3 and 10% at pH 7, so it was infered that there is an effect of the iron that is still supported on the resin. In this way, a mixed homogeneous/heterogeneous mechanism could be proposed. While the experimental data for the desorption of iron at pH 3 was well suited to a pseudo second order kinetic model, the desorption of iron at pH 7 was fit to pseudo-first order kinetics. Experimental results of dye decolorization were on the other hand, fitted to a pseudo first order kinetics.
Acknowledgements
The authors acknowledge the Mexican National Council for Science and Technology (CONACYT) for financial support of this work (Grants 106590 and 339451). O. García-Rodríguez and H.C. Arredondo Valdez, also thank CONACYT for a graduate and a post-foctoral fellowship, respectively.
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Articles in the same Issue
- Editorial
- Special Issue in Honor of J. Alberto Ochoa-Tapia
- Research Articles
- The Scientific Achievements of J. Alberto Ochoa-Tapia
- Volume Averaged Equations for Mass Transport and Reaction for In-Situ Combustion
- Non-Isothermal Effectiveness Factor for Catalytic Particles with Non-Fickian Diffusion
- Finite Time Estimation for Switched Nonlinear Systems: Application to Stirred Tank Bioreactor
- Numerical Solution for a System of Fractional Differential Equations with Applications in Fluid Dynamics and Chemical Engineering
- Characterization and Evaluation of Sorbent Materials Obtained from Orange Peel as an Alternative of Sustainable Materials for Water Treatment
- Metal complexes supported on activated carbon as catalysts for the hydrogenation of anthracene
- Iron Supported on Ion Exchange Resin as Source of Iron for Fenton Reagent: A Heterogeneous or a Homogeneous Fenton Reagent Generation?
- Stokes Flow Inside Topographically Patterned Microchannel Using Boundary Element Method
- Degradation and Mineralization of a Cationic Dye by a Sequential Photo-Sono Catalytic Process
- Preparation of Mo/HZSM-5/Bentonite Catalyst for Methane Aromatization in a Fluidized Bed Reactor
- On the Understanding of the Adsorption of 2-Phenylethanol on Polyurethane-Keratin based Membranes
- La-, Mn- and Fe-Doped Zirconia Washcoats Deposited on Monolithic Reactors via Sol-Gel Method: Characterization and Evaluation of their Mass Transfer Phenomena and Kinetics in Trichloroethylene Combustion
- State Estimation Based on Nonlinear Observer for Hydrogen Production in a Photocatalytic Anaerobic Bioreactor
Articles in the same Issue
- Editorial
- Special Issue in Honor of J. Alberto Ochoa-Tapia
- Research Articles
- The Scientific Achievements of J. Alberto Ochoa-Tapia
- Volume Averaged Equations for Mass Transport and Reaction for In-Situ Combustion
- Non-Isothermal Effectiveness Factor for Catalytic Particles with Non-Fickian Diffusion
- Finite Time Estimation for Switched Nonlinear Systems: Application to Stirred Tank Bioreactor
- Numerical Solution for a System of Fractional Differential Equations with Applications in Fluid Dynamics and Chemical Engineering
- Characterization and Evaluation of Sorbent Materials Obtained from Orange Peel as an Alternative of Sustainable Materials for Water Treatment
- Metal complexes supported on activated carbon as catalysts for the hydrogenation of anthracene
- Iron Supported on Ion Exchange Resin as Source of Iron for Fenton Reagent: A Heterogeneous or a Homogeneous Fenton Reagent Generation?
- Stokes Flow Inside Topographically Patterned Microchannel Using Boundary Element Method
- Degradation and Mineralization of a Cationic Dye by a Sequential Photo-Sono Catalytic Process
- Preparation of Mo/HZSM-5/Bentonite Catalyst for Methane Aromatization in a Fluidized Bed Reactor
- On the Understanding of the Adsorption of 2-Phenylethanol on Polyurethane-Keratin based Membranes
- La-, Mn- and Fe-Doped Zirconia Washcoats Deposited on Monolithic Reactors via Sol-Gel Method: Characterization and Evaluation of their Mass Transfer Phenomena and Kinetics in Trichloroethylene Combustion
- State Estimation Based on Nonlinear Observer for Hydrogen Production in a Photocatalytic Anaerobic Bioreactor