Abstract
A benzophenone-containing SET-LRP initiator based on renewable and abundant cardanol was synthesised in 71 % yield using the selective etherification reaction. Next, methyl methacrylate (MMA) as a monomer was polymerised under SET-LRP conditions using the newly prepared initiator to prepare cardanol-end poly(methyl methacrylate) (PMMA). The kinetic results of the polymerisation indicated that the reaction was controllable when the monomer conversion was lower than approximately 50 %, and the molecular masses of PMMA measured by GPC were higher than the theoretical values while the monomer conversion was more than 50 %. In addition, most of the carbon-carbon double bonds of the side hydrocarbon chain of the end-cardanol group in the PMMA were kept intact from 1H NMR spectrum characterisation. Accordingly, when the cardanolend PMMA together with a tertiary amine-containing cardanol derivative was irradiated by UV light, the corresponding UV-cured resin was obtained. The chemical resistance and hardness of the UV-cured film were enhanced with the increasing irradiation time.
References
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Institute of Chemistry, Slovak Academy of Sciences
Articles in the same Issue
- Catalysis in glycerol: a survey of recent advances
- A rapid LC-MS/MS method for determination of urinary EtG and application to a cut-off limit study
- Validated chiral chromatographic methods for clopidogrel bisulphate and its related substances in bulk drug and pharmaceutical dosage forms
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- Effect of rapid batch decompression on hydrolysate quality after hydrothermal pretreatment of wheat straw
- Anthocyanins profile, total phenolics and antioxidant activity of two Romanian red grape varieties: Feteascǎ neagrǎ and Bǎbeascǎ neagrǎ (Vitis vinifera)
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- Synthesis of cardanol-based photo-active SET-LRP initiator and its application to preparation of UV-cured resin
- Preparation, characterization and ion adsorption properties of functionalized polystyrene modified with 1,4-phenylene diisocyanate and diethylenetriamine
- Synthesis of lanthanide-based SBA-15 mesoporous hybrids by a novel route
- Comparative ESI FT-MS and MALDI-TOF structural analyses of representative human N-linked glycans
Articles in the same Issue
- Catalysis in glycerol: a survey of recent advances
- A rapid LC-MS/MS method for determination of urinary EtG and application to a cut-off limit study
- Validated chiral chromatographic methods for clopidogrel bisulphate and its related substances in bulk drug and pharmaceutical dosage forms
- Effect of SO2 on SCR activity of MnOx/PG catalysts at low temperature
- Preparation of Pd/Al2O3@silicalite-1 core–shell beads and their application to hydrogenation reactions
- Effect of rapid batch decompression on hydrolysate quality after hydrothermal pretreatment of wheat straw
- Anthocyanins profile, total phenolics and antioxidant activity of two Romanian red grape varieties: Feteascǎ neagrǎ and Bǎbeascǎ neagrǎ (Vitis vinifera)
- Polyphenols, radical scavenger activity, short-chain organic acids and heavy metals of several plants extracts from “Bucharest Delta”
- Reaction of anhydrous zinc chloride with 2,3-thiophenedicarbaldehyde bis(semicarbazone) (2,3BSTCH2) and bis(thiosemicarbazone) (2,3BTSTCH2): Crystal structure of {[C6H5N2S]+[ZnCl3(C6H4N2S)]−} complex
- Synthesis and evaluation of a novel hydrophobically associating polymer based on acrylamide for enhanced oil recovery
- Synthesis of cardanol-based photo-active SET-LRP initiator and its application to preparation of UV-cured resin
- Preparation, characterization and ion adsorption properties of functionalized polystyrene modified with 1,4-phenylene diisocyanate and diethylenetriamine
- Synthesis of lanthanide-based SBA-15 mesoporous hybrids by a novel route
- Comparative ESI FT-MS and MALDI-TOF structural analyses of representative human N-linked glycans