Startseite Syntheses, structures and properties of isonicotinamidium, thionicotinamidium, 2- and 3-(hydroxymethyl)pyridinium nitrates
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Syntheses, structures and properties of isonicotinamidium, thionicotinamidium, 2- and 3-(hydroxymethyl)pyridinium nitrates

  • Zuzana Lukačovičová EMAIL logo , Darina Lacková , Michal Brienik , Iveta Ondrejkovičová , Ondrej Záborský , Jana Doháňošová und Marian Koman
Veröffentlicht/Copyright: 15. Mai 2015
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Chemical Papers
Aus der Zeitschrift Chemical Papers Band 69 Heft 8

Abstract

New salts containing cations of selected pyridine derivatives of the composition [pyH]NO3, where py is 2-pyridylmethanol (2-(hydroxymethyl)pyridine, 2pm), 3-pyridylmethanol (3-(hydroxymethyl) pyridine, 3pm), isonicotinamide (4-(aminocarbonyl)-pyridine, inia) and thionicotinamide (4- (aminothiocarbonyl)pyridine, tnia) were synthesised using two methods. By the first method, the above salts were obtained from reaction mixtures prepared from Fe(NO3)3 ·9H2O and the appropriate pyridine derivative py in ethanol without the addition of acids. The protons required for protonation of the given pyridine derivatives are formed by the protolytic reaction of [Fe(H2O)6]3+, which acts as a cationic Brønstedt acid. These cations are present in the solid state of Fe(NO3)3 · 9H2O as well as in its solutions. Under the second procedure, the salts were prepared by a direct reaction of the selected pyridine derivative py with a diluted solution of HNO3. The first method affords crystals with lower yields but the second method produces microcrystals with higher yields. All the compounds were characterised by elemental analysis, infrared and NMR spectroscopic analyses and [3pmH]NO3 and [2pmH]NO3 by X-ray structure analysis also. [3pmH]NO3 crystallises in the monoclinic and [2pmH]NO3 in the triclinic system.

Keywords: pyridinium derivatives; nitrate; structural study; IR spectra; NMR spectroscopy

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Received: 2014-9-9
Revised: 2015-1-12
Accepted: 2015-1-12
Published Online: 2015-5-15
Published in Print: 2015-8-1

© Institute of Chemistry, Slovak Academy of Sciences

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https://doi.org/10.1515/chempap-2015-0105
Schlagwörter für diesen Artikel
pyridinium derivatives; nitrate; structural study; IR spectra; NMR spectroscopy

Artikel in diesem Heft

  1. Deferoxamine–paper for iron(III) and vanadium(V) sensing
  2. Integrated investigations for the characterisation of Roman lead-glazed pottery from Pompeii and Herculaneum (Italy)
  3. Determination of acetylcholinesterase and butyrylcholinesterase activity without dilution of biological samples
  4. Characterization of a novel Aspergillus niger beta-glucosidase tolerant to saccharification of lignocellulosic biomass products and fermentation inhibitors
  5. Immobilisation of tyrosinase on siliceous cellular foams affording highly effective and stable biocatalysts
  6. Displacement washing of soda rapeseed pulp
  7. Hydrovisbreaking of vacuum residue from Russian Export Blend: influence of brown coal, light cycle oil, or naphtha addition
  8. Antimicrobial properties and chemical composition of liquid and gaseous phases of essential oils
  9. Syntheses, structures and properties of isonicotinamidium, thionicotinamidium, 2- and 3-(hydroxymethyl)pyridinium nitrates
  10. Density of lithium fluoride–lithium carbonate-based molten salts
  11. Synthesis and antimicrobial activity of sulphamethoxazole-based ureas and imidazolidine-2,4,5-triones
  12. Synthesis, biological evaluation, quantitative-SAR and docking studies of novel chalcone derivatives as antibacterial and antioxidant agents
  13. Application of polypyrrole nanowires for the development of a tyrosinase biosensor
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  15. Erratum to “Ľubomír Vančo, Magdaléna Kadlečíková, Juraj Breza, Pavol Michniak, Michal Čeppan, Milena Reháková, Eva Belányiová, Beata Butvinová: Differentiation of selected blue writing inks by surface-enhanced Raman spectroscopy”, Chemical Papers 69 (4) 518–526 (2015)
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